Hydrogen adsorption on the indium-rich indium phosphide (001) surface: A novel way to produce bridging In-H-In bonds

Journal of the American Chemical Society

Volumn 124, Issue 50, 2002, Pages 15119-15124

  Raghavachari, K ^c   Fu, Q ^a   Chen, G ^a   Li, L ^b   Li, C H ^a   Law, D C ^a   Hicks, R F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF WISCONSIN MILWAUKEE   (United States)

^c AGERE SYSTEMS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CHEMICAL BONDS; DIMERS; HYDRIDES; INDIUM COMPOUNDS; SPECTROSCOPY; THERMODYNAMIC PROPERTIES;

ELECTRON-DEFICIENT GROUP;

HYDROGEN;

DIMER; HYDROGEN; INDIUM; PHOSPHINE DERIVATIVE;

ABSORPTION; ARTICLE; CHEMICAL REACTION; COVALENT BOND; HYDROGEN BOND; SPECTROSCOPY; STRUCTURE ANALYSIS; THERMODYNAMICS;

EID: 0347298780     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020348p     Document Type: Article

References (38)

1. Taylor, M. J.; Brothers, P. J. In Chemistry of Aluminum, Gallium, Indium and Thallium; Downs, A. J., Ed.; Blackie: Glasgow, 1993; p 111.
2. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry; John Wiley & Sons: New York, 1988.
3. Greenwood, N. N. The Chemistry of Boron; Pergarnon Press: Oxford, 1975.
4. Lawrence, S. H.; Wermer, J. R.; Boocock, S. K.; Banks, M. A.; Keller, P. C.; Shore, S. G. Inorg. Chem. 1986, 25, 367.
5. Downs, A. J.; Pulham, C. R. Chem. Rev. 1994, 23, 175.
6. Browser, F. M.; Matzek, N. E.; Reigler, P. F.; Rinn, H. W.; Roberts, C. B.; Schmidt, D. L.; Snover, J. A.; Terada, K. J. Am. Chem. Soc. 1976, 98, 2450.
7. Downs, A. J.; Goode, M. J.; Pulham, C. R. J. Am. Chem. Soc. 1989, III, 1936.
8. Pulham, C. R.; Downs, A. J.; Goode, M. J.; Rankin, D. W. H.; Robertson, H. E. J. Am. Chem. Soc. 1991, 113, 5149.
9. Pullumbi, P.; Bouteiller, Y.; Manceron, L.; Mijoule, C. Chem. Phys. 1994, 185, 25.
10. Hibbs, D. E.; Hursthouse, M. B.; Jones, C.; Smithies, N. A. Organometallics 1998, 17, 3108 and references therein.
11. Hunt, P.; Schwerdtfeger, P. Inorg. Chem. 1996, 35, 2085.
12. Bennett, F. R.; Connelly, J. P. J. Phys. Chem. 1996, 100, 9308.
13. Duke, B. J.; Liang, C.; Schaefer, H. F. J. Am. Chem. Soc. 1991, 113, 2884.
14. Fu, Q.; Negro, E.; Chen, G.; Law, D. C.; Li, C. H.; Hicks, R. F.; Raghavachari, K. Phys. Rev. B 2002, 65, 075318.
15. Qi, H.; Gee, P. E.; Hicks, R. F. Phys. Rev. Lett. 1994, 72, 250.
16. Li, L.; Han, B.-K.; Fu, Q.; Hicks, R. F. Phys. Rev. Lett. 1999, 82, 1879.
17. Hicks, R. F.; Qi, H.; Fu, Q.; Han, B. K.; Li, L. J. Chem. Phys. 1999, 110, 10498.
18. Fu, Q.; Li, L.; Hicks, R. F. Phys. Rev. B 2000, 61, 11034.
19. Fu, Q.; Li, L.; Li, C. H.; Begarney, M. J.; Law, D. C.; Hicks, R. F. J. Phys. Chem. B 2000, 104, 5595.
20. Pashley, M. D. Phys. Rev. B 1989, 40, 10481.
21. Li, L.; Fu, Q. Li, C. H.; Han, B.-K.; Hicks, R. F. Phys. Rev. B. 2000, 61, 10223.
22. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. A.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.: Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B. G.; Chen, W.; Wong, M. W.; Andres, J. L.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Gaussian 98, rev. A.7: Gaussian, Inc.: Pittsburgh, PA, 1998.
23. Becke, A. D. J. Chem. Phys. 1993, 98, 1372.
24. Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B 1988, 37, 785.
25. Godbout, N.; Salahub, D. R.; Andzelm, J.; Wimmer, E. Can. J. Chem. 1992, 70, 560.
26. Igel-Mann, G.; Stoll, H.; Preuss H. Mol. Phys. 1988, 65, 1321.
27. Dunning, T. H., Jr.; Hay, P. J. In Modern Theoretical Chemistry; Schaefer, H. F., III, Ed.; Plenum: New York, 1976; Vol. 3, p 1.
28. Bergner, A.; Dolg, M.; Kuechle, W.; Stoll, H.; Preuss, H. Mol. Phys. 1993, 80, 1431.
29. Chabal, Y. J. Surf. Sci. Rep. 1988, 8, 211; Weldon, M. K.; Queeney, K. T.; Gurevich, A. B.; Stefanov B. B.; Chabal. Y. J.; Raghavachari, K. J. Chem. Phys. 2000, 113, 2440.
30. Chabal, Y. J. Surf. Sci. Rep. 1988, 8, 211; Weldon, M. K.; Queeney, K. T.; Gurevich, A. B.; Stefanov B. B.; Chabal. Y. J.; Raghavachari, K. J. Chem. Phys. 2000, 113, 2440.
31. Schmidt, W. G. Phys. Rev. B 1998, 57, 14596.
32. Hofacker, G. L.; Marechal, Y.; Ratner, M. A. In The Hydrogen Bond; Schuster, P., Zundel, G., Sandorfy, S., Eds.; North-Holland: Amsterdam, 1976; Vol. 1, p 294.
33. Herzberg, G. Molecular Spectra and Molecular Structure, Infrared and Raman Spectra of Polyatomic Molecules; Van Nostrand Reinhold: New York, 1945; Vol. 2, p 168.
34. Kerr. J. A. In CRC Handbook of Chemistry and Physics 1999-2000: A Ready-Reference Book of Chemical and Physical Data, 79th Ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, Florida, 1998.
35. Swaminathan, V.; Macrander, A. T. Material Aspects of GaAs and InP Based Structures; Prentice Hall: Englewood Cliffs, NJ, 1991.
36. 2.
37. The P-H, In-H and In-In bond energies are assumed to equal 76, 58 and 24 kcal/mol, respectively (Ref. 34). The former value was estimated from the heat of formation of phosphine, whereas the latter two values were taken from the single bond energies listed in ref 1, p 2.
38. 298, where the second term equals the dimerization energy, 22 kcal/mol, and the last term is 58 kcal/mol (ref I, p 12).