메뉴 건너뛰기




Volumn 38, Issue 1-2, 1999, Pages 166-168

Insertion of O2 into a chromium-phenyl bond: Mechanism of formation of the paramagnetic d2 oxo complex [Tp(tBu,Me)Cr(IV)(O)OPh]

Author keywords

Chromium; Insertions; O O activation; Oxygenations; Tripodal ligands

Indexed keywords

CHROMIUM DERIVATIVE; OXYGEN;

EID: 0345390160     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990115)38:1/2<166::AID-ANIE166>3.0.CO;2-E     Document Type: Article
Times cited : (40)

References (22)
  • 10
    • 0344712738 scopus 로고    scopus 로고
    • note
    • 1: of 10127 reflections collected, 4572 were independent and 2593 observed; 364 parameters, SHELXTL software (Version 5.03), R(F) = 0.0658, R(wF) = 0.1137 [I > 2σ(I)], 4 < 2θ ≤ 57. The data were collected on a Siemens P4 diffractometer equipped with a SMART/CCD detector. No absorption correction was required. The hydrogen atom on boron was located from the difference map, the thermal parameter was fixed and the coordinates were allowed to refine. All other hydrogen atoms were treated as idealized contributions. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101985. Copies of the data can be obtained free of charge on application to CCDC. 12 Union Road. Cambridge CB21EZ, UK (fax: (+44)1223-336-033: e-mail: deposit@ccdc.cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.