Determination of trace-element partitioning between fluid and melt using LA-ICP-MS analysis of synthetic fluid inclusions in glass

European Journal of Mineralogy

Volumn 11, Issue 3, 1999, Pages 415-426

  Schäfer, Beate ^a   Frischknecht, Rolf ^b   Günther, Detlef ^b   Dingwell, Donald B ^a  

^a UNIVERSITÄT BAYREUTH   (Germany)

^b ETH ZURICH   (Switzerland)

Author keywords

Element partitioning; LA ICP MS; Synthetic fluid inclusions

Indexed keywords

CHLORINE COMPOUNDS; GLASS; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; MASS SPECTROMETERS; MINERALOGY; TRACE ANALYSIS;

CHLORIDE SOLUTIONS; ELEMENT PARTITIONING; INTEGRATED INTENSITIES; INTERNAL STANDARD ELEMENT; LA-ICP-MS; PARTITION COEFFICIENT; SYNTHETIC FLUIDS; TRACE ELEMENT PARTITIONING;

TRACE ELEMENTS;

FLUID INCLUSION; PARTITIONING; TRACE ELEMENT;

EID: 0343053387     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/ejm/11/3/0415     Document Type: Article

References (36)

1. Anderson, G.M. & Burnham, C.W. (1983): Feldspar solubility and the transport of aluminium under metamorphic conditions. Am. J. Sci., 283, 283-297.
2. Anovitz, L.M. & Blencoe, J.G. (1997): Experimental determination of the compositions of aqueous fluids coexisting with silicate melts. GSA abstr. A-394.
3. Bos, A. (1990): Hydrothermal elemental distributions at high temperatures: an experimental study on the partitioning of major and trace elements between phlogopite, haplogranitic melt and vapor. Geol. Ultraiectina, Mededelingen van de Faculteit Aardwetenschappen der Rijksuniversiteit et Utrecht, 69, 99 p.
4. Burnham, C.W. (1979): Magmas and hydrothermal fluids. in "Geochemistry of hydrothermal ore deposits", H.L. Barnes, ed., 71-136, 2nd ed.
5. Candela, P.A. (1989a): Magmatic ore-forming fluids: thermodynamic and mass transfer calculations of metal concentrations. in "Ore deposits associated with magmas", J.A. Whitney & A.J. Naldrett, eds., Reviews Econ. Geol., 4, 203-221.
6. _ (1989b): Calculation of magmatic fluid contributions to porphyry-type ore systems: predicting fluid inclusion chemistries. Geochem. J., 23, 295-305.
7. Candela, P.A. & Holland, H.D. (1984): The partitioning of copper and molybdenum between silicate melts and aqueous fluids. Geochim. Cosmochim. Acta, 48, 373-380.
8. Candela, P.A. & Piccoli, P.M. (1995): Model ore-metal partitioning from melts into vapor and vapor/brine mixtures. in "Magmas, fluids and ore deposits", J.F.H. Thompson, ed., Mineral. Assoc. Can., 23, 101-127.
9. Carroll, M.R. & Holloway, J.R. (1994): Volatiles in Magmas. Reviews in Mineralogy, 30, Mineral. Soc. Am., 517 p.
10. 2O à 2 kb, entre 700 et 800°C. Bull. Minéral., 103, 571-578.
11. Dingwell, D.B. (1993): Experimental strategies for the investigation of low temperature properties in granitic and pegmatitic melts. Chem. Geol., 108, 19-30.
12. Eggler, D.H. (1987): Solubility of major and trace elements in mantle metasomatic fluids: experimental constraints, in "Mantle metasomatism", M.A. Menzies & J.C. Hawkesworth, eds., Acad. Press Geol. Series, 21-41.
13. Flynn, R.T. & Burnham, C.W. (1978): An experimental determination of rare earth coefficients between a chloride containing vapor phase and silicate melts. Geochim. Cosmochim. Acta, 42, 685-701.
14. Fournier, R.O. & Potter, R.W. (1982): An equation correlating the solubility of quartz in water from 25° to 900°C at pressures up to 10,000 bars. Geochim. Cosmochim. Acta, 46, 1969-1973.
15. Gammon, J.B., Borcsik, M., Holland, H.D. (1969): Potassium-sodium ratio in aqueous solutions and co-existing silicate melts. Science, 163, 179-181.
16. Günther, D., Audétat, A., Frischknecht, R., Heinrich, C.A. (1998): Quantitative analysis of major, minor and trace elements in fluid inclusions using laser ablation-inductively coupled plasma mass spectrometry. J. Anal. At. Spectrom., 13, 263-270.
17. Günther, D., Frischknecht, R., Heinrich, C.A., Kahlert, H. (1997a): Capabilities of an ArF 193 nm excimer laser for LAM-ICP-MS microanalysis of geological materials. J. Anal. At. Spectrom., 12, 939-944
18. Günther, D., Frischknecht, R., Müschenborn, H.J., Heinrich, C.A. (1997b): Direct liquid ablation: a new calibration strategy for laser ablation-ICP-MS microanalysis of solids and liquids. Fresenius J. Anal. Chem., 359, 390-393.
19. Heinrich, C.A., Ryan, C.G., Mernagh, T.P., Eadington, P.J. (1992): Segregation of ore metals between magmatic brine and vapor: a fluid inclusion study using PIXE microanalysis. Econ. Geol., 87, 1566-1583.
20. Holland, H.D. (1972): Granites, solutions and base metal deposits. Econ. Geol., 67, 281-301.
21. Keppler, H. (1996): Constraints from partitioning experiments on the composition of subduction-zone fluids. Nature, 380, 237-240.
22. 2O-HF. Contrib. Mineral. Petrol., 109, 139-150.
23. London,D., Hervig, R.L., Morgan, G.B. (1988): Melt-vapor solubilities and elemental partitioning in peraluminous granite-pegmatite systems: experimental results with Macusani glass at 200 MPa. Contrib. Mineral. Petrol., 99, 360-373.
24. Longerich, H.P., Jackson, S.E., Günther, D. (1996): Laser ablation - inductively coupled plasma - mass spectrometric transient signal data acquisition and analyte concentration calculation. J. Anal. At. Spectrom., 11, 899-904
25. Mavrogenes, J.A., Bodnar, R.J., Anderson, A.J., Bajt, S., Sutton, S.R., Rivers, M.L. (1995): Assessment of the uncertainties and limitations of quantitative elemental analysis of individual fluid inclusions using synchrotron x-ray fluorescence (SXRF). Geochim. Cosmochim. Acta, 59, 3987-3995.
26. Pascal, M.L. & Anderson, G.M. (1989): Speciation of Al, Si, and K in supercritical solutions: experimental study and interpretation. Geochim. Cosmochim. Acta, 53, 1843-1855.
27. Potter II, R.W., Clynne, M.A., Brown, D.L. (1978): Freezing point depression of aqueous sodium chloride solutions. Econ. Geol., 73, 284-285.
28. Reed, M.J. (1995): Distribution of rare earth elements between aqueous fluids and granitic melt. Ph.D. thesis, Univ. Maryland at College Park, 197 p.
29. Romano, C., Dingwell, D.B., Sterner, S.M. (1994): Kinetics of quenching of hydrous feldspathic melts: quantification using synthetic fluid inclusions. Am. Mineral., 79, 1125-1134.
30. Romano, C., Mungall, J.E., Sharp, T., Dingwell, D.B. (1996): Tensile strengths of hydrous vesicular glasses: an experimental study. Am. Mineral., 81, 1148-1154.
31. Ryabchikov, I.D., Rekharsky, V.L., Kudrin, A.V. (1981): Mobilization of moybdenum by fluids during the cystallization of granite melts. Geochem. Intl., 18, 183-186.
32. Ryan, C.G., Cousens, D.R., Heinrich, C.A., Griffin, W.A., Sie, S.H., Mernagh, T.P. (1991): Quanitative PIXE microanalysis of fluid inclusions based on a layered yield model. Nucl. Instr. Meth., B 54, 292-297.
33. Urabe, T. (1987): The effect of pressure on the partitioning ratios of lead and zinc between vapor and rhyolitic melt. Econ. Geol., 82, 1049-1052.
34. Vanko, D.A., Sutton, S.R., Rivers, M.L., Bodnar, R.L. (1993): Major-element ratios in synthetic fluid inclusions by synchrotron X-ray fluorescence microprobe. Chem. Geol., 109, 125-134.
35. Webster, J.D. (1997): Exsolution of magmatic volatile phases from Cl-enriched mineralizing granitic magmas and implications for ore metal transport. Geochim. Cosmochim. Acta, 61, 1017-1029.
36. Xie, Z. & Walther, J.V. (1993): Quartz solubilities in NaCl solutions with and without wollastonite at elevated temperatures and pressures. Geochim. Cosmochim. Acta, 57, 1947-1955.