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Volumn 126, Issue 51, 2004, Pages 16712-16713

Efficient photodissociation of O2 from synthetic heme and heme/M (M = Fe, Cu) complexes

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; HEME DERIVATIVE; IRON COMPLEX; OXYGEN DERIVATIVE; COPPER; DRUG DERIVATIVE; FERROUS ION; HEME; OXYGEN;

EID: 11244289417     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja045195f     Document Type: Article
Times cited : (13)

References (34)
  • 1
    • 0004214293 scopus 로고
    • Academic Press: New York
    • James, B. R. The Porphyrins; Academic Press: New York, 1978; Vol. V.
    • (1978) The Porphyrins , vol.5
    • James, B.R.1
  • 24
    • 11244345782 scopus 로고    scopus 로고
    • note
    • An alternative photochemical method was sometimes used for in situ generation of the heme-superoxo/non-heme compound. Prolonged photolysis of the heme/non-heme oxo-bridged compound under 1 atm of dioxygen in THF at 198 K produced UV-visible absorption spectra consistent with complete generation of the heme-superoxo/non-heme compound.
  • 25
    • 11244293167 scopus 로고    scopus 로고
    • note
    • Steady-state UV-vis absorption measurements before and after laser excitation showed no evidence for permanent photochemistry.
  • 27
    • 11244298986 scopus 로고    scopus 로고
    • See Supporting Information
    • See Supporting Information.
  • 28
    • 11244357520 scopus 로고    scopus 로고
    • note
    • -1; see refs 14 and 15.
  • 29
    • 11244353852 scopus 로고    scopus 로고
    • note
    • +, upon warming.
  • 30
    • 11244343659 scopus 로고    scopus 로고
    • note
    • Dioxygen is not known to bind to the non-heme portion of this complex.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.