Role of cuprous oxide in the autoxidation of aqueous sulphur dioxide and its atmospheric implications

Atmospheric Environment

Volumn 33, Issue 10, 1999, Pages 1503-1512

  Manoj, S V ^a   Sharma, Madhu ^a   Gupta, K S ^a  

^a UNIVERSITY OF RAJASTHAN   (India)

Author keywords

Autoxidation; Catalysis; Copper(I) oxide; Kinetics; Sulphur dioxide; Sulphur(IV)

Indexed keywords

ACETATE; AUTOXIDATION;

CATALYSIS; COPPER OXIDES; FREE RADICAL REACTIONS; OXIDATION; REACTION KINETICS; SULFUR DIOXIDE; SUSPENSIONS (FLUIDS);

AIR POLLUTION;

COPPER; SULFUR OXIDE;

ATMOSPHERIC POLLUTION; COPPER; SMELTING; SULFUR DIOXIDE;

ACID RAIN; ADSORPTION; ARTICLE; ATMOSPHERIC DISPERSION; AUTOOXIDATION; CATALYSIS; COMBUSTION; OXYGEN TRANSPORT; PRIORITY JOURNAL; REACTION ANALYSIS; SUSPENSION;

EID: 0033136680     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(98)00241-6     Document Type: Article

References (47)

1. Backstrom, H.L.J., 1934. Der kettenmechanisms bei der autoxidation von aldehyden. Zeitschrift fuer Physikalische Chemie (Leipzig) 25, 99-121.
2. Bal Reddy, K., van Eldik, R., 1992. Kinetics and mechanism of the sulfite induced autoxidation of Fe(II) in aqueous solution. Atmospheric Environment 26A, 661-665.
3. Barron, C.H., O'Hern, H.A., 1966. Reaction kinetics of sodium sulfite by the rapid mixing method. Chemical Engineering Science 21, 397-404.
4. - radicals in aqueous solution. Journal of Physical Chemical Reference Data 14, 1042.
5. Berglund, J., Elding, L.I., 1995. Manganese-catalysed autoxidation of dissolved sulfur dioxide in the atmospheric aqueous phase. Atmospheric Environment 29, 1379-1391.
6. Berglund, J., Fronaeus, S., Elding, L.I., 1993. Kinetics and mechanism for manganese-catalysed oxidation of sulfur(IV) by oxygen in aqueous solution. Inorganic Chemistry 32, 4527-4538.
7. Bhargava, R., Prasad, D.S.N., Rani, A., Bhargava, P., Jain, U., Gupta, K.S., 1992. Kinetics of autoxidation of aqueous sulphur dioxide in suspensions of nickel(III) oxide. Transition of Metal Chemistry 17, 238.
8. 2 from flue gases. Indian Journal of Chemistry 32A, 713-716.
9. Bhargava, R., Rani, A., Gupta, K.S., 1992. Surface mediated autoxidation of aqueous sulphur dioxide in ceramic powder suspensions. Indian Journal of Chemistry 31A, 683-687.
10. Brandt, C., van Eldik, R., 1995. Transition metal catalysed oxidation of sulfur(IV) oxides. Atmospheric relevant processes and mechanisms. Chemical Reviews 95, 119-190.
11. Brodzinsky, R.J., Chang, S.G., Markowitz, S.S., Novakov, T., 1980. Kinetics and mechanism for the catalytic oxidation of sulfur dioxide on carbon in aqueous suspensions. Journal of Physical Chemistry 84, 3354-3358.
12. Buxton, G.V., Mc. Gowan, S., Salmon, G.A., Williams, J.E., Wood, N.D., 1996. A study of the spectra and reactivity of oxysulphur - Radical anions involved in the chain oxidation of S(IV): A pulse and γ-radiolysis study. Atmospheric Environment 30, 2483-2493.
13. Chen, L.C., Peoples, S.M., Carthy, J.F., Amdur, M.O., 1989. Copper oxide aerosol: Reaction with sulphur dioxide. Atmospheric Environment 23, 149-154.
14. Coichev, N., van Eldik, R., 1991a. Kinetics and mechanism of the sulfite induced autoxidation of cobalt(II) in aqueous azide medium. Inorganic Chemistry 30, 2375-2380.
15. Coichev, N., van Eldik, R., 1991b. A mechanistic study of the sulfite induced autoxidation of Mn(II) in aqueous azide medium. Inorganica Chimica Acta 185, 69-73.
16. Conklin, M.H., Hoffmann, M.R., 1988. Metal ion-sulphur(IV) chemistry. 2. Kinetic studies of the redox chemistry of copper(II)-sulfur(IV) complexes. Environmental Science and Technology 22, 891-907.
17. 2. 1. The uncatalyzed reaction. Inorganic Chemistry 34, 4543-4553.
18. 2. 2. The manganese(II) catalysed reaction. Inorganic Chemistry 35, 4613-4621.
19. Dogliotti, L., Hayon, E., 1967. Flash photolysis of persulfate ions in aqueous solutions, study of the sulfate and ozonide radical anions. Journal of Physical Chemistry 71, 2511-6.
20. Fuller, E.C., Crist, R.H., 1941. The rate of oxidation of sulfite ions by oxygen. Journal of American Chemical Society 63, 1644-1650.
21. - radicals. Journal of American Chemical Society 94, 47-57.
22. Hobson, D.B., Richardson, P.J., Robinson, P.J., Hewitt, E.A., Smith, I., 1986. Kinetics and mechanism of the cobalt catalysed reaction of oxygen and sulphite at very low concentrations. Journal of Chemical Society Faraday Transactions I 82, 869-881.
23. Hoffmann, M.R., Boyce, S.D., 1983. Catalytic autoxidation of aqueous sulphur dioxide in relationship to atmospheric systems. In: Schwartz, S.E. (Ed.), Trace Atmospheric Constituents: Properties, Transformations and Fates. Wiley, New York, pp. 147-189.
24. 2 Oxidation Mechanisms. Atmospheric Considerations. Butterworth, Boston, pp. 101-172.
25. Jain, U., Sharma, M., Rani, A., Gupta, K.S., 1995. Kinetics and mechanism of copper(II) catalysed autoxidation of aqueous sulphur dioxide in acetate buffers. Indian Journal of Chemistry 34A, 971-975.
26. Karlin, K.D., Gultneh, Y., 1987. Binding and activation of molecular oxygen by copper complexes. Progress in Inorganic Chemistry 35, 238.
27. Kotrly, S., Sucha, L., 1985. Handbook of Chemical Equilibria in Analytical Chemistry. Ellis Horwood, Chichester, U.K.
28. Kraft, J., van Eldik, R., 1989. Kinetics and mechanism of the iron(III) catalysed autoxidation of sulphur(IV) oxides in aqueous solution. 2. Decomposition of transient iron(III)-sulfur(IV) complexes. Inorganic Chemistry 28, 2306-2312.
29. Lunak, S., El-Wakil, A.M., Veprek-Siska, J., 1978. Autoxidation of sulfite catalysed by 3d transition metals and inhibited by 2- propanol: Mechanism of inhibited and induced reactions. Collection of Czechoslovak Chemical Communications 43, 3306-3316.
30. Maahs, H.G., 1982. Sulfur dioxide/water equilibria between 0° and 50°C: An examination of data at low concentrations. In: Schryer, D.R. (Ed.), Heterogeneous Atmospheric Chemistry. American Geophysical Union., Washington, DC, pp. 187-195.
31. Mishra, G.C., Srivastava, R.D., 1976. Homogeneous kinetics of potassium sulfite oxidation. Chemical Engineering Science 31, 969-971.
32. Nriagu, J.O., 1979. Copper in the atmosphere and precipitation. In: Nriagu, J.O. (Ed.), Copper in the Environment Part I Ecological Cycling. Wiley, New York, pp. 43-100.
33. Parks, G.A., 1965. The isoelectric points of solid oxides, solid hydroxides and aqueous hydroxo complex systems. Chemical Reviews 65, 177.
34. Prasad, D.S.N., Rani, A., Gupta, K.S., 1992. Surface catalysed autoxidation of sulfur(IV) in aqueous silica and copper(II) oxide suspensions. Environmental Science and Technology 26, 1361-1368.
35. Prasad, D.S.N., Rani, A., Madnawat, P.V.S., Bhargava, R., Gupta, K.S., 1991. Kinetics of surface catalysed oxidation of sulphur(IV) by dioxygen in aqueous suspensions of cobalt(II) oxide. Journal of Molecular Catalysis 69, 393-405.
36. Rani, A., Prasad, D.S.N., Bhargava, R., Gupta, K.S., 1991. Dynamics of autoxidation of aqueous sulfur dioxide in aqueous suspensions of cadmium oxide. Bulletin of the Chemical Society Japan 64, 1955-1961.
37. Reinders, W., Vles, S.I., 1925. The catalytic oxidation of sulfites. Recueil des Travaux Chemica 44, 249-268.
38. Rollmann, L.D., Chan, S.I., 1971. Electron spin resonance studies of low spin cobalt(II) complexes. Base adducts of cobalt phthalocyanine. Inorganic Chemistry 10, 1978-1982.
39. Schmittkunz, H., 1963. Chemilumineszenz der Sulfito Oxidation. Dissertation naturwissenschaftliche Fakultat, Frankfurt. Cited in Hoffmann, M.R., Jacob, D.J., 1984).
40. Sedlak, D.L., Hoigne, J., 1993. The role of copper and oxalate in the redox cycling of iron in atmospheric waters. Atmospheric Environment 27A, 2173-2185.
41. Siskos, P.A., Peterson, N.C., Huie, R.E., 1984. Kinetics of manganese(III)-S(IV) reaction in aqueous perchloric acid solutions. Inorganic Chemistry 23, 1135-1137.
42. Smith, R.M., Martell, A.E., 1976. Critical Stability Constants, vol. 4. Plenum, New York.
43. Titoff, A., 1903. Beitrage zur kenntnis der negativen katalyse in homogeneous system. Zeitschrift fuer Physikalische Chemie 45, 641-683.
44. von Piechowski, M., Nauser, T., Hoigne, J., Buehler, R.E., 1993. Superoxide decay catalysed by cupric and cuprous ions in aqueous solutions: A pulse radiolysis study for atmospheric chemistry. Berichte der Bunsengesellschaft fuer Physikalische Chemie 97(6), 762-71.
45. 2 production and destruction. Environmental Science and Technology 25, 791-800.
46. Zeck, O.F., Carlyle, D.W., 1974. Electron transfer between sulfur(IV) and chloroiron(III) and chlorocopper(II) ions in aqueous chloride media. Formation of a sulfur dioxide complex with chlorocopper(I). Inorganic Chemistry 13, 34-38.
47. Ziajka, J., Beer, F., Warneck, P., 1994. Iron catalysed oxidation of bisulphite aqueous solution: Evidence for a free radical chain mechanism. Atmospheric Environment 28, 2549-2552.