Potentiometric determination of cadmium-acetate complexation in aqueous solutions to 250°C

Chemical Geology

Volumn 167, Issue 1-2, 2000, Pages 11-24

  Bénézeth, Pascale ^a   Palmer, Donald A ^a  

^a OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Acetate; Cadmium; Formation quotients; Potentiometry; Thermodynamic properties

Indexed keywords

ACETATE; AQUEOUS SOLUTION; CADMIUM; THERMODYNAMICS;

EID: 0343527977     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(99)00197-7     Document Type: Conference Paper

References (53)

1. Aditya S., Prasad B. Studies on the behaviour of bi-univalent salts in aqueous solution: Part V. Cadmium acetate. J. Indian Chem. Soc. 30:1953;255-260.
2. Archer D.W., Monk C.B. Ion-association constants of some acetates by pH (glass electrode) measurements. J. Chem. Soc. 1963;3117-3122.
3. Baes C.F., Mesmer R.E. Jr. The hydrolysis of cations. 1976;Wiley, New York. 489 pp.
4. Bardhan S., Aditya S. Ionic equilibria in solution: Part I. Cadmium acetate in aqueous solution. J. Indian Chem. Soc. 32:1955;102-104.
5. Bénézeth P., Castet S., Dandurand J.L., Gout R., Schott J. Experimental study of aluminum-acetate complexing between 60 and 200°C. Geochim. Cosmochim. Acta. 58:1994;4561-4571.
6. Bénézeth P., Palmer D.A., Wesolowski D.J. The aqueous chemistry of aluminum. A new approach to high-temperature solubility measurements. Geothermics. 26:1997;465-481.
7. 2+. Acta Chem. Scand. 16:1962;2221-2239.
8. Boily J.F., Fein J.B. Experimental study of cadmium-citrate co-adsorption onto α-Al2O3. Geochim. Cosmochim. Acta. 60:1996;2929-2938.
9. Bradley D.J., Pitzer K.S. Thermodynamics of electrolytes: 12. Dielectric properties of water and Debye-Hückel parameters to 350°C and l kbar. J. Phys. Chem. 83:1979;1599-1603.
10. Busing, W.R., Levy, H.A., 1962. A general fortran least squares program, Oak Ridge National Laboratory Report ORNL-TM-271, RNL-TM-271.
11. Carothers W.W., Kharaka Y.K. Aliphatic acid anions in oil field-waters and their implications for the origin of natural gas. Bull. Am. Assoc. Pet. Geol. 62:1978;2441-2453.
12. Choudhary B.K., Prasad B. Ionic equilibria in aqueous solutions of cadmium acetate and the related thermodynamic functions. J. Ind. Chem. 1975;679-684.
13. 3 solubilities (25 to 150°C), and La-acetate complexing (25 to 80°C). Chem. Geol. 151:1998;349-372.
14. Fabes L., Swaddle T.H. Reagents for high temperature aqueous chemistry: Trifluoromethanesulfonic acid and its salts. Can. J. Chem. 53:1975;3053-3059.
15. Fein J.B. Experimental study of Al-, Ca- and Mg-acetate complexing at 80°C. Geochim. Cosmochim. Acta. 55:1991;955-964.
16. Ferrell E., Ridgion J.M., Riley H.L. A potentiometric investigation of electrolytic dissociation: Part II. Copper and cadmium carboxylic salts. J. Chem. Soc. 1934;1440-1447.
17. Gammons C.H., Seward T.M. Stability of manganese (II) chloride complexes from 25 to 300°C. Geochim. Cosmochim. Acta. 60:1996;4295-4311.
18. Gerding P. Thermochemical studies on metal complexes. Acta Chem. Scand. 22:1968;1283-1296.
19. GESAMP, 1984. IMO/FAO/UNESCO/WMO/IAEA/UN/UNEP Joint Group of Experts on the Scientific Aspects of Marine Pollution: Report of the fourteenth Session, Vienna, 20-30 March 1984, Vienna. International Atomic Energy Agency, Reports and studies no. 21.
20. GESAMP, 1987. IMO/FAO/UNESCO/WMO/IAEA/UN/UNEP Joint Group of Experts on the Scientific Aspects of Marine Pollution: Report of the seventeenth Session, Rome. Geneva, World Health Organization, Reports and studies no. 31.
21. 4) solubility in acetate solutions: the determination of stability constants for lead acetate complexes to 85°C. Geochim. Cosmochim. Acta. 53:1989;359-366.
22. Giordano T.H., Drummond S.E. The potentiometric determination of stability constants for zinc acetate complexes in aqueous solutions to 295°C. Geochim. Cosmochim. Acta. 55:1991;2401-2415.
23. Hahne H.C.H., Kroontje W. Significance of pH and chloride concentration of behavior of heavy metal pollutants: mercury (II), cadmium (II), zinc (II) and lead (II). J. Environ. Qual. 2:1973;444-450.
24. Heinrichs H., Schulz-Dobrick, Wedepohl K.L. Terrestrial geochemistry of Cd, Bi, Tl, Pb, Zn and Rb. Geochim. Cosmochim. Acta. 44:1980;1519-1532.
25. Hellwege H.E., Schweitzer G.K. The determination of association constants of aqueous cadmium complexes by a chelate solvent extraction method. J. Inorg. Nucl. Chem. 27:1965;99-104.
26. Hennet R.J.C., Crerar D.A., Schwartz J. Organic complexes in hydrothermal systems. Econ. Geol. 83:1988;742-764.
27. Ho P.C., Palmer D.A. Electrical conductances of aqueous sodium trifluoromethanesulfonate from 0 to 450°C and pressures to 250 MPa. J. Sol. Chem. 24:1995;753-769.
28. Hutchinson M.H., Higginson W.C.E. Stability constants for association between bivalent cations and some univalent anions. J. Chem. Soc. 1973;1247-1253.
29. Kettler R.M., Palmer D.A., Wesolowski D.J. Dissociation quotients of oxalic acid in aqueous sodium chloride media to 175°C. J. Sol. Chem. 20:1991;905-927.
30. Kolat R.S., Powell J.E. Acetate complexes of the rare earth and several transition metal ions. Inorg. Chem. 1:1962;293-296.
31. Mesmer R.E. Comment on "A new approach to measuring pH in brines and other concentrated electrolytes" Knaves K.G., Wolery T.J., Jackson K.J. Geochim. Cosmochim. Acta. 55:1991;1175-1176.
32. Mesmer R.E., Patterson C.S., Sweeton F.H. Acidity measurements at elevated temperatures: IV. Apparent dissociation product of water in 1 m potassium chloride up to 292°C. J. Phys. Chem. 74:1970;1937-1942.
33. Mesmer R.E., Palmer D.A., Simonson J.M. Ion association at high temperatures and pressures. Pitzer K.S. Activity coefficients in electrolyte solutions. 1991;491 CRC Press.
34. Namasivayam C., Ranganathan K. Effect of organic ligands on the removal of Pb(II), Ni(II) and Cd(II) by 'waste' Fe(III)/Cr(III) hydroxide. Water Res. 32:1998;969-971.
35. Palmer D.A., Bell J.L.S. Aluminum speciation and equilibria in aqueous solution: IV. A potentiometric study of aluminum acetate complexation in acidic NaCl brines to 150°C. Geochim. Cosmochim. Acta. 58:1994;651-659.
36. Palmer D.A., Drummond S.E. Potentiometric determination of the molal formation constants of ferrous acetate complexes in aqueous solutions to high temperatures. J. Phys. Chem. 92:1988;6795-6800.
37. Palmer D.A., Drummond S.E. The molal dissociation quotients of water in sodium trifluoromethanesulfonate solutions to high temperatures. J. Sol. Chem. 17:1988;153-164.
38. Palmer D.A., Hyde K.E. An experimental determination of ferrous chloride and acetate complexation in aqueous solutions to 300°C. Geochim. Cosmochim. Acta. 57:1993;1393-1408.
39. Pitzer K.S. Thermodynamics of electrolytes: I. Theoretical basis and general equations. J. Phys. Chem. 77:1973;268-277.
40. Quist A.S., Marshall W.L. Assignment of limiting equivalent conductances for single ions to 400°C. J. Phys. Chem. 69:1965;2984-2987.
41. Scott A., Taube H. Complexing tendency of trifluoromethanesulfonate ion as measured using chromium (III). Inorg. Chem. 3:1971;191-214.
42. 2O and acetate solutions at 100-350°C and 500 bars: Constraints on calcium hydroxide and calcium acetate complex stability. Geochim. Cosmochim. Acta. 55:1991;659-669.
43. Semmler J., Irish D.E., Ozeki T. Vibrational spectral studies of solutions at elevated temperatures and pressures: 12. Magnesium acetate. Geochim. Cosmochim. Acta. 54:1990;947-954.
44. Shock E.L., Helgeson H.C. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Correlation algorithms for ionic species and equation of state predictions to 5 kb and 1000°C. Geochim. Cosmochim. Acta. 53:1988;2009-2036.
45. Shock E.L., Helgeson H.C. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: standard partial molal properties of organic species. Geochim. Cosmochim. Acta. 54:1990;915-945.
46. Shock E.L., Koretsky C.M. Metal-organic complexes in geochemical processes: Calculation of standard partial molal thermodynamic properties of aqueous acetate complexes at high pressures and temperatures. Geochim. Cosmochim. Acta. 57:1993;4899-4922.
47. Sverjensky D.A., Shock E.L., Helgeson H.C. Prediction of the thermodynamic properties of aqueous metal complexes to 1000°C and 5 kb. Geochim. Cosmochim. Acta. 61:1997;1359-1412.
48. Tanaka N., Kamada M., Osawa H., Satô G. The formation constants of metal acetate complexes: III. Polarographic determination of the formation constants of acetatocadmium (II) and acetatocobalt (II) complexes. Bull. Chem. Soc. Jpn. 33:1960;1412-1416.
49. Willey L.M., Kharaka Y.K., Presser T.S., Rapp J.B., Barnes I. Short chain aliphatic acid anions in oil field waters and their contribution to the measured alkalinity. Geochim. Cosmochim. Acta. 39:1975;1707-1711.
50. Wilson, B., 1988. Investigation of trace metals in the aqueous environment: Final report (January 1986-December 1987), Houston, Texas Southern University. p. 28. Report No. DOE/CH/10255-T1, prepared for the US Department of Energy, Washington.
51. 3+ complexation with acetate in 0.1 molal NaCl solution from 25-250°C. Chem. Geol. 1999;. this volume.
52. Yang M., Crerar D.A., Irish D.E. A Raman spectroscopic study of lead and zinc acetate complexes in hydrothermal solutions. Geochim. Cosmochim. Acta. 53:1989;319-326.
53. Yasuda M., Yamasaki K., Ohtaki H. Stability of complexes of several carboxylic acids formed with bivalent metals. Bull. Chem. Soc. Jpn. 33:1960;1067-1070.