Measurement of a linear free energy relationship one molecule at a time

Proceedings of the National Academy of Sciences of the United States of America

Volumn 101, Issue 52, 2004, Pages 17920-17923

  Rao, B V ^a   Kwon, K Y ^a   Liu, A ^a   Bartels, L ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Hammett equation; Scanning tunneling microscopy; Single molecule chemistry

Indexed keywords

FUNCTIONAL GROUP; HALOGEN; METHYL GROUP; THIOPHENOL;

ARTICLE; CHEMISTRY; DEHYDROGENATION; ENERGY; HAMMET EQUATION; LINEAR FREE ENERGY; MEASUREMENT; MODEL; MOLECULE; PREDICTION; PRIORITY JOURNAL; QUANTUM MECHANICS; REACTION TIME; SCANNING TUNNELING MICROSCOPY; SINGLE MOLECULE CHEMISTRY;

BENZOIC ACID; BIOPHYSICS; COPPER; HYDROGEN; KINETICS; MICROSCOPY, SCANNING TUNNELING; MODELS, CHEMICAL; PHENOLS; SULFHYDRYL COMPOUNDS; THERMODYNAMICS; TIME FACTORS; WATER;

EID: 11144222709     PISSN: 00278424     EISSN: None     Source Type: Journal    
DOI: 10.1073/pnas.0406223101     Document Type: Article

References (24)

1. Eigler, D. M. & Schweizer, E. K. (1990) Nature 344, 524-526.
2. Shen T. C., Wang, C., Abeln, G. C., Tucker, J. R., Lyding, J. W., Avouris, P. & Walkup, R. E. (1995) Science 268, 1590-1592.
3. Gimzewski, J. K. & Joachim, C. (1999) Science 283, 1683-1688.
4. Stranick, S. J., Kamna, M. M. & Weiss, P. S. (1994) Science 266, 99-102.
5. Bartels, L., Meyer, G., Rieder, K. H., Velic, D., Knoesel, E., Hotzel, A., Wolf, M. & Ertl, G. (1998) Phys. Rev. Lett. 80, 2004-2007.
6. Stipe, B. C., Rezaei, M. A., Ho, W., Gao, S., Persson, M. & Lundqvist, B. I. (1997) Phys. Rev. Lett. 78, 4410-4413.
7. Binnig, G., Rohrer, H., Gerber, C. & Weibel, E. (1983) Phys. Rev. Lett. 50, 120-123.
8. Hla, S. W., Bartels, L., Meyer, G. & Rieder, K. H. (2000) Phys. Rev. Lett. 85, 2777-2780.
9. Stipe, B. C., Rezaei, M. A. & Ho, W. (1998) Science 280, 1732-1735.
10. Komeda, T., Kim, Y., Kawai, M., Persson, B. N. J. & Ueba, H. (2002) Science 295, 2055-2058.
11. Hammett, P. L. (1937) J. Am. Chem. Soc. 59, 96-103.
12. Morrison, R. T. & Boyd, R. N. (1992) Organic Chemistry (Prentice-Hall, Englewood Cliffs, NJ), 6th Ed.
13. Johnson, C. D. (1973) The Hammett Equation (Cambridge Univ. Press, Cambridge, U.K.).
14. Jaffé, H. H. (1953) Chem. Rev. 53, 191-261.
15. Star, A., Man, T. R., Gabriel, J. C. P., Bradley, K. & Gruner, G. (2003) Nano Lett. 3, 1421-1423.
16. Gellman, A. J., Buelow, M. T., Street, S. C. & Morton, T. H. (2000) J. Phys. Chem. A 104, 2476-2485.
17. Meyers, J. M. & Gellman, A. J. (1995) Surf. Sci. 337, 40-50.
18. Rao, B. V., Kwon, K. Y., Liu, A. W. & Bartels, L. (2003) J. Chem. Phys. 119, 10879-10884.
19. Jackson, G. J., Woodruff, D. P., Jones, R. G., Singh, N. K., Chan, A. S. Y., Cowie, B. C. C. & Formoso, V. (2000) Phys. Rev. Lett. 84, 119-122.
20. Carey, F. A. & Sundberg, R. J. (2000) Advanced Organic Chemistry (Kluwer Academic/Plenum, New York), 4th Ed.
21. Schwarzenbach, G. & Rudin, E. (1939) Helv. Chim. Acta 22, 360-376.
22. Lorente, N., Persson, M., Lauhon, L. J. & Ho, W. (2001) Phys. Rev. Lett. 86, 2593-2596.
23. Sautet, P. (1997) Chem. Rev. 97, 1097-1116.
24. Pascual, J. I., Lorente, N., Song, Z., Conrad, H. & Rust, H. P. (2003) Nature 423, 525-528.