Synthesis, crystal structure, magnetic susceptibility, and Mössbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound: (H3DETA)[Fe3(C2O4) 2(HPO4)2(PO4)] (DETA = diethylenetriamine)

Chemistry of Materials

Volumn 15, Issue 8, 2003, Pages 1633-1638

  Jiang, Yau Chen ^a   Wang, Sue Lein ^a   Lii, Kwang Hwa ^b,c   Nguyen, Ninh ^d   Ducouret, Annie ^d  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

^b NATIONAL CENTRAL UNIVERSITY   (Taiwan)

^c INSTITUTE OF CHEMISTRY   (Taiwan)

^d UNIVERSITÉ DE CAEN   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; CRYSTAL STRUCTURE; HYDROTHERMAL SYNTHESIS; MAGNETIC SUSCEPTIBILITY; MOSSBAUER SPECTROSCOPY; PHOSPHATES; POWDERS;

HYBRID COMPOUNDS;

CRYSTALLINE MATERIALS;

DIETHYLENETRIAMINE; INORGANIC COMPOUND; IRON DERIVATIVE; LIGAND; ORGANIC COMPOUND; OXALIC ACID DERIVATIVE; PHOSPHATE; TRANSITION ELEMENT;

ARTICLE; CALCULATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; ELECTRIC FIELD; ELECTRON; HEAT TREATMENT; HYBRID; HYDROLYSIS; MAGNETISM; MOSSBAUER SPECTROSCOPY; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037461243     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm021701t     Document Type: Article

References (39)

1. Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. 1999, 38, 2638 and references therein.
2. Férey, G. Chem. Mater. 2001, 13, 3084 and references therein.
3. Lii, K.-H.; Huang, Y.-F. Inorg. Chem. 1999, 38, 1348.
4. Chen, C.-Y.; Lo, F.-R.; Kao, H.-M.; Lii, K.-H. J. Chem. Soc., Chem. Commun. 2000, 1061.
5. Shi, Z.; Feng, S.; Gao, S.; Zhang, L.; Yang, G.; Hua, J. Angew. Chem. Int. Ed. 2000, 39, 2325.
6. Huang, C.-H.; Huang, L.-H.; Lii, K.-H. Inorg. Chem. 2001, 40, 2625.
7. Jiang, Y.-C.; Lai, Y.-C.; Wang, S.-L.; Lii, K.-H. Inorg. Chem. 2001, 40, 5320.
8. Huang, L.-H.; Kao, H.-M.; Lii, K.-H. Inorg. Chem. 2002, 41, 2936.
9. Tsai, Y.-M.; Wang, S.-L.; Huang, C.-H.; Lii, K.-H. Inorg. Chem. 1999, 38, 4183.
10. Do, J.; Bontchev, R. P.; Jacobson, A. J. Inorg. Chem. 2000, 39, 3230.
11. Do, J.; Bontchev, R. P.; Jacobson, A. J. Chem. Mater. 2001, 13, 2601.
12. Lethbridge, Z. A. D.; Hillier, A. D.; Cywinski, R.; Lightfoot, P. J. Chem. Soc., Dalton Trans. 2000, 1595.
13. Lethbridge, Z. A. D.; Tiwary, S. K.; Harrison, A.; Lightfoot, P. J. Chem. Soc., Dalton Trans. 2001, 1904.
14. Lin, H.-M.; Lii, K.-H.; Jiang, Y.-C.; Wang, S.-L. Chem. Mater. 1999, 11, 519.
15. Lethbridge, Z. A. D.; Lightfoot, P. J. Solid State Chem. 1999, 143, 58.
16. Choudhury, A.; Natarajan, S.; Rao, C. N. R. J. Solid State Chem. 1999, 146, 538.
17. Choudhury, A.; Natarajan, S. J. Mater. Chem. 1999, 9, 3113.
18. Choudhury, A.; Natarajan, S.; Rao, C. N. R. Chem. Mater. 1999, 11, 2316.
19. Choudhury, A.; Natarajan, S.; Rao, C. N. R. Chem. Eur. J. 2000, 6, 1168.
20. Chang, W.-J.; Lin, H.-M.; Lii, K.-H. J. Solid State Chem. 2001, 157, 233.
21. Lightfoot, P.; Lethbridge, Z. A. D.; Morris, R. E.; Wragg, D. S. Wright, D. S.; Wright, P. A.; Kvick, Å Vaughan, G. B. M. J. Solid State Chem. 1999, 143, 74.
22. Kedarnath, K.; Choudhury, A.; Natarajan, S. J. Solid State Chem. 2000, 150, 324.
23. Chen, C.-Y.; Chu, P. P.; Lii, K.-H. Chem. Commun. 1999, 1473.
24. Lii, K.-H.; Chen, C.-Y. Inorg. Chem. 2000, 39, 3374.
25. Hung, L.-C.; Kao, H.-M.; Lii, K.-H. Chem. Mater. 2000, 12, 2411.
26. Huang, Y.-F.; Lii, K.-H. J. Chem. Soc., Dalton Trans. 1998, 4085.
27. Natarajan, S. J. Solid State Chem. 1998, 139, 200.
28. Neeraj, S.; Natarajan, S.; Rao, C. N. R. J. Chem. Soc., Dalton Trans. 2001, 289.
29. Sheldrick, G. M. SHELXTL Programs, version 5.1; Bruker AXS GmbH: Karlsruhe, Germany, 1998.
30. 5 trigonal bipyramids and phosphate tetrahedra to generate channels along the b- and c-axis. The oxalate unit shows a bisbidentate coordination to iron atoms.
31. Sheldrick, G. M. SADABS; Siemens Analytical X-ray Instrument Division: Madison, WI, 1995.
32. Brown, I. D.; Altermatt, D. Acta Crystallogr. 1985, B41, 244.
33. Boudin, S.; Lii, K.-H. Inorg. Chem. 1998, 37, 799.
34. Teillet, J.; Varret, F. MOSFIT Program; Université du Maine: France, unpublished.
35. Calage, Y.; Teillet, J.; Varret, F. "EFGDIR" program for lattice EFG tensors; Université du Maine: France, 1982.
36. Ingalls, R. Phys. Rev. 1962, 128, 1155.
37. Sternheimer, R. M. Phys. Rev. 1962, 92, 1460.
38. Gütlich, P.; Link, R.; Trautwein, A. Inorganic Chemistry Concepts, Vol. 3, Mössbauer Spectroscopy and Transition Metal Chemistry; Spinger Verlag: Berlin, 1978.
39. Shannon, R. D. Acta Crystallogr. 1976, A32, 751.