Regioselective hydrogenation of olefinic or carbonyl functional group of α,β-unsaturated substrates by iridium cycloocta-1,5-diene precursor stabilized with hydro(pyrazolyl)borate ligands

Journal of Molecular Catalysis A: Chemical

Volumn 207, Issue 2, 2004, Pages 117-122

  López Linares, Francisco ^a   Agrifoglio, Giuseppe ^a   Labrador, Ángel ^a   Karam, Arquímedes ^a  

^a INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

Author keywords

Hydro(pyrazolyl)borate; Hydrogenation; Iridium; , Unsaturated substrates

Indexed keywords

ALCOHOLS; HYDROGENATION; OLEFINS; SUBSTRATES;

LIGANDS; REGIOSELECTIVITY;

ALDEHYDES;

ALDEHYDE; ALKADIENE; ALKENE; BORIC ACID; CARBONYL DERIVATIVE; DIHYDROBIS(3,4,5 TRIMETHYLPYRAZOLYL)BORATE; HYDROTRIS(3,4,5 TRIMETHYLPYRAZOLYL)BORATE; HYDROTRIS(3,5 DIMETHYLPYRAZOLYL)BORATE; HYDROTRIS(PYRAZOLYL)BORATE; IRIDIUM; LIGAND; PYRAZOLE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; HYDROGENATION;

EID: 1042264283     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(03)00492-8     Document Type: Article

References (40)

1. Trofimenko S. Acc. Chem. Res. 4:1971;17.
2. Trofimenko S. Chem. Rev. 72:1972;497.
3. Trofimenko S. Chem. Rev. 93:1993;943.
4. Kitajima N., Tolman W.B. Prog. Inorg. Chem. 43:1995;419.
5. S. Trofimenko, Scorpionates: the Coordination Chemistry of Polypyrazolylborate Ligands, Imperial College Press, 1999.
6. Gemel C., Trimmel G., Slugovc C., Kremel S., Mereiter K., Schmid R., Kirchner K. Organometallics. 15:1996;3998.
7. Slugovc C., Mereiter K., Zobetz E., Schmid R., Kirchner K. Organometallics. 15:1996;5275.
8. Slugovc C., Schmid R., Kirchner K. Coord. Chem. Rev. 185/186:1999;109.
9. Gorun S.M., Hu Z., Stibrany R.T., Carpenter G. Inorg. Chim. Acta. 297:2000;383.
10. Slugovc C., Padilla-Martínez I., Sirol S., Carmona E. Coor. Chem. Rev. 213:2001;129.
11. Scheuer S., Fischer J., Kress J. Organometallics. 14:1995;2627.
12. Long D.P., Bianconi P.A. J. Am. Chem. Soc. 118:1996;12453.
13. Katayama H., Yamamura K., Miyaki Y., Ozawa F. Organometallics. 16:1997;4497.
14. Katayama H., Yoshida T., Ozawa F. J. Organomet. Chem. 562:1998;203.
15. Nakazawa H., Ikai S., Imaoka K., Kai Y., Yano T. J. Mol. Cat. 132:1998;33.
16. Kunrath F.A., de Souza R.F., Casagrande O.L. J. Macromol. Rapid Commun. 21:2000;277.
17. Furlan L.G., Gil M.P., Casagrande O.L. J. Macromol. Rapid Commun. 21:2000;1054.
18. Karam A., Jimeno M., Lezama J., Catarí E., Figueroa A., De Gascue B.R. J. Mol. Cat. A. 176:2001;65.
19. Gil M.P., dos Santos J.H.Z., Casagrande O.L. Macromol. Chem. Phys. 202:2001;319.
20. López-Linares F., Barrios A.D., Ortega H., Karam A., Agrifoglio G., González E. J. Mol. Cat. A. 179:2002;87.
21. Murtuza S., Casagrande O.L., Jordan R.F. Organometallics. 21:2002;1882.
22. Tanke R.S., Crabtree R.H. Inorg. Chem. 28:1989;3444.
23. M.J. Fernández, M.J. Rodriguez, L.A. Oro, F.J. Lahoz, J. Chem. Soc. Dalton Trans. (1989) 2073.
24. Alvarado Y., Boutry O., Gutiérrez E., Monge A., Nicasio M.C., Poveda M.L., Pérez P.J., Ruiz C., Bianchini C., Carmona E. Chem. Eur. J. 3:1997;860.
25. Tellers D.M., Bergman R.G. J. Am. Chem. Soc. 122:2000;954.
26. Slugovc C., Mereiter K., Trofimenko S., Carmona E. Angew. Chem. Int. Ed. 112:2000;2242.
27. Onishi M., Ikemoto K., Hiraki K. Inorg. Chim. Acta. 190:1991;157.
28. Chan W., Lau C., Chen Y., Fang Y., Ng S., Jia G. Organometallics. 16:1997;34.
29. Vicente C., Shul'pin G.B., Moreno B., Sabo-Etienne S., Chaudret B. J. Mol. Cat. A. 98:1995;L5-L8.
30. Alvarado Y., Busolo M., López-Linares F. J. Mol. Cat. A. 142:1999;163.
31. D.F. Shriver, The Manipulation of Air Sensitive Compounds, Mac Graw-Hill, USA, 1969.
32. Onderdelinden A.L. Inorg. Synth. 12:1970;99.
33. Trofimenko S. Prog. Inorg. Chem. 34:1986;115.
34. Crabtree R.H. Organometallics. 2:1983;855.
35. Lyn Y., Finke R.G. Inorg. Chem. 33:1994;4891.
36. Bowens M., Gerfin T., Gramlich V., Petter W., Venanzi L.M., Harward M.T., Jackson S.A., Eisenstein O. N. J. Chem. 16:1992;337-345.
37. Albinati A., Bovens M., Rügger H., Vennanzi L. Inorg. Chem. 36:1997;5991ew.
38. Heinekey D.M., Oldham W.J. Jr. Chem. Rev. 93:1993;913.
39. Heinekey D.M., Oldham W.J. Jr. J. Am. Chem. Soc. 116:1994;3157.
40. Oldham W.J., Hinkle A.S., Heinekey D.M. J. Am. Chem. Soc. 119:1997;11028.