Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge

Chemical Geology

Volumn 213, Issue 1-3, 2004, Pages 71-87

  Wilke, Max ^a   Partzsch, Georg M ^b   Bernhardt, Ralf ^b   Lattard, Dominique ^b  

^a UNIVERSITY OF POTSDAM   (Germany)

^b UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Fe oxidation state; M ssbauer spectroscopy; XANES

Indexed keywords

BASALT; GLASS; IRON; REDOX CONDITIONS; SILICATE MELT; XANES SPECTROSCOPY;

EID: 10944246642     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2004.08.034     Document Type: Article

References (52)

1. H.V. Alberto J.L. Pinto da Cunha B.O. Mysen J.M. Gil N. Ayres de Campos Analysis of Mössbauer spectra of silicate glasses using a two-dimensional Gaussian distribution of hyperfine parameters J. Non-Cryst. solids 194 1996 48-57
2. K. Attenkofer U. Brüggmann N. Haack M. Herrmann P. Kappen E. Welter Improvements for absorption spectroscopy at beamlines A1, E4, X1 HASYLAB Annual Report 2000 63-68
3. S. Bajt S.R. Sutton J.S. Delany X-ray microprobe analysis of iron oxidation states in silicates and oxides using X-ray absorption near edge structure (XANES) Geochim. Cosmochim. Acta 58 1994 5209-5214
4. A.J. Berry H.S.C. O'Neill K.D. Jayasuriya S.J. Cambell G.J. Foran XANES calibrations for the oxidation state of iron in a silicate glass Am. Mineral. 88 2003 976-977
5. M. Bonnin-Mosbah A.S. Simionovici N. Métrich J.-P. Duraud D. Massare P. Dillmann Iron oxidation state in silicate glass fragments and glass inclusions with a XANES microprobe J. Non-Cryst. solids 288 2001 103-113
6. G.E. Brown Jr. F. Farges G. Calas X-ray scattering and X-ray spectroscopy studies of silicate melts. In: J.F. Stebbins P.F. McMillan D.B. Dingwell (Eds.). Structure, Dynamics and Properties of Silicate Melts Reviews in Mineralogy vol. 32 1995 317-410
7. D.J.M. Burkhard Iron-bearing silicate glasses at ambient conditions J. Non-Cryst. solids 275 2000 175-188
8. G. Calas J. Petiau Coordination of iron in oxide glasses through high-resolution Kedge spectra: Information from the pre-edge Solid State Commun. 48 1983 625-629
9. P. Deines R.H. Nafziger G.C. Ulmer E. Woermann Temperature-oxygen fugacity tables for selected gas mixtures in the system C-H-O at one atmosphere total pressure Bull. Earth Miner. Sci. Exp. Stn., Pennsylvania State University 1974 88
10. 3+/-Fe in amphibole by X-ray absorption near edge structure (XANES) spectroscopy. In: M.D. Dyar C. McCammon M.W. Schaefer (Eds.). Mineral Spectroscopy: A Tribute to Roger G. Burns 1996 The Geochemical Society Houston 165-171
11. D.B. Dingwell Redox viscometry of some Fe-bearing silicate melts Am. Mineral. 76 1991 1560-1562
12. D.B. Dingwell Relaxation in silicate melts: Some applications. In: J.F. Stebbins P.F. McMillan D.B. Dingwell (Eds.). Structure, Dynamics and Properties of Silicate Melts Reviews in Mineralogy vol. 32 1995 21-66
13. G. Dräger R. Frahm G. Materlik O. Brümmer On the multipole character of the X-ray transition in the pre-edge structure of Fe K absorption spectra Phys. Status Solidi, B Basic Res. 146 1988 287-294
14. 3+ distribution in oxidized olivine: A synchrotron micro-XANES study Am. Mineral. 83 1998 1361-1365
15. M.D. Dyar J.S. Delaney S.R. Sutton Fe XANES spectra of iron-rich micas Eur. J. Mineral. 13 2001 1079-1098
16. R.F. Fudali Oxygen fugacities of basaltic and andesitic magmas Geochim. Cosmochim. Acta 29 1965 1063-1075
17. 2 on the ferric-ferrous ratio of silicic melts Chem. Geol. 174 2001 255-273
18. L. Galoisy G. Callas M.A. Arrio High-resolution XANES spectra of iron in minerals and glasses: Structural information from the pre-edge region Chem. Geol. 174 2001 307-319
19. T.L. Grove Use of FePt alloys to eliminate the iron loss problem in 1 atmosphere gas mixing experiments: Theoretical and practical considerations Contrib. Mineral. Petrol. 78 1981 298-304
20. B. Hannoyer M. Lenglet J. Dürr R. Cortes Spectroscopic evidence of octhedral iron (III) in soda-lime silicate glasses J. Non-Cryst. solids 151 1992 209-216
21. 2 Physica. B 208-209 1995 604-606
22. Ö. Helgason S. Steinthorsson S. Morup Rates of redox reactions in basaltic melts determined by Mössbauer spectroscopy Hyperfine Interact. 70 1992 985-988
23. K.D. Jayasuriya H.St.C. O'Neill A.J. Berry S.J. Campbell A Mössbauer study of the oxidation state of iron in silicate melts Am. Mineral. 2004 (in press)
24. W.D. Johnston Oxidation-reduction equilibria in iron-containing glass J. Am. Ceram. Soc. 47 1964 198-201
25. A. Kilinc I.S.E. Carmichael M.L. Rivers R.O. Sack The ferric-ferrous ratios of natural silicate liquids equilibrated in air Contrib. Mineral. Petrol. 83 1983 136-140
26. D.D. Klemm R. Snethlage Üeber die Anwendungsmöglichkeiten und Anwendungsgrenzen von Festkörperpuffern zur Einstellung von Sauerstoffpartialdrucken Neues Jahrb. Mineral., Monatsh. 1975 1975 215-228
27. M.O. Krause J.H. Oliver Natural widths of atomic K and L levels, K alpha X-ray lines and several KLL auger lines J. Phys. Chem. Ref. Data 8 1979 329-338
28. 3 and the effect of composition, temperature, oxygen fugacity and pressure on their redox states Contrib. Mineral. Petrol. 108 1991 82-92
29. G. Moore K. Righter I.S.E. Carmichael The effect of dissolved water on the oxidation state of iron in natural silicate liquids Contrib. Mineral. Petrol. 120 1995 170-179
30. 2-Fe-O: Relationships between redox equilibria, melt structure and liquid phase equilibria Am. Mineral. 70 1985 317-331
31. 57Fe Mössbauer resonant absorption methods Contrib. Mineral. Petrol. 90 1985 101-106
32. 4 Am. Mineral. 72 1987 280-291
33. 2 O-CuO from emf measurements Am. Mineral. 73 1988 470-486
34. G. Ottonello R. Moretti L. Marini M.V. Zuccolini Oxidation state of iron in silicate glasses and melts: A thermochemical model Chem. Geol. 174 2001 157-179
35. 2+ in synthetic basaltic glass: A test of empirical fO2 equations under superliquidus and subliquidus conditions Contrib. Mineral. Petrol. 147 2004 565-580
36. A. Paul Oxidation-reduction equilibrium in glass J. Non-Cryst. solids 123 1990 354-362
37. D.C. Presnall N.L. Brenner A method for studying iron silicate liquids under reducing conditions with negligible iron loss Geochim. Cosmochim. Acta 38 1974 1785-1788
38. 57Fe Mössbauer spectroscopy of tektites Phys. Chem. Miner. 26 1999 530-538
39. 2 glass. New insights into site significance in silicate glasses Europhys. Lett. 49 2000 597-602
40. R.O. Sack I.S.E. Carmichael M. Rivers M.S. Ghiorso Ferric-ferrous equilibria in natural silicate liquids at 1 bar Contrib. Mineral. Petrol. 75 1980 369-376
41. R. Schmid M. Wilke R. Oberhänsli K. Janssens G. Falkenberg L. Franz A. Gaab Micro-XANES determination of ferric iron and its application in thermobarometry Lithos 70 2003 381-392
42. U.C. Srivastava H.L. Nigam X-ray absorption edge spectrometry (XAES) as applied to coordination chemistry Coord. Chem. Rev. 9 1973 275-310
43. P. Thy G.E. Lofgren Experimental constraints on the low-pressure evolution of transitional and mildly alkalic basalts: The effect of Fe-Ti oxide minerals and the origin of basaltic andesites Contrib. Mineral. Petrol. 116 1994 340-351
44. M.J. Toplis M.R. Carroll An experimental study of the influence of oxygen fugacity on Fe-Ti oxide stability, phase relations, and mineral-melt equilibria in ferro-basaltic systems J. Petrol. 36 1995 1137-1170
45. 2,3-edge electron energy-loss near edge structure spectroscopy Phys. Chem. Miner. 25 1998 323-327
46. 57Fe Moessbauer study Phys. Chem. Miner. 12 1985 65-76
47. 2+ in molten alkali silicates Nature 350 1988 251-253
48. T.E. Westre P. Kennepohl J.G. DeWitt B. Hedman K.O. Hodgson E.I. Solomon A multiplet analysis of Fe K-edge 1s-3d pre-edge features of iron complexes J. Am. Chem. Soc. 119 1997 6297-6314
49. E.H. White H.A. McKinstry Chemical effect on X-ray absorption-edge fine structure Adv. X-Ray Anal. 9 1966 376-392
50. M. Wilke F. Farges P.-E. Petit G.E. Brown Jr. F. Martin Oxidation state and coordination of Fe in minerals: An Fe K-XANES spectroscopic study Am. Mineral. 86 2001 714-730
51. M. Wilke H. Behrens D.J.M. Burkhard S. Rossano The oxidation state of iron in silicic melt at 500 MPa water pressure Chem. Geol. 189 2002 55-67
52. A.D. Wilson A new method for the determination of ferrous iron in rocks and minerals Bull. Geol. Surv. G. B. 9 1955 56-58