Kinetics and mechanism of the osmium(VIII)-catalysed autoxidation of aqueous sulfur dioxide in acidic and alkaline media

Journal of the Indian Chemical Society

Volumn 81, Issue 12, 2004, Pages 1083-1092

  Gupta, K S ^a   Jain, Usha ^a   Singh, Abhilasha ^a   Mehta, R K ^b   Manoj, S V ^c   Prasad, D S N ^d   Sharma, Ashok ^d   Parashar, P ^e   Bansal, S P ^a  

^a UNIVERSITY OF RAJASTHAN   (India)

^b State Forensic Science Laboratory   (India)

^c Maharshi Arvind Institute E   (India)

^d Government College   (India)

^e LBS College   (India)

Author keywords

[No Author keywords available]

Indexed keywords

OSMIUM; OXYGEN; PHOSPHATE; SULFUR DIOXIDE;

ACIDITY; ALKALINITY; AUTOOXIDATION; CATALYSIS; CHEMICAL REACTION KINETICS; REDUCTION; REVIEW; SPECTROPHOTOMETRY;

EID: 12344302252     PISSN: 00194522     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Review

References (51)

1. C. Brandt and R.van Eldik, Chem. Rev., 1995, 95, 119.
2. 2 Oxidation Mechanisms : Atmospheric Considerations", ed. J. G. Calvert, Butterworth, Boston, 1984, pp. 63-100.
3. M. R. Hoffmann and J. G. Calvert, "Chemical Transformation Modules for Eulerian Acid Deposition Models", Government Printing Office, Washington, DC, (Aqueous Phase Chemistry), USEPA-NCAR Interagency Agreement DW 930237, 1985, Vol. 11.
4. D. A. Hegg and P. V. Hobbs, Atmos. Environ., 1978, 12, 241.
5. S. Beilke and G. Gravenhorst, Atmos. Environ., 1978, 12, 231.
6. M. R. Hoffmann, Environ. Sci. Technol., 1980, 14, 1061.
7. A. Huss (Jr.), P. K. Lim and C. A. Eckert, J. Am. Chem. Soc., 1978, 100, 6252.
8. S. Tsunogai, J. Geochem., 1971, 5, 175.
9. M. R. Hoffmann and S. D. Boyce in "Trace Atmospheric Constituents, Properties, Transformations and Fates", ed. S. E. Schwartz, John Wiley, New York, 1983.
10. 2 Oxidation Mechanisms, Atmospheric Considerations", ed. J. G. Calvert, Butterworth, Boston, 1984, p. 601.
11. D. E. Linn (Jr.), M. J. Dragan and D. E. Miller, Inorg. Chem., 1990, 29, 4356.
12. J. Berglund, S. Fronaeus and L. I. Elding, Inorg. Chem., 1993, 32, 4527; J. Berglund and L. I. Elding, Atoms. Envrion., 1995, 29, 1379.
13. J. Berglund, S. Fronaeus and L. I. Elding, Inorg. Chem., 1993, 32, 4527; J. Berglund and L. I. Elding, Atoms. Envrion., 1995, 29, 1379.
14. C. Brandt, I. Fabian and R. van Eldik, Inorg. Chem., 1994, 33, 687.
15. U. Jain, M. Sharma, A. Rani and K. S. Gupta, Indian J. Chem., Sect. A, 1995, 34, 971.
16. S. V. Manoj, R. Singh, M. Sharma and K. S. Gupta, Indian J. Chem., Sect. A, 2000, 37, 2000.
17. K. S. Gupta, P. Bhargava and S. V. Manoj, Transition Met. Chem., 2000, 25, 274; K. S. Gupta, P. Bhargava, S. V. Manoj and R. Bhargava, Transition Met. Chem., 2000, 25, 329.
18. K. S. Gupta, P. Bhargava and S. V. Manoj, Transition Met. Chem., 2000, 25, 274; K. S. Gupta, P. Bhargava, S. V. Manoj and R. Bhargava, Transition Met. Chem., 2000, 25, 329.
19. B. Padkrajsek, G. Bercic, J. Tursic and I. Grgic, J. Atmos. Chem., 2004, 47, 287.
20. F. R. Hartley (ed.), "Chemistry of the Platinum Group Metals", Studies in Inorganic Chemistry II, Elsevier, Amsterdam, 1991, p. 495.
21. H. S. Singh in "Organic Synthesis by Oxidation with Metal Compounds", eds. W. J. Mills and C. R. H. I. De Jonge, Plenum, New York, 1986.
22. V. Sharma, K. Chaudhury and K. K. Banerji, Int. J. Chem. Kinet., 1990, 22, 1039.
23. L. Bhatt, P. D. Sharma and Y. K. Gupta, J. Chem. Soc., Dalton Trans., 1984, 2563.
24. G. Sharma, A. R. Binyalia and P. D. Sharma, J. Chem. Res. (S), 2000, 213.
25. D. Gupta, I. Sharma and P. D. Sharma, J. Chem. Res. (M), 1998, 3377.
26. P. V. S. Madnawat, A. Rani, M. Sharma, D. S. N. Prasad and K. S. Gupta, Atmos. Environ., 1993, 27A, 1985.
27. D. S. N. Prasad, A. Rani and K. S. Gupta, Environ. Sci. Technol., 1992, 26, 1361.
28. S. V. Manoj, M. Sharma and K. S. Gupta, Atmos. Environ., 1999, 33, 1503.
29. F. A. Cotton and G. Wilkinson, "Advanced Inorganic Chemistry", 3rd ed., Wiley, New York, 1972, pp. 1003-1016.
30. N. V. Sidgwick, "The Chemical Elements and their Compounds", Oxford, London, 1950, Vol. II, pp. 1501-1520.
31. T. W. Newton and G. M. Arcand, J. Am. Chem. Soc., 1953, 75, 2449.
32. D. S. N. Prasad, A. Rani, P. V. S. Madnawat, R. Bhargava and K. S. Gupta, J. Mol. Catal., 1991, 69, 393.
33. A. Rani, D. S. N. Prasad, U. Jain and K. S. Gupta, Indian J. Chem., Sect. A, 1991, 30, 756.
34. R. E. Connick and Y. -X. Zhang, Inorg. Chem., 1996, 35, 4613.
35. R. E. Connick, Y. X. Zhang, S. Lee, R. Adamic and P. Chieng, Inorg. Chem., 1995, 34, 4543.
36. W. Pasiuk-Bronikowska, T. Bronikowski and M. Ulejczyk, J. Atmos. Chem., 2003, 44, 97.
37. J. Ziajka and W. Pasiuk-Bronikowska in "Proceedings from the EUROTRAC-2 Symposium 2000", Springer-Verlag, Berlin, 2001, pp. 519-523.
38. I. Grgic, M. Poznic and M. Bizjak, J. Atmos. Chem., 1999, 33, 89; M. Bizjak, I. Grgic and V. Hudnik, Chemosphere, 1999, 38, 1233.
39. I. Grgic, M. Poznic and M. Bizjak, J. Atmos. Chem., 1999, 33, 89; M. Bizjak, I. Grgic and V. Hudnik, Chemosphere, 1999, 38, 1233.
40. M. H. Conklin and M. R. Hoffmann, Environ. Sci. Technol., 1988, 22, 883, 891, 899.
41. J. F. Cairns and H. L. Roberts, J. Chem. Soc. (C), 1968, 640.
42. J. Perichon, S. Palous and R. Buvet, Bull. Chem. Soc. Fr., 1963, 982.
43. D. M. Vost and R. J. White, J. Am. Chem. Soc., 1928, 50, 81.
44. M. P. Singh, H. S. Singh, B. S. Arya, A. K. Singh and A. K. Sisodia, Indian J. Chem., 1975, 13, 489.
45. G. Mahal and R. van Eldik, Inorg. Chem., 1987, 26, 2838.
46. M. R. Hoffmann and J. O. Edwards, J. Phys. Chem., 1975, 79, 2096.
47. R. Bhargava, A. Rani and K. S. Gupta, Indian J. Chem., Sect. A, 1992, 31, 383.
48. R. Bhargava, A. Rani and K. S. Gupta, Indian J. Chem., Sect. A, 1993, 32, 713.
49. D. S. N. Prasad, A. Rani, M. Sharma and K. S. Gupta, Indian J. Chem. Technol., 1994, 1, 87.
50. W. Levason in Ref. (10), p. 495.
51. T. Behling, M. V. Capparelli, A. C. Skapski and G. Wilkinson, Polyhedron, 1982, 1, 840.