An experimental study of kaolinite dissolution and precipitation kinetics as a function of chemical affinity and solution composition at 150°C, 40 bars, and pH 2, 6.8, and 7.8

Geochimica et Cosmochimica Acta

Volumn 61, Issue 24, 1997, Pages 5165-5186

  Devidal, Jean Luc ^a   Schott, Jacques ^a   Dandurand, Jean Louis ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DISSOLUTION; KAOLINITE; PRECIPITATION KINETICS;

EID: 0031430159     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(97)00352-9     Document Type: Article

References (74)

1. Aagaard P. and Helgeson H. C. (1982) Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions: I. Theoretical considerations. Amer. J. Sci. 282, 237-285.
2. Bates R. G. (1973) Determination of pH. Theory and Practice. Wiley.
3. Bennet P. C. (1991) Quartz dissolution in organic rich aqueous systems. Geochim. Cosmochim. Acta 55, 1781-1797.
4. Berger G., Cadore E., Schott J., and Dove P. (1994) Dissolution rates of quartz in lead and sodium electrolyte solutions between 25 and 300°C: Effect of the nature of surface complexes and reaction affinity. Geochim. Cosmochim. Acta 58, 541-551.
5. Bjørlykke K. (1984) Formation of secondary porosity: How important is it? In Clastic Diagenesis (ed. D. A. McDonald and R. C. Surdam); AAPG Mem. 37, 277-286.
6. Bjørlykke K. (1984) Formation of secondary porosity: How important is it? In Clastic Diagenesis (ed. D. A. McDonald and R. C. Surdam); AAPG Mem. 37, 277-286.
7. Blum A. E. and Stillings L. L. (1995) Feldspar dissolution kinetics. In Chemical Weathering Rates of Silicate Minerals (ed. A. F. White and S. L. Brantley); Rev. Mineral. 31, 291-346.
8. Blum A. E. and Stillings L. L. (1995) Feldspar dissolution kinetics. In Chemical Weathering Rates of Silicate Minerals (ed. A. F. White and S. L. Brantley); Rev. Mineral. 31, 291-346.
9. Boudart A. (1976) Consistancy between kinetics and thermodynamics. J. Phys. Chem. 80, 2869-2870.
10. Burch T. E., Nagy K. L., and Lasaga A. C. (1993) Free energy dependence of albite dissolution kinetics at 80°C, pH 8.8. Chem. Geol. 105, 137-162.
11. Carroll-Webb S. A. and Walther J. V. (1988) A surface reaction model for the pH-dependence of corundum and kaolinite dissolution rates. Geochim. Cosmochim. Acta 52, 2609-2623.
12. Carroll S. A. and Walther J. V. (1990) Kaolinite dissolution at 25, 60, and 80°C. Amer. J. Sci. 290, 797-810.
13. Cases J. M., Cunin P., Grillet Y., Poinsignon C., and Yvon J. (1986) Methods of analysing morphology of kaolinites: Relations between crystallographic and morphological properties. Clay Minerals 21, 55-68.
14. Casey W. H., Westrich H. R., and Arnold G. W. (1988) Surface chemistry of labradorite feldspar reacted with aqueous solutions at pH 2, 3, and 12. Geochim. Cosmochim. Acta 52, 2795-2807.
15. Casey W. H., Westrich H. R., Massis T., Banfiles J. F., and Arnold G. W. (1989) The surface chemistry of labradorite feldspar after acid hydrolysis. Chem. Geol. 78, 205-218.
16. Castet S., Dandurand J. L., Schott J., and Gout R. (1993) Boehmite solubility and aqueous aluminum speciation in hydrothermal solutions (90-350°C): Experimental study and modeling. Geochim. Cosmochim. Acta 57, 4869-4884.
17. Chen Y. and Brantley S. L. (1997) Temperature-and pH-dependence of albite dissolution rate at acid pH. Chem. Geol. 135, 275-290.
18. De Endredy A. S. (1963) Estimation of free iron oxides in soils and clays by a photolythic method. Clays Mineral. Bull. 5, 209-217.
19. Deer W. A., Howie R. A., and Zussman J. (1982) An Introduction to the Rock Forming Minerals. Longman.
20. Devidal J. L., Dandurand J. L., and Schott J. (1992) Dissolution and precipitation kinetics of kaolinite as a function of chemical affinity (T = 150°C, pH = 2 and 7.8). In Water Rock Interaction (ed. Y. K. Kharaka et al.), pp. 93-96. Balkema.
21. Devidal J. L., Dandurand J. L., and Gout R. (1996) Gibbs free energy of formation of kaolinite from solubility measurement in basic solution between 60 and 170°C. Geochim. Cosmochim. Acta 60, 553-564.
22. Dietzel M. and Udowski E. (1995) Depolymerization of soluble silicate in dilute aqueous solutions. Colloid Polym. Sci. 273, 590-597.
23. Dougan W. K. and Wilson A. J. (1974) The absorptiometric determination of aluminum in water. A comparison of some chromogenic reagents and the development of an improved method. Analyst 99, 413-430.
24. Dove P. and Crerar D. A. (1990) Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal reactor. Geochim. Cosmochim. Acta 54, 955-969.
25. Fischer J. R. and Barnes H. L. (1972) The ion product constant of water to 350°C. J. Phys. Chem. 76, 90-99.
26. Fowler R. and Guggenheim E. A. (1939) Statistical Thermodynamics. Univ. Press.
27. Franks S. G. and Forester R. W. (1984) Relationships among secondary porosity, pore-fluid chemistry and carbon dioxide, Texas Gulf Coast. In Clastic Diagenesis (ed. D. A. McDonald and R. C. Surdam); AAPG Mem. 37, 63-79.
28. Franks S. G. and Forester R. W. (1984) Relationships among secondary porosity, pore-fluid chemistry and carbon dioxide, Texas Gulf Coast. In Clastic Diagenesis (ed. D. A. McDonald and R. C. Surdam); AAPG Mem. 37, 63-79.
29. Ganor J., Mogollon J. L., and Lasaga A. C. (1995) The effect of pH on kaolinite dissolution rates and on activation energy. Geochim. Cosmochim. Acta 59, 1037-1052.
30. Gautier J.-M., Oelkers E. H., and Schott J. (1994) Experimental study of K-feldspar dissolution rates as a function of chemical affinity at 150°C and pH 9. Geochim. Cosmochim. Acta 58, 4549-4560.
31. Helgeson H. C. and Kirkham D. H. (1974) Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures. I. Summary of the thermodynamic/ electrostatic properties of the solvent. Amer. J. Sci. 274, 1089-1198.
32. Hinckley D. N. (1963) Variability in crystallinity values among the kaolin deposits of the coastal plain of Georgia and South Carolina. Clays Clay Mineral. 11, 229-235.
33. Huang W. L. (1993) Stability and kinetics of kaolinite to boehmite conversion under hydrothermal conditions. Chem. Geol. 105, 197-214.
34. Iler R. K. (1979) Chemistry of Silica - Solubility, Polymerisation, Colloid and Surface Properties and Biochemistry. Wiley Interscience.
35. Kittrick J. A. (1966) Free energy of formation of kaolinite from solubility measurements. Amer. Mineral. 51, 1457-1466.
36. Koroleff F. (1976) Determination of silicon. In Methods of Seawater Analysis (ed. K. Grasshoff), pp. 148-158.
37. Labrid J. and Duquerroix J. P. (1991) Thermodynamic and kinetic aspects of the dissolution of quartz-kaolinite mixtures by alkalis. Rev. Inst. Français Pétr. 30, 67-74.
38. Lasaga A. C. (1981) Transition State Theory. In Kinetics of Geochemical Processes (ed. A. C. Lasaga and R. J. Kirkpatrick); Rev. Mineral. 8, 135-169.
39. Lasaga A. C. (1981) Transition State Theory. In Kinetics of Geochemical Processes (ed. A. C. Lasaga and R. J. Kirkpatrick); Rev. Mineral. 8, 135-169.
40. Lasaga A. C. (1995) Fundamental approaches in describing mineral dissolution and precipitation rates. In Chemical Weathering Rates of Silicate Minerals (eds. A. F. White and S. L. Brantley); Rev. Mineral. 31, 23-86.
41. Lasaga A. C. (1995) Fundamental approaches in describing mineral dissolution and precipitation rates. In Chemical Weathering Rates of Silicate Minerals (eds. A. F. White and S. L. Brantley); Rev. Mineral. 31, 23-86.
42. Lietard O. (1977) Contribution à l'étude des propriétés physicochimiques, cristallochimiques et morphologiques des kaolins. Thèse de Doctorat, Nancy.
43. Murphy W. M., Pabalan R. T., Prikryi J. D., and Goulet C. J. (1996) Reaction kinetics and thermodynamics of dissolution and growth of analcime and clinoptilolite. Amer. J. Sci. 296, 128-186.
44. Nagy K. L. (1995) Dissolution and precipitation kinetics of sheet silicates In Chemical Weathering Rates of Silicate Minerals (ed. A. F. White and S. L. Brantley); Rev. Mineral. 31, 173-225.
45. Nagy K. L. (1995) Dissolution and precipitation kinetics of sheet silicates In Chemical Weathering Rates of Silicate Minerals (ed. A. F. White and S. L. Brantley); Rev. Mineral. 31, 173-225.
46. Nagy K. L., Blum A. E., and Lasaga A. C. (1991) Dissolution and precipitation kinetics of kaolinite at 80°C and pH 3: The dependence on solution saturation state. Amer. J. Sci. 291, 649-686.
47. Naumov J. D., Ryhzenko B. N., and Khodakovsky I. L. (1974) Handbook of thermodynamic data. U.S. Geol. Survey, Report N°PB226-722.
48. Nielsen A. E. and Toft J. M. (1984) Electrolyte crystal growth kinetics. J. Cryst. Growth 67, 278-288.
49. Oelkers E. H. (1996) Properties of rocks and fluids for mass transport calculations. In Reactive Transport in Porous Media (ed. P. C. Lichtner et al.); Rev. Mineral. 34, 132-191.
50. Oelkers E. H. (1996) Properties of rocks and fluids for mass transport calculations. In Reactive Transport in Porous Media (ed. P. C. Lichtner et al.); Rev. Mineral. 34, 132-191.
51. Oelkers E. H. and Schott J. (1994) Experimental study of kyanite dissolution rates as a function of Al and Si concentration. Mineral. Mag. 58A, 659-660.
52. Oelkers E. H. and Schott J. (1995) The dissolution and the crystallization rates of silicate minerals as a function of their structure and composition. In Water Rock Interaction (ed. Y. K. Kharaka and O. V. Chudaev), pp. 153-156. Balkema.
53. Oelkers E. H. and Schott J. (1997) Experimental study of kyanite dissolution rates as a function of chemical affinity and solution composition. Geochim. Cosmochim. Acta (submitted).
54. Oelkers E. H., Schott J., and Devidal J. L. (1994) The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions. Geochim. Cosmochim. Acta 58, 2011-2024.
55. Oelkers E. H., Schott J., Ward D. B., Brady P. V., and Gout R. (1995) The dissolution rates of single and multi-(hydr)oxide silicate minerals. I: Experimental observations. GSA Abstr. Prog. 27, A-43 (abstr.).
56. Polzer W. L. and Hem J. D. (1965) The dissolution of kaolinite. J. Geophys. Res. 70, 24, 6233-6240.
57. Prigogine I. and Defay R. (1950) Thermodynamique Chimique. Desoer.
58. Read A. J. (1982) Ionization constants of aqueous ammonia from 25 to 250°C and to 2000 bars. J. Soln. Chem. 11, 649-664.
59. Rimstidt J. D. and Barnes H. L. (1980) The kinetics of silica-water interactions. Geochim. Cosmochim. Acta 44, 1683-1700.
60. Schott J. and Oelkers E. H. (1995) Dissolution and crystallization rates of silicate minerals as a function of chemical affinity. Pure Appl. Chem. 67, 903-910.
61. Schweda P. (1990) Kinetics and mechanisms of alkali feldspar dissolution at low temperatures. PhD Thesis, Stockholm Univ.
62. Scofield J. H. (1976) Hartree-Slater sub-shell photoionization cross sections at 1254 and 1487 eV. J. Electro. Spectros. Related Phenom. 8, 129-137.
63. Siever R. and Woodford N. (1973) Sorption of silica by clay minerals. Geochim. Cosmochim. Acta 37, 1851-1830.
64. Sillen L. G. and Martell A. E. (1971) Stability Constants of Metal-Ion Complexes. Supplement No1. Chem. Soc.
65. Soong C. (1993) Hydrothermal kinetics of kaolinite-water interaction at pH 4.2 and 7.3, 130°C to 230°C. PhD. Thesis. Penn. State Univ.
66. Stumm W. (1992) Chemistry of the Solid-Water Interface. Wiley.
67. Stumm W. and Wieland E. (1990) Dissolution of oxide and silicate minerals: Rates depend on surface speciation. In Aquatic Chemical Kinetics (ed. W. Stumm), pp. 367-400. Wiley.
68. Tanger J. C. and Helgeson H. C. (1988) Revised equation of state for the standard partial molal properties of ions and electrolytes. Amer. J. Sci. 288, 19-98.
69. 3 colloids. Environ. Sci. Tech. 22, 37-41.
70. Walderhaug O. (1994) Precipitation rates for quartz cement in sandstones determined by fluid-inclusion microthermometry and temperature-history modelling. J. Sediment. Res. A64, 324-333.
71. Wieland E. and Stumm W. (1992) Dissolution kinetics of kaolinite in acidic aqueous solutions at 25°C. Geochim. Cosmochim. Acta 56, 3339-3355.
72. Wieland E., Werhli B., and Stumm W. (1988) The coordination chemistry of weathering: III. A potential generalization on dissolution rates of minerals. Geochim. Cosmochim. Acta 52, 1969-1981.
73. Wollast R. and Chou L. (1985) Kinetic study of the dissolution of albite with a continuous flow-through reactor. In The Chemistry of Weathering (ed. J. Drever) pp. 75-96. D. Reidel Publ. Co.
74. Xie Z. and Walther J. V. (1992) Incongruent dissolution and surface area of kaolinite. Geochim. Cosmochim. Acta 56, 3357-3363.