Variation in the Mode of Coordination of Aryl Sulfonates to Zirconocene in the Solid State

Inorganic Chemistry

Volumn 37, Issue 14, 1998, Pages 3471-3474

  Hüsgen, Nicola S ^a   Luinstra, Gerrit A ^a   Schaper, Frank ^a   Schmidt, Katrin ^a  

^a UNIVERSITY OF KONSTANZ   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0542395827     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971597v     Document Type: Article

References (27)

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4. (b) 354. INOR.
5. (c) Hüsgen, N. S.; Luinstra, G. A. Manuscript in preparation.
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13. Cf.: (a) Klima, S.; Thewalt, U. J. Organomet. Chem. 1988, 354, 77. (b) Thewalt, U.; Lasser, W. Z. Naturforsch. 1983, 38b, 1501. (c) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1984, 276, 341. (d) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1989, 363, C12.
14. Cf.: (a) Klima, S.; Thewalt, U. J. Organomet. Chem. 1988, 354, 77. (b) Thewalt, U.; Lasser, W. Z. Naturforsch. 1983, 38b, 1501. (c) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1984, 276, 341. (d) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1989, 363, C12.
15. Cf.: (a) Klima, S.; Thewalt, U. J. Organomet. Chem. 1988, 354, 77. (b) Thewalt, U.; Lasser, W. Z. Naturforsch. 1983, 38b, 1501. (c) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1984, 276, 341. (d) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1989, 363, C12.
16. Cf.: (a) Klima, S.; Thewalt, U. J. Organomet. Chem. 1988, 354, 77. (b) Thewalt, U.; Lasser, W. Z. Naturforsch. 1983, 38b, 1501. (c) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1984, 276, 341. (d) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1989, 363, C12.
17. (e) Siedle, A. R.; Newmark, R. A.; Gleason, W. B.; Lamanna, W. M. Organometallics 1990, 9, 1290.
18. Desiraju, G. R.; Sarma, J. A. R. P. Proc.-Indian Acad. Sci., Chem. Sci. 1986, 96, 599.
19. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
20. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
21. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
22. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
23. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
24. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
25. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
26. Sulfonate double bridged structures: (a) Tateyama, Y.; Ohki, Y.; Suzuki, Y.; Uochi, A. Bull. Chem. Soc. Jpn. 1988, 61, 2214. (b) Kretz, b. C. M.; Gallo, E.; Floriani, C.; Villa, A. C; Rizzoli, C. J. Am. Chem. Soc. 1994, 116, 10775. Single bridged: (c) Gano, F. E.; Subramaniam, G.; Birnbaum, R. J. J. Org. Chem. 1990, 55, 4760. Bridged in bimetallic compounds: (d) Rheinwald, G.; Stoeckli-Evans, H.; Suss-Fink, G. J. Organomet. Chem. 1992, 441, 295. (e) Ferrara, J. D.; Tessier-Youngs, C.; Youngs, W. Inorg. Chem. 1988, 27, 2201. (f) Dedert, P. L.; Sorrell, T.; Marks, T. J.; Ibers, J. A. Inorg. Chem. 1982, 21, 3506. (g) Clegg, W.; Akhter, L.; Garner, C. D. J. Chem. Soc., Chem. Commun. 1984, 101. In K and Rb salts a bidentate sulfonate coordination was found: (h) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
27. This is also obvious from the distances of O2, O3, and O6 to the CE1-CE2-Zr plane in 1 of -0.36, -2.18, and 1.91 Å; the corresponding distances (O1, O4, O5a) are -2.069, 0.1617, and 2.2382 Å in 2 and 1.478 Å in 4.