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0344225439
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The excitation wavelength for both gels and sols is 320 nm where there is similar optical density for both forms; fluorescence intensities are compared at their respective maxima (Figure 1)
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The excitation wavelength for both gels and sols is 320 nm where there is similar optical density for both forms; fluorescence intensities are compared at their respective maxima (Figure 1).
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0344656876
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note
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The highly oriented pyrolitic graphite (HOPG) substrate was spotted with hot gelator solution and allowed to cool in a sealed chamber for 45 min. Under these conditions minimal evaporation was observed. Both pure solvent and the solvent-gelator solution completely "wet" this substrate. We estimate the film thickness to be 5-10 mM; under these conditions we presume that dewetting plays little role in the structure formation observed. The images were obtained in the tapping mode.
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30
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84989729992
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31
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0345087723
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The concentration of the gelator is critical for obtaining these "fibers"; at lower concentrations the gels are not sufficiently stable, while at higher concentrations it is difficult to "pull" out the strings. The fibers are relatively elastic and easily distorted by pressure
-
The concentration of the gelator is critical for obtaining these "fibers"; at lower concentrations the gels are not sufficiently stable, while at higher concentrations it is difficult to "pull" out the strings. The fibers are relatively elastic and easily distorted by pressure.
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32
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0344225440
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note
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In the case of 4 we actually observe a small decrease in fluorescent lifetime upon gelation, which may suggest an increase in self- or impurity-quenching which might be attributed to an increase in concentration upon gelation as pure solvent is incorporated into the "scaffolding" while the remaining "solution" is enriched in solute.
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35
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Manabe, O.4
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