A Mössbauer study of the oxidation state of Fe in silicate melts

American Mineralogist

Volumn 89, Issue 11-12, 2004, Pages 1597-1609

  Jayasuriya, Kasthuri D ^a,b   O'Neill, Hugh St C ^c   Berry, Andrew J ^c   Campbell, Stewart J ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

^b UNIVERSITY OF KELANIYA   (Sri Lanka)

^c AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EUTECTICS; FELDSPAR; GLASS; HEMATITE; MOLYBDENUM METALLOGRAPHY; SILICATES; STOICHIOMETRY; UNCERTAINTY ANALYSIS;

EUTECTIC COMPOSITION; FITTING PROCEDURE; NEGATIVE VALUES; OXIDATION STATE; OXYGEN FUGACITY; SSBAUER SPECTROSCOPIES; THEORETICAL EXPRESSION; THEORETICAL VALUES;

IRON METALLOGRAPHY;

IRON; MINERALOGY; MOSSBAUER SPECTROSCOPY; REDOX POTENTIAL; SILICATE MELT;

EID: 3543115495     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2004-11-1203     Document Type: Article

References (45)

1. Barin, I., Sauert, F., Schultze-Rhonhof, E., and Sheng, W.S. (1989) Thermochemical data of pure substances, part I and part II, 1-1739 p. VCH Verlagsgesellschaft, Weinheim, Germany.
2. 2. Geochimica et Cosmochimica Acta, 55, 3191-3208.
3. Berry, A.J., O'Neill, H.St.C., Jayasuriya, K.D., Campbell, S.J., and Foran, G.J. (2003) XANES calibrations for the oxidation state of iron in a silicate glass. American Mineralogist, 88, 967-977.
4. Borisov, A. and Jones, J.H. (1999) An evaluation of Re, as an alternative to Pt, for the 1 bar loop technique: An experimental study at 1400 °C. American Mineralogist, 84, 1528-1534.
5. 2+ in magmas to their composition, oxygen fugacity, and temperature. Geokhimiya, 6, 892-g897.
6. 57Fe-bearing oxide, silicate and aluminosilicate minerals. In L.M. Coyne, S.W.S. McKeever, and D.F. Blake, Eds., Spectroscopic Characterisation of Minerals and their Surfaces, ACS Symposium Series, 415, p. 262-283. American Chemical Society, Washington, D.C.
7. Campbell, S.J., and Aubertin, F. (1989) Evaluation of distributed hyperfine parameters. In G.J.Long and F. Grandjean, Eds., Mössbauer Spectroscopy Applied to Inorganic Chemistry, vol. 3, p. 183-242. Plenum Press, New York.
8. Carmichael, I. (1991) The redox states of basic and silicic, magmas - a reflection of their source regions. Contributions to Mineralogy and Petrology, 106, 129-141.
9. Christie, D.M., Carmichael, I.S.E., and Langmuir, C.H. (1986) Oxidation states of mid-ocean ridge basalt glasses. Earth and Planetary Science Letters, 79, 397-411.
10. 2+ ratios: A Mössbauer and wet-chemical study. American Mineralogist, 72, 792-800.
11. Fudali, R.F. (1965) Oxygen fugacities of basaltic and andesitic magmas. Geochimica et Cosmochimica Acta, 29, 1063-1075.
12. O2 on the ferric-ferrous ratio of silicic, melts. Chemical Geology, 174, 255-273.
13. Helgason, Ö., Steinthorsson S., and Mørup, S. (1992) Rates of redox reactions in basaltic melts determined by Mössbauer spectroscopy. Hyperfine Interactions, 70, 985-988.
14. Jing, J., Campbell, S.J., and Pellegrino, J. (1992) A stand-alone Mössbauer spectrometer based on the MC 68008 microprocessor. Measurement Science and Technology, 3, 80-84.
15. Johnston, W.D. (1964) Oxidation-reduction equilibria in iron-containing glass. Journal of the American Ceramic Society, 47, 198-201.
16. Kennedy, G.C. (1948) Equilibrium between volatiles and iron oxides in igneous rocks. American Journal of Science, 246, 529-549.
17. Kilinc, A., Carmichael, I.S.E., Rivers, M.L., and Sack, R.O. (1983) The ferric-ferrous ratio of natural silicate liquids equilibrated in air. Contributions to Mineralogy and Petrology, 83, 136-140.
18. Kress, V.C. and Carmichael, I.S.E. (1988) Stoichiometry of the iron oxidation reaction in silicate melts. American Mineralogist, 73, 1267-1274.
19. Kress, V.C. and Carmichael, I.S.E. (1989) The lime-iron-silicate melt system: Redox and volume systematics. Geochimica et Cosmochimica Acta, 53, 2883-2892.
20. 3 and the effect of composition, temperature, oxygen fugacity and pressure on their redox states. Contributions to Mineralogy and Petrology, 108, 82-92.
21. 2 melts: Effects of analytical techniques on derived partial molar volumes. Geochimica, et Cosmochimica Acta, 53, 2195-2204.
22. Le Caër, G. and Dubois, J.M. (1979) Evaluation of hyperfine parameter distributions from overlapped Mössbauer spectra of amorphous alloys. Journal of Physics E, 12, 1083-90.
23. Moore, G., Righter, K., and Carmichael, I.S.E. (1995) The effect of dissolved water on the oxidation state of iron in natural silicate liquids. Contributions to Mineralogy and Petrology, 120, 170-179.
24. Murad, E. and Cashion J. (2004) Mössbauer spectroscopy of environmental materials and their industrial utilization. Kluwer Academic Publishers, Boston, pp 417.
25. Mysen, B.O. (1992) Iron and phosphorus in calcium silicate quenched melts. Chemical Geology, 98, 175-202.
26. 57Fe Mössbauer resonant absorption methods. Contributions to Mineralogy and Petrology, 90, 101-106.
27. 2-Fe-O: relationships between redox equilibria, melt structure and liquidus phase equilibria. American Mineralogist, 70, 317-331.
28. Nikolaev, G.S., Borisov, A.A., and Ariskin A. A. (1996) Calculation offerric-ferrous ratio in magmatic melts: testing and additional calibration of empirical equations for various magmatic series. Geochemistry International, 34, 641-649.
29. 3 in silicate melts. Chemical Geology, 186, 151-158.
30. O'Neill, H.S.C. and Mavrogenes, J.A. (2002) The sulfide capacity and the sulfur content at sulfide saturation of silicate melts at 1400 °C and 1 bar. Journal of Petrology, 43, 1049-1087.
31. Ottonello, G., Moretti, R., Marini, L., and Vetuschi Zuccolini, M. (2001) Oxidation state of iron in silicate glasses and melts: A thermochemical model. Chemical Geology, 174, 157-179.
32. Paul, A. and Douglas, R.W. (1965) Ferrous-ferric equilibrium in binary alkali silicate glasses. Physics and Chemistry of Glasses, 6, 207-211.
33. 3 at oxygen pressures up to 45 atmospheres. Journal of Physical Chemistry, 64, 1451-1453.
34. Popper, K. (1963) Conjectures and refutations, 431 p. Routledge, Kegan Paul, London.
35. 5 Pascals) Pressure and at Higher Temperatures, 461 p. United States Government Printing Office, Washington.
36. 57Fe Mössbauer spectroscopy of tektites. Physics and Chemistry of Minerals, 26, 530-538.
37. Sack, R.O., Carmichael, I.S.E., Rivers, M., and Ghiorso, M.S. (1980) Ferric-ferrous equilibria in natural silicate liquids at 1 bar. Contributions to Mineralogy and Petrology, 75, 369-376.
38. Thornber, C.R., Roeder, P.L., and Foster, J.R. (1980) The effect of composition on the ferric-ferrous ratio in basaltic liquids at atmospheric pressure. Geochimica et Cosmochimica Acta, 44, 525-532.
39. Toplis, M.J. and Corgne, A. (2002). An experimental study of element partitioning between magnetite, clinopyroxene and iron-bearing silicate liquids with particular emphasis on vanadium. Contributions to Mineralogy and Petrology, 144, 22-37.
40. Toplis, M.J., Dingwell, D.B., and Libourel, G. (1994) The effect of phosphorus on the iron redox ratio, viscosity, and density of an evolved ferro-basalt. Contributions to Mineralogy and Petrology, 117, 293-304.
41. 57Fe Mössbauer study. Physics and Chemistry of Minerals, 12, 65-76.
42. 57 in ferrichrome A. Physical Review, 152, 345-357.
43. Wilke, M., Behrens H., Burkhard, D.J.M., Rossano, S. (2002) The oxidation state of iron in silicic melt at 500 MPa water pressure. Chemical Geology, 189, 55-67.
44. Wood, B.J. and Nicholls, J. (1978) The thermodynamic properties of reciprocal solid solutions. Contributions to Mineralogy and Petrology, 66, 389-400.
45. Wriedt, H.A. (1991) The Fe-O (iron-oxygen) system. Journal of Phase Equilibria, 12, 170-200.