Synthesis and characterization of [W(NC4Me4) 2Cl2] and [W(NC4Me4) 2(CH3)2], the first azametallocene tungsten complexes with pyrrolyl ligands. Electronic structure and bonding of tungsten bispyrrolyl complexes

Inorganica Chimica Acta

Volumn 356, Issue , 2003, Pages 249-258

  Ascenso, José R ^a   Dias, Alberto R ^a   Ferreira, André P ^a   Galvão, Ana Castro ^a   Salema, Margarida S ^a   Veiros, Luis F ^a  

^a INSTITUTO SUPERIOR TÉCNICO   (Portugal)

Author keywords

Azametallocenes; DFT calculations; NMR; Pyrrolyl complexes; Synthesis; Tungsten

Indexed keywords

CHELATION; ELECTRONIC STRUCTURE; ISOMERS; LIGANDS; MASS SPECTROMETRY; MOLECULAR ORBITALS; NUCLEAR MAGNETIC RESONANCE; SYNTHESIS (CHEMICAL); TUNGSTEN;

AZAMETALLOCENES; COORDINATION MODES; DFT CALCULATION; DICHLORO COMPLEXES; MOLECULAR ORBITAL STUDIES; PYRROLYL; RELATIVE STABILITIES; SYNTHESIS AND CHARACTERIZATIONS;

TUNGSTEN COMPOUNDS;

LIGAND; NITROGEN; PYRROLE DERIVATIVE; TUNGSTEN DERIVATIVE;

ANALYTIC METHOD; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL PARAMETERS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ISOMERISM; MASS SPECTROMETRY; MOLECULAR INTERACTION; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM YIELD; STEREOCHEMISTRY; SYNTHESIS;

EID: 1042275910     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(03)00401-8     Document Type: Article

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