Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface speciation and chemical affinity control

Geochimica et Cosmochimica Acta

Volumn 68, Issue 1, 2004, Pages 31-45

  Pokrovsky, Oleg S ^a   Schott, Jacques ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; BRUCITE; DISSOLUTION; MAGNESIUM; POLLUTANT; PRECIPITATION (CHEMISTRY); REACTION RATE;

EID: 0347062517     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(03)00238-2     Document Type: Article

References (75)

1. Allison J. D., Brown D. S., and Novo-Gradac K. J. (1991) MINTEAQA2/PRODEFA2, A geochemical assessment model for environmental systems: Version 3.0 user's manual. U.S. EPA, Athens, GA, 106 p
2. Altmaier M., Metz V., Neck V., Muller R., and Fanghanel T. (in press) Solid-liquid equilibria of Mg(OH)2(cr) and Mg2(OH)3Cl · 4H2O(cr) in the system Mg-Na-H-OH-Cl-H2O at 25°C. Geochim. Cosmochim. Acta
3. Amrhein C.Suarez D.L.The use of a surface complexation model to describe the kinetics of ligand-promoted dissolution of anorthite Geochim. Cosmochim. Acta 52 1988 2785-2793
4. Baes C.F.Jr.Mesmer R.E. The Hydrolysis of Cations 1976 John Wiley - SonsNew York
5. Berger G.Cadoré E.Schott J.Dove P.M.Dissolution rate of quartz in Pb and Na electrolyte solutions between 25 and 300°C. Effect of the nature of the surface complexes and reaction affinity Geochim. Cosmochim. Acta 58 1994 541-551
6. 2 over Phanerozoic time Am. J. Sci. 291 1991 339-376
7. Berry A.J.Fraser D.G.Grime G.W.Craven J.Sleeman J.T.The hydration and dissolution of periclase Mineral. Magazine 62A 1998 158-159
8. Boudart M.Consistency between kinetics and thermodynamics J. Phys. Chem. 80 1976 2869-2870
9. Brady P.V.House W.A.Surface controlled dissolution and growth of minerals Brady P.V. Physics and Chemistry of Mineral Surfaces 1996 225-306 CRC Press
10. Brady P.V.Walther J.V.Controls on silicate dissolution rates in neutral and basic pH solutions at 25°C Geochim. Cosmochim. Acta 53 1989 2823-2830
11. Casey W.H.On the relative dissolution rates of some oxides and orthosilicate minerals J. Colloid Interface Sci. 146 1991 586-589
12. 3 Geochim. Cosmochim. Acta 54 1990 2329-2336
13. Chieng C.Nancollas G.H.The crystallization of magnesium hydroxide, a constant composition study Desalination 42 1982 209-219
14. Devidal J.-L.Schott J.Dandurand J.-L.An experimental study of kaolinite dissolution and precipitation kinetics as a function of chemical affinity and solution composition at 150 C, 40 bars, and pH 2, 6.8, and 7.8 Geochim. Cosmochim. Acta 61 1997 5165-5186
15. Dove P.M.The dissolution kinetics of quartz in sodium chloride solutions at 25°C to 300°C Am. J. Sci. 294 1994 665-712
16. Duval Y.Mielczarski J.A.Pokrovsky O.S.Mielczarski E.Ehrhardt J.J.Evidence of the existence of three types of species at the quartz-aqueous solution interface at pH 0-10: XPS surface group quantification and surface complexation modeling J. Phys. Chem. B 106 2002 2937-2945
17. Fenter P.Geissbuhler P.DiMasi E.Srajer G.Sorensen L.B.Sturchio N.C.Surface speciation of calcite observed in situ by high-resolution X-ray reflectivity Geochim. Cosmochim. Acta 64 2000 1221-1228
18. Gautier J.-M.Oelkers E.H.Schott J.Experimental study of K-feldspar dissolution rates as a function of chemical affinity at 150 C and pH 9 Geochim. Cosmochim. Acta 58 1994 4549-4560
19. Grant M.Jordan R.B.Kinetics of solvent water exchange on iron (III) Inorg. Chem. 20 1981 55-60
20. Guy C.Schott J.Multisite surface reaction versus transport control during the hydrolysis of a complex oxide Chem. Geol. 78 1989 181-204
21. Hayes K.F.Redden G.Ela W.Leckie J.O.Surface complexation models: An evaluation of model parameters estimation using FITEQL and oxide mineral titration data J. Colloid. Interface Sci. 142 1991 448-469
22. Hostetler P.B.The stability and surface energy of brucite in water at 25°C Am. J. Science 261 1963 238-258
23. Huertas F.J.Chou L.Wollast R.Mechanism of kaolinite dissolution at room temperature and pressure: Part 1. Surface speciation Geochim. Cosmochim. Acta 62 1998 417-431
24. Hunter R.J. Foundation of Colloid Science Vol. 1 1989 Clarendon PressOxford
25. Jones C.F.Segall R.L.Smart S.C.Turner P.S.Initial dissolution kinetics of ionic oxides Proc. R. Soc. London A 374 1981 141-153
26. Jones C.F.Reeve R.A.Rigg R.Segall R.L.Smart R.S.C.Turner P.S.Surface area and the mechanism of hydroxylation of ionic oxide surfaces J. Chem. Soc. Faraday Trans. I 80 1984 2609-2617
27. Jordan G.Rammensee W.Dissolution rates and activation energy for dissolution of brucite (001): A new method based on the microtopography of crystal surfaces Geochim. Cosmochim. Acta 60 1996 5055-5062
28. Jordan G.Higgins S.R.Eggleston C.M.Dissolution of the periclase (001) surface: A scanning force microscopy study American Mineralogist 84 1999 144-151
29. Klein D.H.Smith M.D.Driy J.A.Homogeneous nucleation of magnesium hydroxide Talanta 14 1967 937-940
30. 2, temperature, and time Geochim. Cosmochim. Acta 57 1993 285-294
31. Kramer S.M.Hering J.G.Influence of solution saturation state on the kinetics of ligand-controlled dissolution of oxide phases Geochim. Cosmochim. Acta 61 1997 2855-2866
32. Lasaga A.C.Transition State Theory. In Kinetics of Geochemical Processes (ed. A. C. Lasaga and R. J. Kirkpatrick Rev. Mineral. 8 1981 135-169
33. Liu S.-T.Nancollas G.H.The crystallization of magnesium hydroxide Desalination 12 1973 75-84
34. MacDonald D.D.Owen D.The dissolution of magnesium oxide in dilute sulfuric acid Canad. J. Chem. 49 1971 3375-3380
35. Monastra V.Grandstaff D.E.Kinetics of MgO dissolution and buffering fluids in the Waste Isolation Pilot Plant (WIPP) repository Mat. Res. Soc. Symp. Proc. 556 1999 625-632
36. Morth C.-M, and Strandh H. (1999) Brucite dissolution at pH 1.74 to 4.7 at 25°C to 55°C. Proceed. Internat. Conf. Geochemistry of the Earth Surface, Reykjavik, 1999, p. 457-460
37. Nagy K.L.Lasaga A.C.Dissolution and precipitation kinetics of gibbsite at 80° C and pH 3: The dependence on solution saturation state Geochim. Cosmochim. Acta 56 1992 3093-3111
38. Nagy K.L.Blum A.Lasaga A.C.Dissolution and precipitation kinetics of kaolinite at 80°C and pH 3: The dependence on solution saturation state Am. J. Sci. 291 1991 649-686
39. 2+(aq) Inorg. Chem. 37 1998 4760-4763
40. Oelkers E.H.General kinetic description of multioxide silicate mineral and glass dissolution Geochim. Cosmochim. Acta 65 2001 3703-3719
41. Oelkers E.H.Schott J.An experimental study of enstatite dissolution rates as a function of pH, temperature, and aqueous Mg and Si concentration, and the mechanism of pyroxene/pyroxenoid dissolution Geochim. Cosmochim. Acta 65 2001 1219-1231
42. Oelkers E.H.Schott J.Devidal J.-L.The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions Geochim. Cosmochim. Acta 58 1994 2011-2024
43. Palmer D.A.Wesolowski D.J.Potentiometric measurements of the first hydrolysis quotient of magnesium(II) to 250°C and 5 molal ionic strength (NaCl) J. Solution Chem. 26 1997 217-232
44. 2 crystal in an aqueous environment at 60°C J. Crystal Growth 41 1977 228-234
45. Pokrovsky O.S.Savenko V.S.Experimental determination of magnesium activity coefficient in seawater Oceanology 326 1992 724-730
46. Pokrovsky O.S.Schott J.Processes at the magnesium-bearing carbonates/solution interface. II. Kinetics and mechanism of magnesite dissolution Geochim. Cosmochim. Acta 63 1999 881-897
47. Pokrovsky O.S.Schott J.Kinetics and mechanism of forsterite dissolution at 25°C and pH from 1 to 12 Geochim. Cosmochim. Acta 64 2000 3313-3325
48. Pokrovsky O.S.Schott J.Surface chemistry and dissolution mechanism of divalent metal carbonates Environ. Sci. Technol. 36 2002 426-432
49. Pokrovsky O.S.Schott J.Thomas F.Processes at the magnesium-bearing carbonates/solution interface. I. A surface speciation model for magnesite Geochim. Cosmochim. Acta 63 1999 863-880
50. Pokrovsky O.S.Schott J.Thomas F.Dolomite surface speciation and reactivity in aquatic systems Geochim. Cosmochim. Acta 63 1999 3133-3143
51. Samson S.D.Eggleston C.M.Active sites and the non-steady-state dissolution of hematite Environ. Sci. Technol. 32 1998 2871-2875
52. 3 at pH 3 and pH 6 Geochim. Cosmochim. Acta 64 2000 3675-3683
53. Samson S.D.Stillings L.L.Eggleston C.M.The depletion and regeneration of dissolution-active sites at the mineral-water interface: I. Fe, Al, and In sesquioxides Geochim. Cosmochim. Acta 64 2000 3471-3484
54. Sangwal K.Arora S.K.Etching of MgO crystals in acids: Kinetics and mechanism of dissolution J. Material Sci. 13 1978 1977-1985
55. Schindler P.W.Stumm W.The surface chemistry of oxides, hydroxides, and oxide minerals Stumm W. Aquatic Surface Chemistry 1987 337-365 Wiley
56. Schott H.Electrokinetic studies of magnesium hydroxide J. Pharmac. Sci. 70 1981 486-489
57. Schott J.M . Modeling of the dissolution of strained and unstrained multiple oxides: The surface speciation approach Stumm W.
58. Schott J.Berner R.A.X-ray photoelectron studies of the mechanism of iron silicate dissolution during weathering Geochim. Cosmochim. Acta 47 1983 2233-2240
59. Schott J.Berner R.A.Dissolution mechanisms of pyroxenes and olivines during weathering Drever J.J. The Chemistry of Weathering 1985 35-53 D. Riedel
60. Schott J.Oelkers E.Dissolution and crystallization of silicate minerals as a function of chemical affinity Pure Appl. Chem. 67 1995 903-910
61. Schott J.Berner R.A.Sjöberg E.L.Mechanism of pyroxene and amphibole weathering - I. Experimental studies of iron-free minerals Geochim. Cosmochim. Acta 45 1981 2123-2135
62. Segall R.L.Smart R.S.C.Turner P.S.Ionic oxides: Distinction between mechanisms and surface roughening effects in the dissolution of magnesium oxide J. Chem. Soc. Faraday Trans. I 74 1978 2907-2912
63. Stumm W. (1992) Chemistry of the Solid-Water Interface. Wiley
64. Stumm W.Reactivity at the mineral-water interface: Dissolution and inhibition Colloids Surfaces, A: Physicochem. Eng. Aspects 120 1997 143-166
65. Stumm W.Wieland E.Dissolution of oxide and silicate minerals: Rates depend on surface speciation Stumm W. Aquatic Chemical Kinetics: Reaction Rates of Processes in Natural Waters 1990 367-400 J. Wiley - Sons
66. Sverjensky D.A.Sahai N.Theoretical prediction of single-site surface-protonation equilibrium constants for oxides and silicates in water Geochim. Cosmochim. Acta 60 1996 3773-3797
67. Tsuge H.Okada K.Yano T.Fukushi N.Akita H.Reactive crystallization of magnesium hydroxide. Separation and Purification by Crystallization ACS Symposium Series 667 1997 254-266
68. Van Cappellen P.Charlet L.Stumm W.Wersin P.A surface complexation model of the carbonate mineral - aqueous solution interface Geochim. Cosmochim. Acta 57 1993 3505-3518
69. Velbel M.A.Bond strength and the relative weathering rates of simple orthosilicates Am. J. Sci. 299 1999 679-696
70. 2 in aqueous solutions J. Electrochem. Soc. 116 1969 1179-1183
71. Westrich H.R.Cygan R.T.Casey W.H.Zemitis C.Arnold G.W.The dissolution kinetics of mixed-cation orthosilicate minerals Am. J. Sci. 293 1993 869-893
72. Wieland E.Wehrli B.Stumm W.The coordination chemistry of weathering: III. Generalization of the dissolution rates of minerals Geochim. Cosmochim. Acta 52 1988 1969-1981
73. 2, and organic acids Geochim. Cosmochim. Acta 55 1991 943-954
74. Wogelius R.A.Refson K.Fraser D.G.Grime G.W.Goff J.P.Periclase surface hydroxylation during dissolution Geochim. Cosmochim. Acta 59 1995 1875-1881
75. Wu L.Forsling W.Schindler P.W.Surface complexation of calcium minerals in aqueous solution. 1. Surface protonation at fluorapatite - water interface J. Colloid. Interface Sci. 147 1991 178-185