New series of oxalato-gallophosphate structures containing transition metal centers

Chemistry of Materials

Volumn 17, Issue 1, 2005, Pages 74-80

  Chang, Wen Ming ^a   Wang, Sue Lein ^a  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; MAGNETIC SUSCEPTIBILITY; NEGATIVE IONS; PHOSPHATES; SINGLE CRYSTALS; X RAY DIFFRACTION ANALYSIS;

METAL PHOSPHATE CHEMISTRY; ORGANIC-METALLOPHOSPHATE HYBRID FRAMEWORKS; OXALATO-GALLOPHOSPHATE STRUCTURES; SINGLE-CRYSTAL X-RAY DIFFRACTION;

TRANSITION METALS;

CHELATING AGENT; FLUORIDE; GALLIUM; HALOGEN; INORGANIC COMPOUND; MANGANESE; MANGANESE DERIVATIVE; METAL OXIDE; ORGANIC COMPOUND; OXALIC ACID; OXYGEN; PHOSPHATE; TRANSITION ELEMENT; VANADIUM DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL COMPOSITION; CROSS LINKING; CRYSTAL STRUCTURE; HEAT TREATMENT; HYDROLYSIS; MAGNETISM; SYNTHESIS; THERMOGRAVIMETRY; X RAY DIFFRACTION;

EID: 11844262591     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm049411v     Document Type: Article

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17. The reaction mixture was placed in a Teflon-lined Parr bomb (60% filling) and heated at 160 °C for 1-4 and 170 °C for 5 for 3 days. The resulting products were green crystals for 1 and 2 and pale pink crystals for 3, 4, and 5.
18. Compound 4 was first prepared with pip, resulting in a clear structure with ordered template but a yield too poor for further characterizations. Substituting pip with aepip resulted also in structure 4, only that the template molecules, having broken into mpips during reaction, are disordered in the channels and that the yield is sufficient to our experimental need.
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