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Volumn 121, Issue 23, 2004, Pages 12074-12084

Nonanalytic curvature contributions to solvation free energies: Influence of drying

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; COLLOIDS; FLUID DYNAMICS; GASES; SPHERES; SURFACE CHEMISTRY;

EID: 11044230865     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1819316     Document Type: Article
Times cited : (51)

References (48)
  • 2
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    • H. Reiss, H. L. Frisch, E. Helfand, and J. L. Lebowitz, J. Chem. Phys. 32, 119 (1960); H. Reiss, Adv. Chem. Phys. 9. 1 (1965).
    • (1965) Adv. Chem. Phys. , vol.9 , pp. 1
    • Reiss, H.1
  • 5
    • 0001177288 scopus 로고
    • For example, D. E. Sullivan, D. Levesque, and J. J. Weiss, J. Chem. Phys. 72, 1170 (1980); P. Tarazona and R. Evans, Mol. Phys. 52, 847 (1984); F. van Swol and J. R. Henderson, Phys. Rev. Lett. 53, 1376 (1984); J. R. Henderson and F. van Swol, Mol. Phys. 56, 1313 (1985).
    • (1980) J. Chem. Phys. , vol.72 , pp. 1170
    • Sullivan, D.E.1    Levesque, D.2    Weiss, J.J.3
  • 6
    • 20544466000 scopus 로고
    • For example, D. E. Sullivan, D. Levesque, and J. J. Weiss, J. Chem. Phys. 72, 1170 (1980); P. Tarazona and R. Evans, Mol. Phys. 52, 847 (1984); F. van Swol and J. R. Henderson, Phys. Rev. Lett. 53, 1376 (1984); J. R. Henderson and F. van Swol, Mol. Phys. 56, 1313 (1985).
    • (1984) Mol. Phys. , vol.52 , pp. 847
    • Tarazona, P.1    Evans, R.2
  • 7
    • 4243415684 scopus 로고
    • For example, D. E. Sullivan, D. Levesque, and J. J. Weiss, J. Chem. Phys. 72, 1170 (1980); P. Tarazona and R. Evans, Mol. Phys. 52, 847 (1984); F. van Swol and J. R. Henderson, Phys. Rev. Lett. 53, 1376 (1984); J. R. Henderson and F. van Swol, Mol. Phys. 56, 1313 (1985).
    • (1984) Phys. Rev. Lett. , vol.53 , pp. 1376
    • Van Swol, F.1    Henderson, J.R.2
  • 8
    • 11544335707 scopus 로고
    • For example, D. E. Sullivan, D. Levesque, and J. J. Weiss, J. Chem. Phys. 72, 1170 (1980); P. Tarazona and R. Evans, Mol. Phys. 52, 847 (1984); F. van Swol and J. R. Henderson, Phys. Rev. Lett. 53, 1376 (1984); J. R. Henderson and F. van Swol, Mol. Phys. 56, 1313 (1985).
    • (1985) Mol. Phys. , vol.56 , pp. 1313
    • Henderson, J.R.1    Van Swol, F.2
  • 17
    • 0038507633 scopus 로고    scopus 로고
    • R. Evans, R. Roth, and P. Bryk, Europhys. Lett. 62, 815 (2003). Note that the coefficient ā(T) in this paper is identical to ξa (T) in the present.
    • (2003) Europhys. Lett. , vol.62 , pp. 815
    • Evans, R.1    Roth, R.2    Bryk, P.3
  • 19
    • 0032045753 scopus 로고    scopus 로고
    • and references therein
    • T. Bieker and S. Dietrich, Physica A 252, 85 (1998), and references therein.
    • (1998) Physica A , vol.252 , pp. 85
    • Bieker, T.1    Dietrich, S.2
  • 23
    • 0009601877 scopus 로고
    • An earlier attempt at proving the curvature expansion of the free energy is analytic in scaled particle theory, by D. M. Tully-Smith and H. Reiss, J. Chem. Phys. 53, 4015 (1970), is less convincing than Ref. 10 and is in fact violated by dispersion interaction and wetting/drying nonanalyticity.
    • (1970) J. Chem. Phys. , vol.53 , pp. 4015
    • Tully-Smith, D.M.1    Reiss, H.2
  • 26
    • 11044237830 scopus 로고    scopus 로고
    • note
    • b(μ)] is finite provided δμ0.<0.
  • 28
    • 11044222594 scopus 로고    scopus 로고
    • note
    • BT/ε = 1.
  • 30
    • 0002245425 scopus 로고
    • edited by D. Henderson (Marcel Dekker, New York)
    • For a review see R. Evans, in Fundamentals of Inhomogeneous Fluids, edited by D. Henderson (Marcel Dekker, New York, 1992). p. 85.
    • (1992) Fundamentals of Inhomogeneous Fluids , pp. 85
    • Evans, R.1
  • 33
    • 0002458126 scopus 로고
    • D. S. Fisher and D. A. Huse, Phys. Rev. B 32, 247 (1985). For a general review of wetting see S. Dietrich, in Phase Transitions and Critical Phenomena, edited by C. Domb and J. L. Lebowitz (Academic, London, 1988), Vol. 12, p. 1.
    • (1985) Phys. Rev. B , vol.32 , pp. 247
    • Fisher, D.S.1    Huse, D.A.2
  • 34
    • 0001786512 scopus 로고
    • edited by C. Domb and J. L. Lebowitz (Academic, London)
    • D. S. Fisher and D. A. Huse, Phys. Rev. B 32, 247 (1985). For a general review of wetting see S. Dietrich, in Phase Transitions and Critical Phenomena, edited by C. Domb and J. L. Lebowitz (Academic, London, 1988), Vol. 12, p. 1.
    • (1988) Phase Transitions and Critical Phenomena , vol.12 , pp. 1
    • Dietrich, S.1
  • 37
    • 11044220537 scopus 로고    scopus 로고
    • note
    • w(∞,μ)] w.r.t. L just as one can obtain Γ(R,μ) by integrating the r.h.s. of Eq. (9) w.r.t. R.
  • 41
    • 11044233543 scopus 로고    scopus 로고
    • note
    • x/(RΔρ).
  • 42
    • 11544335707 scopus 로고
    • See, e.g., J. R. Henderson and F. van Swol, Mol. Phys. 56, 1313 (1985); A. O. Parry and R. Evans, ibid. 78, 1527 (1993), and references therein.
    • (1985) Mol. Phys. , vol.56 , pp. 1313
    • Henderson, J.R.1    Van Swol, F.2
  • 43
    • 0008521998 scopus 로고
    • and references therein
    • See, e.g., J. R. Henderson and F. van Swol, Mol. Phys. 56, 1313 (1985); A. O. Parry and R. Evans, ibid. 78, 1527 (1993), and references therein.
    • (1993) Mol. Phys. , vol.78 , pp. 1527
    • Parry, A.O.1    Evans, R.2
  • 48
    • 11044221051 scopus 로고    scopus 로고
    • note
    • ex. This would be weaker than the R In R contribution associated with complete drying - see present Eq. (13).


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