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Volumn 126, Issue 49, 2004, Pages 15960-15961

Proton transfer at helium temperatures during dioxygen activation by heme monooxygenases

Author keywords

[No Author keywords available]

Indexed keywords

BUFFER; GLYCEROL; HELIUM; HEME; OXYGEN; UNSPECIFIC MONOOXYGENASE;

EID: 10344264502     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja044646t     Document Type: Article
Times cited : (42)

References (27)
  • 10
    • 10344265478 scopus 로고    scopus 로고
    • note
    • In certain cases a superoxo-ferriheme is trapped.
  • 13
    • 10344228891 scopus 로고    scopus 로고
    • note
    • In certain cases a superoxo-ferroheme is trapped.
  • 15
    • 10344229410 scopus 로고    scopus 로고
    • note
    • 17 Samples were irradiated for ∼10 min at 4.2 K.; in one set of experiments the temperature was rapidly raised to ∼6 K to increase spectrometer stability and EPR spectra were promptly collected in 5 min; in a second set, the temperature was increased to 9 K before data collection.
  • 18
    • 10344233648 scopus 로고    scopus 로고
    • note
    • A solv-KIE also is seen for this reaction within P450cam ethylene-glycol/ buffer, but the process is complicated by the appearance of multiple oxyP450cam substates in this medium.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.