Tricarbonylrhenium(I) halide complexes of chiral non-racemic 2-(dioxolanyl)-6-(dioxanyl)pyridine ligands: Synthesis, NMR and DFT calculations

Polyhedron

Volumn 22, Issue 25-26, 2003, Pages 3371-3378

  Heard, Peter J ^a   King, Paul M ^a   Sroisuwan, Phunrawie ^a   Kaltsoyannis, Nikolas ^b  

^a QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

^b UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

1H NMR; Acetal ligands; DFT calculations; Diastereoisomers; Tricarbonylrhenium(I) halide complexes

Indexed keywords

ACTIVATION ENERGY; CHELATION; DENSITY FUNCTIONAL THEORY; FREE ENERGY; PYRIDINE; SYNTHESIS (CHEMICAL);

1H NMR; ACETAL LIGAND; DFT CALCULATION; DIASTEREOISOMERS; DONOR LIGANDS; DYNAMIC PROCESS; HALIDE COMPLEXES; O-DONOR; PYRIDINE LIGANDS; TRICARBONYLRHENIA(I) HALIDE COMPLEX;

LIGANDS;

1,3 DIOXOLANE DERIVATIVE; 2 (4,5 DIMETHYL 1,3 DIOXOLAN 2 DEUTERYL) 6 (4,6 DIMETHYL 1,3 DIOXAN 2 YL)PYRIDINE; 2 (4,5 DIMETHYL 1,3 DIOXOLAN 2 YL) 6 (4,6 DIMETHYL 1,3 DIOXAN 2 YL)PYRIDINE; 2,6 DIBROMOPYRIDINE; ACETAL; BROMINE DERIVATIVE; CARBONYL DERIVATIVE; CHELATE; HALIDE; HALOGEN; LIGAND; NITROGEN; OXYGEN; PYRIDINE DERIVATIVE; RHENIUM; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL REACTION; CHIRALITY; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; DYNAMICS; ENERGY; ENVIRONMENTAL TEMPERATURE; NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0742304473     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2003.08.012     Document Type: Article

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