Synthesis and Spectroscopic Studies of Cobalt(II) and Copper(II) Complex Compounds with 4-Methoxybenzaldehyde-N-[4-(4′-chlorophenylenesulfonyl) benzoyl]hydrazone

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 33, Issue 10, 2003, Pages 1927-1941

  Cǎlinescu, Mirela ^a   Emandi, Ana ^a   Şerban, Ileana ^a   Pop, Veronica ^a  

^a UNIVERSITY OF BUCHAREST   (Romania)

Author keywords

[No Author keywords available]

Indexed keywords

4 METHOXYBENZALDEHYDE N [4 (4' CHLOROPHENYLENE SULFONYL)BENZOYL]HYDRAZONE COMPLEX; COBALT ACETATE; COBALT CHLORIDE; COPPER; COPPER BROMIDE; COPPER CHLORIDE; COPPER COMPLEX; DIMER; HYDRAZONE DERIVATIVE; MONOMER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; DRUG SYNTHESIS; ELECTRON SPIN RESONANCE; INFRARED SPECTROMETRY; MAGNETISM; SPECTROSCOPY; THERMOGRAVIMETRY;

EID: 0347916945     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120026557     Document Type: Article

References (31)

1. Sharma, R.C.; Ambwani, J.; Varshney, V.K. Synthetic and antimicrobial studies of some heterocyclic hydrazones and their bivalent metal complexes. J. Indian Chem. Soc. 1992, 69, 770-772.
2. Ersan, S.; Nacak, S.; Berkem, R. Synthesis and antimicrobial activity of N-[(alpha-methyl)benzylidene]-(3-substituted-1,2,4-triazol-5-yl-thio) -acetohydrazides. Farmaco 1998, 53 (12), 773-776.
3. Nawar, N.; Khattab, M.A.; Hosny, N.M. Some metal(II) complexes of o-aminoacetophenone benzoylhydrazone. Synth. React. Inorg. Met.-Org. Chem. 1999, 28 (8), 1365-1384.
4. Chohan, Z.H. Synthesis, characterization and biological properties of bivalent transition metal complexes of Co(II), Cu(II), Ni(II) and Zn(II) with some acylhydrazine derived furanyl and thienil ONO and SNO donor Schiff base ligands. Synth. React. Inorg. Met.-Org. Chem. 2001, 31 (1), 1-16.
5. Gürsoy, A.; Terzioglu, N.; Ötük, G. Synthesis of some new hydrazide-hydrazones, thiosemicarbazides and thiazolidinones as possible antimicrobials. J. Med. Chem. 1997, 32, 753-757.
6. Levejoy, D.B.; Richardson, D.R. Complexes of gallium(III) and other metal ions and their potential in the treatment of neoplasia. Expert Opin. Investig. Drugs 2000, 9 (6), 1257-1270.
7. Van Reyk, D.; Sarel, S.; Hunt, N. Inhibition of in vitro lymphoproliferation by three novel iron chelators of the pyridoxal and salicyl aldehyde hydrazone. Biochem. Pharmacol. 2000, 60 (4), 581-587.
8. Negoiu, D.; Calinescu, M.; Emandi, A.; Badau, E. Synthesis and structural characterization of Cr(III), Co(II), Ni(II) and Cu(II) complexes with salycilaldehyde-N-[4-(4′-chlorophenylene sulphonyl)benzoyl]hydrazone. Russ. J. Coord. Chem. 1999, 25 (1), 36-41.
9. Singh, N.K.; Agrawal, N.; Aggarwal, R.C. Synthesis, characterization and antibacterial studies of iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) complexes of pyridine-4-carboxaldehyde isonicotinoyl hydrazone. Indian J. Chem. 1984, 23A, 1011-1015.
10. Dwiedi, D.K.; Agarwala, B.V.; Dey, A.K. Synthesis and structural characterization of 2-hydroxy-1-naphthalidene-3,5-dinitrobenzoylhydrazone complexes. J. Indian Chem. Soc. 1988, LXV, 461-463.
11. Tossidis, I.A.; Bolos, C.A.; Cristofides, A. Monohalogenobenzoylhydrazones. VI. New antimony(III) complexes with monochlorobenzoylhydrazones of 2-furaldehyde, 2-pyrrolaldehyde and 2-thiophenaldehyde as ligands. J. Therm. Anal. 1989, 35, 1339-1350.
12. Dutta, R.L.; Hossain, Md.M. Coordination chemistry of acyl, aroyl, heteroaroyl hydrazones and related ligands. J. Sci. Ind. Res. 1985, 44, 635-674.
13. Mishira, R.C.; Mohapatra, B.K.; Panda, D. Studies of hydrazones, semicarbazones, thiosemicarbazones and oximes as ligands. 7. Some divalent metal-complexes of benzalacetone thiosemicarbazone. J. Indian Chem. Soc. 1983, 60, 782-783.
14. Lal, K.; Malhotra, S.R. Magnetic and spectral studies on copper(II), nickel(II), cobalt(II), iron(III) and manganese(II) complexes of 3-bromo-2-hydroxy-5-methylacetophenone hydrazone. Rev. Roum. Chim. 1985, 30 (5), 395-400.
15. Agarwala, B.V.; Reddy, P.S.N. Complexes of nicotinoyl-and isonicotinoyl hydrazone Schiff bases with divalent metal ions. Acta Chim. Hung. 1990, 127 (2), 269-275.
16. Gang, Z.; Yongxiang, M. Coordination complexes of acetylferrocene-m- nitrobenzoylhydrazone with lanthanides. Polyhedron 1991, 10 (18), 2185-2189.
17. Qing-bao, S.; Pan-ming, J.; Xiao-li, W.; Guo-sheng, H.; Yong-Xiang, M. Norbornenyl aroylhydrazones and their copper(II) and mercury(II) complexes. Synth. React. Inorg. Met.-Org. Chem. 1996, 26 (10), 1753-1763.
18. Mohan, M.; Gupta, N.K.; Kumar, M.; Jha, N.K.; Antholine, W.E. Synthesis, magnetic and electrochemical properties of binuclear copper(II) complexes of pyridoxal hydrazones. Inorg. Chim. Acta 1992, 797, 39-46.
19. Bhardwaj, S.; Ansari, M.N.; Jain, M.C. Synthesis and characterization of some 3d metal complexes with isatin hydrazones. Indian J. Chem. 1989, 28A, 81-82.
20. Chandra, R.; Sahni, S.K.; Kapoor, R.N. Synthesis and characterization of chromium(III), manganese(III), iron(III) and cobalt(III) complexes of dihydrazones derived from salicylaldehyde and aliphatic dicarboxylic acid dihydrazides. Acta Chim. Hung. 1983, 112 (4), 385-400.
21. Dutta, R.L.; Sarkar, A.K. A study of metal-complexes of carbohydrazide. J. Inorg. Nucl. Chem. 1981, 43, 2557-2559.
22. Lever, A.B.P. Crystal field spectra. Cobalt(II). In Inorganic Electronic Spectroscopy, Elsevier Publishing Company: Amsterdam, 1968; 320.
23. Furlani, C. Ligand field interpretation of some cases of pentacoordination. Coord. Chem. Rev. 1968, 3, 141-167.
24. Mohan, M.; Kumar, A.; Kumar, M. Synthesis, characterization and antitumor activity of manganese(II), cobalt(II), nickel(II), copper(II), zinc(II) and platinum(II) complexes of 3-and 5-substituted salicylaldehyde benzoylhydrazones. Inorg. Chim. Acta 1987, 136, 65-74.
25. Mohan, M.; Gupta, M.P.; Chandra, L.; Jha, N.K. Synthesis, characterization and antitumour properties of some metal(II) complexes of 2-pyridinecarboxaldehyde 2′-pyridylhydrazone and related compounds. Inorg. Chim. Acta 1988, 151, 61-68.
26. Hathaway, B.J.; Tomlinson, A.A.G. Copper(II) ammonia complexes. Coord. Chem. Rev. 1970, 5, 1-43.
27. Yokoi, H.; Isobe, T. ESR and optical absorption studies of the copper(II) complexes of ethylenediamine and its alkyl derivatives. Bull. Chem. Soc. Jpn. 1969, 42, 2187-2193.
28. Yokoi, H.; Sai, M.; Isobe, T. ESR studies of bis-(N,N′- diethylethylenediamine)copper(II) perchlorate. Bull. Chem. Soc. Jpn. 1969, 42, 2232-2238.
29. Kivelson, D.; Nieman, R. ESR studies on the bonding in copper complexes. J. Chem. Phys. 1961, 35, 149-155.
30. Procter, I.M.; Hathaway, B.J.; Nicholls, P. The electronic properties and stereochemistry of the copper(II) ion. Part I. Bis(ethylenediamine) copper(II) complexes. J. Chem. Soc. 1968, 1678-1684.
31. Badau, E. Doctor's Thesis; 1966; Bucharest.