Cyclometalation and solvent deoxygenation during reduction of a homoleptic Th(OAr)4 complex: Serendipitous formation of a terminally bonded Th-OH function

Organometallics

Volumn 23, Issue 26, 2004, Pages 6248-6252

  Korobkov, Ilia ^a   Arunachalampillai, Athimoolan ^a   Gambarotta, Sandro ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; OXIDATION; PROBLEM SOLVING; REDUCTION; STOICHIOMETRY; URANIUM;

REACTION CONDITIONS; SOLVENT CLEAVAGE; SOLVENT DEOXYGENATION;

SOLVENTS;

EID: 11044227135     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049369d     Document Type: Article

References (39)

1. Edelmann, F. T. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, U.K., 1995.
2. (a) Parry, J. S.; Cloke, G. F. N.; Cole, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867 and references cited therein.
3. (b) Kannellakopulos, B.; Dornberger, E.; Baumgaertner, F. In. Nucl. Chem. Lett 1974, 10, 155.
4. (c) Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Zhang, H. J. Chem. Soc. Chem. Commun. 1986, 15, 1148.
5. (d) Spirlet, M. R.; Rebizant, J.; Goffart, J. Acta Crystallogr., Sect. B 1982, 38, 2400.
6. Bratsch, S. G.; Lagowski, J. J. J. Phys Chem. 1986, 90, 307.
7. For a recent review on U(III) chemistry, see for example: Korobkov, I.; Gambarotta, S. Prog. Inorg. Chem., in press.
8. See for example: Gambarotta, S.; Scott, J. Angew. Chem., Int. Ed. 2003, 42, and references cited therein.
9. (a) Warner, B. P.; Scott, B. L.; Burns, C. J. Angew. Chem., Int. Ed. 1998, 37, 959.
10. (b) Fagan, P. J.; Manriquez, J. M.; Marks, T. J.; Day, C. S. S.; Vollmer, H.; Day, V. W. Organometallics 1982, 1, 170.
11. (c) Diaconescu, P.; Arnold, P. L.; Baker, T.; Mindiola, D.; Cummins, C. C. J. Am. Chem. Soc. 2000, 12, 6108.
12. (d) Evans, W. J.; Davis, B. L. Chem. Rev. 2002, 102, 2119.
13. Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2003, 42, 814.
14. (a) Korobkov, I.; Gambarotta, S. Organometallics, in press. Korobkov, I.; Gambarotta, S. Manuscript in preparation.
15. Korobkov, I.; Gambarotta, S. Angew. Chem., Int. Ed. 2003, 42, 4958.
16. See for example: (a) Yu, J. S.; Ankianiec, B. C.; Nguyen, M. T.; Rothwell, I. P. J. Am. Chem. Soc. 1992, 114, 1927.
17. (b) Hill, J. E.; Balaich, G. J.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1993, 12, 2911.
18. (c) Hill, J. E.; Fanwick, P. E.; Rothwell, I. P. Polyhedron 1990, 9, 1617.
19. (d) Kerschner, J. L.; Fanwick, P. E.; Rothwell, I. P.; Huffman, J. C. Inorg. Chem. 1989, 28, 780.
20. (e) Rothwell, I. P. Acc. Chem. Res. 1968, 21, 153.
21. Korobkov, I.; Gambarotta, S. Unpublished procedure.
22. Blessing, R. Acta Crystallogr. 1995, A51, 33.
23. Blake, P. C.; Lappert, M. F.; Taylor, R. G.; Atwood, J. L.; Zhang, H. Inorg. Chim. Acta 1987, 739, 13.
24. Berg, J. M.; Clarck, D. L.; Huffmann, J. C.; Morris, D. E.; Sattelberger, A. P.; Streib, W. E.; Van der Sluys, W. G.; Watkin, J. G. J. Am. Chem. Soc. 1992, 114, 10811.
25. See for example: (a) Steffey, B. D.; Chamberlain, L. R.; Chesnut, R. W.; Chebi, D. E.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1989, 8, 1419.
26. (b) Chesnut, R. W.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P.; Huffman, J. C. Polyhedron 1990, 9, 1051.
27. (c) Kerschner, J. L.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1989, 8, 1431.
28. (d) Chesnut, R. W.; Gayatry, G. J.; Yu, J. S.; Fanwick, P. E.; Rothwell, I. P. Organomttallics 1991, 10, 321.
29. Steffey, B. D.; Chamberlain, L. R.; Chesnut, R. W.; Chebi, D. E.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1989, 8, 1419.
30. See for example: (a) Guan, J.; Dubé, T.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 4820.
31. (b) Schumann, H.; Palamidis, E.; Loebel, J.; J. Organomet. Chem. 1990, 384, C49.
32. (c) Pasynkiewicz, S.; Buchowicz, W.; Pietrzykowski, A. J. Organomet. Chem. 1997, 531, 121.
33. (d) Ekkehard, B. J. Organomet. Chem. 1985, 284, 149.
34. (e) Evans, W. J.; Allen, N. T.; Ziller, J. W. J. Am. Chem. Soc. 2001, 123, 7927.
35. Dubé, T.; Gambarotta, S.; Yap, G. P. A. Organometallics 1998, 17, 3967.
36. (a) Roussel, P.; Boaretto, R.; Kingsley, A J.; Alcock, N. W.; Scott, P. Dalton 2002, 1423.
37. (b) Karmazarin, L.; Mazzanti, M.; Pecaut, J. Inorg. Chem. 2003, 42, 5900.
38. (c) Ariyaratne, K. A. N. S.; Cramer, R. E.; Jamieson, G. B.; Gilje, J. W. J. Organomet. Chem. 2004, 689, 2029.
39. Lukens, W. W.; Beshouri, S. M.: Blosch, L. L.; Andersen, R. A. J. Am. Chem. Soc. 1996, 118, 901.