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Briefly, the preparation method comprises the following processes: 5 mg of glass spheres (Polyscience Inc.) are treated for 10 min in 3% solution of (3-mercaptopropyl)trimethoxysilane (MPTS) in toluene at 80°C under vigorous stirring followed by a 4-fold washing in fresh toluene. This procedure results in a near monolayer of MPTS on the surface of the glass spheres. Then the spheres with the MPTS-activated surface are mixed with a highly diluted colloidal solution of (CdSe)ZnS quantum dots in toluene. Under stirring, the (CdSe)-ZnS dots are bound to the surface of glass spheres via formation of S-Zn chemical bonds between surface Zn atoms and MPTS mercapto groups.
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