Kinetic study of photocatalytic degradation of carbamazepine, clofibric acid, iomeprol and iopromide assisted by different TiO2 materials - Determination of intermediates and reaction pathways

Water Research

Volumn 38, Issue 4, 2004, Pages 955-964

  Doll, Tusnelda E ^a   Frimmel, Fritz H ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Anatase (Hombikat UV100); Anatase rutile (P25); Aqueous suspensions; Contrast media; Degradation products; Pharmaceuticals

Indexed keywords

IRRADIATION; OXIDATION; PHOTOCATALYSIS; REACTION KINETICS; SOLAR RADIATION;

REACTION PATHWAYS;

PHOTODEGRADATION;

ALIPHATIC COMPOUND; AROMATIC COMPOUND; CARBAMAZEPINE; CLOFIBRIC ACID; ION; IOPROMIDE; TITANIUM DIOXIDE;

AQUEOUS SOLUTION; KINETICS; OXIDATION; PHARMACEUTICAL INDUSTRY; PHOTOCHEMICAL TREATMENT; POLLUTANT REMOVAL;

ADSORPTION; AQUEOUS SOLUTION; ARTICLE; DRUG DEGRADATION; MINERALIZATION; PHOTOCATALYSIS; PRIORITY JOURNAL; QUANTITATIVE ANALYSIS; SOLAR RADIATION;

EID: 0842324551     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.watres.2003.11.009     Document Type: Article

References (27)

1. Ternes T.A. Occurrence of drugs in German sewage treatment plants and rivers. Water Res. 32:1998;3245-3260.
2. Halling-Sørensen B., Nors Nielsen S., Lanzky P.F., Ingerslev F., Holten Lützhøft H.C., Jorgensen S.E. Occurrence, fate and effects of pharmaceutical substances in the environment - a review. Chemosphere. 36:1998;357-393.
3. Daughton C.G., Ternes T.A. Pharmaceuticals and personal care products in the environment. agents of subtle change ? Environ Health Perspect. 107:1999;907-938.
4. Putschew A., Wischnack S., Jekel M. Occurrence of triiodinated X-ray contrast agents in the aquatic environment. Sci Total Environ. 255:2000;129-134.
5. Möhle E., Kempter C., Kern A., Metzger J.W. Examination of the degradation of drugs in municipal sewage plants using liquid chromatography-electrospray mass spectrometry. Acta Hydrochim Hydrobiol. 27:1999;430-436.
6. Ternes T.A., Hirsch R. Occurrence and behavior of X-ray contrast media in sewage facilities and the aquatic environment. Environ Sci Technol. 34:2000;2741-2748.
7. Heberer T., Stan H-.J. Occurrence of polar organic contaminants in Berlin drinking water. Vom Wasser. 86:1996;19-31.
8. Sacher F., Lange F.T., Brauch H-.J., Blankenhorn I. Pharmaceuticals in groundwaters analytical methods and results of a monitoring program in Baden-Württemberg, Germany. J Chromatogr A. 938:2001;199-210.
9. Heberer T., Dünnbier U., Reilich C., Stan H-.J. Detection of drugs and drug metabolites in groundwater samples of drinking water treatment plant. Fresenius Environ Bull. 6:1997;438-443.
10. Ternes T.A., Meisenheimer M., McDowell D., Sacher F., Brauch H-.J., Haist-Gulde B., Preuss G., Wilme U., Zulei-Seibert N. Removal of pharmaceuticals during drinking water treatment. Environ Sci Technol. 36:2002;3855-3863.
11. Ternes T.A., Stüber J., Herrmann N., McDowell D., Ried A., Kampmann M., Teiser B. Ozonation. a tool for removal of pharmaceuticals, contrast media and musk fragrances from wastewater ? Water Res. 37:2003;1976-1982.
12. Huber M.M., Canonica S., Park G-.Y., von Gunten U. Oxidation of pharmaceuticals during ozonation and advanced oxidation processes. Environ Sci Technol. 37:2003;1016-1024.
13. Zwiener C., Frimmel F.H. Oxidative treatment of pharmaceuticals in water. Water Res. 34:2000;1881-1885.
14. Sprehe M., Geissen S-.U., Vogelpohl A. Photochemical oxidation of iodized X-ray contrast media (XRC) in hospital wastewater. Water Sci Technol. 44:2001;317-323.
15. Ollis DF, Al-Ekabi H, editors. Photocatalytic purification and treatment of water and air. Amsterdam: Elsevier Science; 1993.
16. Hoffmann M.R., Martin S.T., Choi W., Bahnemann D.W. Environmental applications of semiconductor photocatalysis. Chem Rev. 95:1995;69-96.
17. 2 photocatalysis for the treatment of water contaminated with metals and organic chemicals. Environ Sci Technol. 27:1993;1776-1782.
18. Bahnemann D. Photocatalytic detoxification of polluted water. In: Boule P, editor. The handbook of environmental chemistry, vol. 2, Part L. Environmental photochemistry. Berlin/Heidelberg: Springer; 1999.
19. Malato S., Blanco J., Vidal A., Richter C. Photocatalysis with solar energy at a pilot-plant scale. an overview Appl Catal. B37:2002;1-15.
20. Turchi C.S., Ollis D.F. Photocatalytic degradation of organic water contaminants. mechanisms involving hydroxyl radical attack J Catal. 122:1990;178-192.
21. Doll T.E., Frimmel F.H. Fate of pharmaceuticals - photodegradation by simulated solar UV-light. Chemosphere. 52:2003;1757-1769.
22. Frank R., Klöpffer W. Spectral solar photon irradiance in central Europe and the adjacent North Sea. Chemosphere. 17:1988;985-994.
23. 2-catalyzed photooxidation of Arsenite(III) to Arsenate(V) in aqueous samples. Chemosphere. 44:2001;751-757.
24. Defoin A., Defoin-Stratmann R., Hildenbrand K., Bittersmann E., Kreft D., Kuhn H.J. A new liquid phase actinometer. quantum yield and photo-CIDNP study of phenylglyoxylic acid in aqueous solutions J Photochem. 33:1986;237-255.
25. Doll T.E., Frimmel F.H., Kumke M.U., Ohlenbusch G. Interaction between natural organic matter (NOM) and polycyclic aromatic compounds (PAC) - comparison of fluorescence quenching and solid phase micro extraction (SPME). Fresenius J Anal Chem. 364:1999;313-319.
26. 2 photoreactivity and size quantization. J Chem Soc Faraday Trans. 21:1994;3315-3322.
27. Doll T.E., Frimmel F.H. Behavior of carbamazepine, clofibric acid, iomeprol, iopromide in the environment - photochemical degradation by simulated solar UV-light. Vom Wasser. 100:2003;99-110.