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0 is the hydroxide-independent "acid" hydrolysis rate constant and f is that fraction of the buffer comprising the 9:1 (lowest pH) buffer component. For the buffers listed in Table 1S, these fractions are, from bottom to top, 1, 0.743 (rac), 0.512 (meso), 0.425, 0.342, 0.252, 0.145, and 0.
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