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Volumn 690, Issue 2, 2005, Pages 276-285

The effect of titanium alkoxides in the synthesis of heterobimetallic complexes by titanocene(III) alkoxide-induced metal-metal bond cleavage of metal carbonyl dimers

Author keywords

Dinuclear metal carbonyls; Heterobimetallic complexes; Ti(III) alkoxides; Ti(III) complex

Indexed keywords

HETEROBIMETALLIC COMPLEXES; ISOCARBONYL BRIDGE; STERIC EFFECTS; TITANIUM ALKOXIDES;

EID: 11844305636     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.09.075     Document Type: Article
Times cited : (8)

References (36)
  • 33
    • 11844249601 scopus 로고    scopus 로고
    • note
    • tBu with metal carbonyl dimers is correlated to the reduction potential of the metal carbonyl dimers measured by cyclic voltammetry. We expected correlation between the oxidation potential of the titanocene(III) alkoxides and their reactivity towards the heterobimetallic complex formation. However, cyclic voltammetric studies of titanocene alkoxides for the determination of their oxidation potentials were hampered; one of the complexes (2a) showed a quasi-reversible redox wave, whereas the others gave complicated voltammograms. To seek for the appropriate conditions to look at the redox waves of all of titanocene(III) compounds is under study.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.