Spectroscopic and Computational Investigations of Stable Radical Anions of Triosmium Benzoheterocycle Clusters

Chemistry - A European Journal

Volumn 9, Issue 23, 2003, Pages 5749-5756

  Nervi, Carlo ^a   Gobetto, Roberto ^a   Milone, Luciano ^a   Viale, Alessandra ^a   Rosenberg, Edward ^b   Rokhsana, Dalia ^b   Fiedler, Jan ^c  

^a UNIVERSITY OF TURIN   (Italy)

^b UNIVERSITY OF MONTANA   (United States)

^c J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

Author keywords

Cluster compounds; Electron transfer; Electron deficient compounds; Osmium; Radical ions

Indexed keywords

CHARGE TRANSFER; COMPLEXATION; ELECTROLYSIS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROBABILITY DENSITY FUNCTION; REDUCTION; RELAXATION PROCESSES;

LIGANDS; NUCLEOPHILES;

AROMATIC COMPOUNDS;

ANION; BENZENE DERIVATIVE; BENZO[F]QUINOLINE; COBALT DERIVATIVE; COBALTOCENE; HETEROCYCLIC COMPOUND; OSMIUM DERIVATIVE; PHENANTHRIDINE DERIVATIVE; QUINOLINE DERIVATIVE; QUINOXALINE DERIVATIVE; RADICAL; SODIUM; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CARBON NUCLEAR MAGNETIC RESONANCE; DENSITY FUNCTIONAL THEORY; ELECTROLYSIS; ELECTRON; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; IMAGE ANALYSIS; LOW TEMPERATURE; PREDICTION; PROTON NUCLEAR MAGNETIC RESONANCE; REDUCTION; ROOM TEMPERATURE; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE; TEMPERATURE SENSITIVITY;

ANIONS; BENZENE; COMPUTATIONAL BIOLOGY; HETEROCYCLIC COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; OSMIUM COMPOUNDS; PHENANTHRIDINES; QUINOLINES;

EID: 0345732176     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305198     Document Type: Article

References (27)

1. E. Arcia, D. S. Kolwaite, E. Rosenberg, K. Hardcastle, J. Ciurash, R. Duque, R. Gobetto, L. Milone, D. Osella, M. Botta, W. Dastru, A. Viale, J. Fiedler, Organometallics 1998, 17, 415-426.
2. M. J. Abedin, B. Bergman, R. Holmquist, R. Smith, E. Rosenberg, J. Ciurash, K. Hardcastle, J. Roe, V. Vazquez, C. Roe, S. Kabir, B. Roy, S. Alam, K. A. Azam, Coord. Chem. Rev. 1999, 192, 975-1002.
3. B. Bergman, R. Holmquist, R. Smith, E. Rosenberg, J. Ciurash, K. Hardcastle, M. Visi, J. Am. Chem. Soc. 1998, 120, 12818-12828.
4. R. Smith, E. Rosenberg, Organometallics 1999, 18, 3519-3527.
5. A. Bar Din, B. Bergman, E. Rosenberg, R. Smith, W. Dastru, R. Gobetto, L. Milone, A. Viale, Polyhedron 1998, 17, 2975-2984.
6. E. Rosenberg, M. J. Abedin, D. Rokhsana, D. Osella, L. Milone, C. Nervi, J. Fiedler, Inorg. Chim. Acta 2000, 300, 769-777.
7. E. Rosenberg, M. J. Abedin, D. Rokhsana, A. Viale, W. Dastru', R. Gobetto, L. Milone, K. Hardcastle, Inorg. Chim. Acta 2002, 334, 343-354.
8. M. J. Abedin, Ph D Thesis, University of Montana. 2002.
9. P. V. Schleyer, B. Kiran, D. V. Simion, T. S. Sorensen, J. Am. Chem. Soc. 2000, 122, 510-513.
10. M. P. Brown, P. A. S. Dolby, M. M. Harding, A. J. Mathews, A. K. Smith, D. Osella, M. Arbrun, R. Gobetto, J. Chem. Soc. Dalton Trans. 1993, 827-834.
11. N. G. Connelly, W. E. Geiger, Chem. Rev. 1996, 96, 877-910.
12. J. L. Robbins, N. Edelstein, B. Spencer, J. C. Smart, J. Am. Chem. Soc. 1982, 104, 1882-1893.
13. E. De Boer, C. MacLean, J. Chem. Phys. 1966, 44, 1334-1342.
14. N. Sutin, Acc. Chem. Res. 1968, 1, 225-231.
15. J. A. Weil, J. R. Bolton, J. E. Wertz, Electron Paramagnetic Resonance, Wiley-Interscience, New York, 1994.
16. L. N. Holy, Chem. Rev. 1974, 74, 243-277.
17. W. Koch, M. C. Holthausen, A Chemist's Guide to Density Functional Theory, Wiley-VCH, Weinheim, 2001.
18. F. Jensen, Introduction to Computational Chemistry, Wiley, Chichester, 1999.
19. J. F. Rihel, N. Koga, K. Morokuma, Organometallics 1993, 12, 4788-4798.
20. M. J. Calhorda, E. Hunstock, L. F. Veiros, F. Hartl, Eur. J. Inorg. Chem. 2001, 223-231.
21. M. Turki, C. Daniel, S. Zalis, A. Vlcek, J. van Slageren, D. J. Stufkens, J. Am. Chem. Soc. 2001, 123, 11431-11440.
22. P. J. Hay, J. Phys. Chem. A 2002, 106, 1634-1641.
23. M. Rance, O. W. Sørensen, G. Bodenhausen, G. Wagner, R. R. Ernst, K. Wüthrich, Biochem. Biophys. Res. Commun. 1983, 117, 479-485.
24. W. E. Geiger, Organometallic Radical Processes, Elsevier, Amsterdam, 1990, p. 144.
25. Gaussian 98 (Revision A.9), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, Jr., R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, A. G. Baboul, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian, Inc., Pittsburgh PA, 1998.
26. A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652.
27. C. Lee, W. Yang, R. G. Parr, Phys. B 1988, 37, 785.