Density functional study of possible intermediates in the mechanism of olefin cyclopropanation catalyzed by metal carboxylates

European Journal of Inorganic Chemistry

Volumn , Issue 5, 2000, Pages 1073-1078

  Rodríguez García, Cristóbal ^a   González Blanco, Òscar ^a   Oliva, Antonio ^a   Ortuño, Rosa M ^a   Branchadell, Vicenç ^a  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

Carbene complexes; Carboxylato complexes; Density functional calculations; Palladium; Rhodium

Indexed keywords

CARBOXYLATION; CATALYSIS; OLEFINS; PALLADIUM COMPOUNDS; RHODIUM COMPOUNDS;

CARBENE COMPLEXES; CARBOXYLATO; CARBOXYLATO COMPLEX; DENSITY-FUNCTIONAL CALCULATIONS; DENSITY-FUNCTIONAL STUDY; M-O BOND; METAL CARBOXYLATE; METAL-CARBENE COMPLEXES; OLEFIN CYCLOPROPANATION; STABLE STRUCTURES;

DENSITY FUNCTIONAL THEORY;

ALKENE; CARBENE; CARBOXYLIC ACID DERIVATIVE; CYCLOPROPANE DERIVATIVE; DIAZOMETHANE; METAL COMPLEX; PALLADIUM COMPLEX; RHODIUM;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; COMPLEX FORMATION; DENSITY; MOLECULAR STABILITY; REACTION ANALYSIS; THERMODYNAMICS;

EID: 0343091284     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(200005)2000:5<1073::AID-EJIC1073>3.0.CO;2-U     Document Type: Article

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