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0347311201
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note
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2 salt of I are highly soluble in THF.
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18
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0347311202
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note
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The structural data obtained for complex II revealed the presence of a bromide impurity, which was present in the original batch of 6 that produced the crystal (see Supporting Information). The data are satisfactorily modeled with the halide occupancy as 60% Br and 40% Cl.
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19
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0347311195
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21
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0011028728
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25
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0033521580
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26
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0034600318
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Littke, A.F.1
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27
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0347311196
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note
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The phenyl substituted ligands 1, 3, and 4 were much less effective in the Suzuki coupling or aryl chlorides. Ligand 6 showed comparable activity to 5 in several model studies. Also, a point of concern pertains to whether the tetraarylborate unit of ligand 5 is transferred during the cross-coupling reactions. While we cannot rule-out this possibility altogether, we note that tolylboronic acids were also screened briefly and found to give comparable yields.
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28
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0347941393
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note
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1 stretch is weak and presumably coincident with the E vibration.
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29
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0000903520
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(a) Cotton, F. A.; Darensbourg, D. J.; Ilsley, W. H. Inorg. Chem. 1981, 20, 578.
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31
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0000075735
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(c) Magee, T. A.; Matthews, C. N.; Wang, T. S.; Wotiz, J. H. J. Am. Chem. Soc. 1961, 83, 3200.
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Wotiz, J.H.4
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