Solvent exchange, solvent interchange, aquation and isomerisation reactions of cis- and trans-[Co(tmen)2(NCMe)2] 3+ in water, Me2SO and MeCN: Kinetics and stereochemistry

Inorganica Chimica Acta

Volumn 357, Issue 3, 2004, Pages 665-676

  Jackson, W Gregory ^a   Rahman, A F M Mokhlesur ^a   Wong, M Anthony ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

Author keywords

Acetonitrile; Cobalt(III); Hydrolysis; Kinetics; Mechanism; Synthesis

Indexed keywords

ACETONITRILE; DIMETHYL SULFOXIDE; ENZYME KINETICS; HYDROLYSIS; ISOMERIZATION; ISOMERS; MECHANISMS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLVENTS; SYNTHESIS (CHEMICAL);

1H NMR SPECTROSCOPY; CIS-TRANS ISOMERISATION; EQUILIBRIUM POSITIONS; FIRST ORDER REACTIONS; ISOMERISATION REACTIONS; SINGLE STEP REACTION; SOLVENT EXCHANGES; UV-VIS SPECTROPHOTOMETRY;

COBALT COMPOUNDS;

CARBON; CHLORINE; COBALT; DIMETHYL SULFOXIDE; HYDROGEN; METHYL GROUP; NITROGEN; SOLVENT; SULFUR;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; ISOMERIZATION; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLVOLYSIS; SPECTROPHOTOMETRY; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS;

EID: 1242283957     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2003.05.010     Document Type: Article

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