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Volumn 15, Issue 7, 1999, Pages 2391-2397

Influence of surface modifiers on the thermal decomposition of methanethiol on Fe(110)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CHEMICAL BONDS; IRON; MONOLAYERS; PYROLYSIS; SULFUR COMPOUNDS; SURFACE PHENOMENA; SURFACE TREATMENT; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 0345534671     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la971313j     Document Type: Article
Times cited : (16)

References (37)
  • 27
    • 0345550092 scopus 로고    scopus 로고
    • note
    • For simplicity, the S(2p) binding energy will represent the S2p-(3/2) component of the doublet.
  • 32
    • 0344256269 scopus 로고    scopus 로고
    • note
    • a species, as a result of background hydrogen adsorption, since the intensity of this feature is attenuated upon heating the crystal above room temperature.
  • 33
    • 0345118743 scopus 로고    scopus 로고
    • note
    • While this is the same peak position for atomic sulfur following decomposition of methanethiol on Fe(110)-p(2 × 2)-S, the peak is much too large to be attributed to cleavage of the C-S bond at 100 K, which on the clean surface is less than 20%.
  • 34
    • 0345550085 scopus 로고    scopus 로고
    • note
    • The evolution of methyl radical was confirmed by deconvolution of the m/e = 15 peak area with the associated cracking area for pure methane which in this case was 0.83 for m/e. 15:16 ratio. This compensates for any signal in m/e = 15 that may be associated with fragmentation of methane.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.