Tricarbonylrhenium(i) halide complexes of 2-[(4R,6R?)-4,6-dimethyl-1,3-dioxan-2-yl]pyridine (L1) and 2,6-bis[(4#,6#)-4,6dimethyI-1,3-dioxan-2-yI]pyridine (L2): Structure and solution stereodynamics

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 11, 2000, Pages 1769-1775

  Heard, Peter J ^a   King, Paul M ^b   Tocher, Derek A ^b  

^a QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

^b UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0037785595     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b001206h     Document Type: Article

References (26)

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3. P. J. Heard, A. D. Bain and P. Hazendonk, Can. J. Client., 1999,77, 1707. Note the title ligand is incorrectly named as a dioxanyl in this paper. The correct ligand name is 2-[(4A,5/J)-4,5-dimethyl-l,3dioxolan-2-yl]pyridine.
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26. The lowering of the transition-state energy for the me, flip process must be more than sufficient to offset the (anticipated) lower ground-state energy in the complexes of L1.