Stereoselective Synthesis of Di- and Trisubstituted Aminoalkenes: Tandem Isomerization/Aza-Claisen Rearrangement/Hydride Reduction Sequence

Synlett

Volumn , Issue 15, 2003, Pages 2380-2382

  Honda, Kiyoshi ^a   Yasui, Hiroto ^a   Inoue, Seiichi ^a  

^a YOKOHAMA NATIONAL UNIVERSITY   (Japan)

Author keywords

Base induced aza Claisen rearrangements; N ylides; Reductions; Stereoselective aminoalkene synthesis; Tandem reactions

Indexed keywords

ALCOHOL; ALKENE DERIVATIVE; AMINE; HETEROCYCLIC COMPOUND; LITHIUM BOROHYDRIDE; N PROPYNYL N BETA METHALLYL DIMETHYLAMMONIUM DERIVATIVE; QUATERNARY AMMONIUM DERIVATIVE; REDUCING AGENT; SODIUM BOROHYDRIDE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CLAISEN REARRANGEMENT; COLUMN CHROMATOGRAPHY; INFRARED SPECTROSCOPY; ISOMERISM; PROTON NUCLEAR MAGNETIC RESONANCE; REDUCTION; STEREOCHEMISTRY; SYNTHESIS;

EID: 0346119070     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-42106     Document Type: Article

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40. 3): δ = 34.3, 36.0, 37.2, 45.4, 65.4, 112.5, 125.7, 128.2, 128.4, 131.3, 142.0, 146.3.
41. 3): δ = 13.3, 34.4, 36.1, 38.8, 45.4, 57.8, 122.9, 125.6, 128.2, 128.5, 129.1, 130.8, 136.6, 142.1.