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In certain cases a superoxo-ferriheme is trapped.
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10344228891
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note
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In certain cases a superoxo-ferroheme is trapped.
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14
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0037181030
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15
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10344229410
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note
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17 Samples were irradiated for ∼10 min at 4.2 K.; in one set of experiments the temperature was rapidly raised to ∼6 K to increase spectrometer stability and EPR spectra were promptly collected in 5 min; in a second set, the temperature was increased to 9 K before data collection.
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16
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2442667845
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18
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10344233648
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note
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A solv-KIE also is seen for this reaction within P450cam ethylene-glycol/ buffer, but the process is complicated by the appearance of multiple oxyP450cam substates in this medium.
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19
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10344226645
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Davydov, R.; Perera, R.; Jin, S.; Yang, T.-C.; Bryson, T. A.; Sono, M.; Dawson, J. H.; Hoffman, B. M. J. Am. Chem. Soc. Submitted.
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