Role of Entropy in Increased Rates of Intramolecular Reactions

Journal of the American Chemical Society

Volumn 125, Issue 47, 2003, Pages 14596-14602

  Armstrong, Anthony A ^a   Amzel, L Mario ^a  

^a JOHNS HOPKINS UNIVERSITY SCHOOL OF MEDICINE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

INTRAMOLECULAR REACTIONS;

ACTIVATION ENERGY; CONDENSATION; CONFORMATIONS; ENTROPY; ESTERS; GROUND STATE; MOLECULAR VIBRATIONS; RATE CONSTANTS;

CARBOXYLIC ACIDS;

DICARBOXYLIC ACID;

ARTICLE; CONFORMATION; DIELECTRIC CONSTANT; ENTROPY; GEOMETRY; POLYMERIZATION;

EID: 0344012142     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0344359     Document Type: Article

References (18)

1. Lightstone, F. C.; Bruice. T. C. J. Am. Chem. Soc. 1996, 118, 8, 2595.
2. Bruice, T. C.; Lightstone, F. C. Acc. Chem. Res. 1999, 32, 2, 127.
3. Jencks. W. P. Catalysis in Chemistry and Enzymology; McGraw-Hill: New York, 1969.
4. Schultz, P. G. Acc. Chem. Res. 1989, 22, 2. 287.
5. Bruice, T. C.; Brown, A.; Harris, D. O. Proc. Natl. Acad. Sci. U.S.A. 1971, 68, 658.
6. Page, M. I.; Jencks W. P. Proc. Natl. Acad. Sci. U.S.A. 1971, 68, 1678.
7. Villa, J.; Strajbl, M.; Glennon, T. M.: Sham, Y. Y.; Chu, Z. T.: Warshel, A. Proc. Natl. Acad. Sci. U.S.A. 2000, 97, 11899.
8. Menger, F. M. Acc. Chem. Res. 1985, 18, 8, 128.
9. Bruice, T. C.; Pandit, U.K. J. Am. Chem. Soc. 1960, 82, 2, 5858.
10. Bruice. T. C.; Bradbury, W. C. J. Am. Chem. Soc. 1968, 90, 3808.
11. Karplus, M.; Kushick, J. N. Macromolecules 1981, 14, 325.
12. Lee, K. H.; Xie, D.; Freire, E.; Amzel, L. M. Proteins: Struct., Funct., Genet. 1994, 20, 68.
13. D'Aquino, J. A.; Freire, E.; Amzel, L. M. Proteins: Struct., Funct., Genet. 2000, Suppl 4, 93.
14. Brooks, B. R.: Bruccoleri, R. E.: Olafson, B. D.; States. D. J.; Swaminathan, S.; Karplus, M. J. Comput. Chem. 1983, 4, 187.
15. Smith, J. C.; Karplus M. J. Am. Chem. Soc. 1992, 114, 801.
16. Creamer, T. P.; Rose, G. D. Proc. Natl. Acad. Sci. U.S.A. 1992, 89, 5937.
17. Akhadov, Y. Y. Dielectric Properties of Binary Solutions; Pergamon Press: Oxford. 1981.
18. Milstien, S.; Cohen, L. A. J. Am. Chem. Soc. 1972, 94, 9158.