The First Silver-Catalyzed Three-Component Coupling of Aldehyde, Alkyne, and Amine

Organic Letters

Volumn 5, Issue 23, 2003, Pages 4473-4475

  Wei, Chunmei ^a   Li, Zigang ^a   Li, Chao Jun ^a,b  

^a Tulane University   (United States)

^b MCGILL UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALKYNE; AMINE; SILVER;

ARTICLE; CATALYSIS; CHEMICAL REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTITATIVE ANALYSIS;

EID: 0344496729     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol035781y     Document Type: Article

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28. 1H NMR showed a quantitative conversion of aldehyde. The product was isolated by flash chromatography on silica gel (eluent: hexanes-EtOAc) to give propargylamine in almost quantitative yield (540 mg, 96%).