Efficient Copper-Catalyzed Chemo Selective Conjugate Addition of Aliphatic Amines to α,β-Unsaturated Compounds in Water

Synlett

Volumn , Issue 15, 2003, Pages 2425-2427

  Xu, Li Wen ^a   Li, Jing Wei ^a   Xia, Chun Gu ^a   Zhou, Shao Lin ^a   Hu, Xiao Xue ^a  

^a LANZHOU INSTITUTE OF CHEMICAL PHYSICS   (China)

Author keywords

Amines; Conjugate addition; Copper; Water; unsaturated compounds

Indexed keywords

ACETONITRILE; ALIPHATIC AMINE; COPPER; PIPERIDINE; WATER;

AMINATION; ARTICLE; CATALYST; CONJUGATE; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; MICHAEL ADDITION; SYNTHESIS; TEMPERATURE;

EID: 0346749656     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-42125     Document Type: Article

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46. 2O was kept at r.t. under vigorous stirring for 12 h. After completion of the reaction, the reaction mixture was extracted with EtOAc and purified by using column chromatography on silical gel to obtain pure product. All the known compounds were fully characterized by GC-MS (Agilent 6890N GC/5973N MS, HP-5MS) and usual spectral methods.