Fluorous reverse-phase silica gel-supported Lewis acids as recyclable catalysts in water

Tetrahedron Letters

Volumn 44, Issue 49, 2003, Pages 8791-8795

  Yamazaki, Osamu ^a   Hao, Xiuhua ^a   Yoshida, Akihiro ^a   Nishikido, Joji ^a  

^a NOGUCHI INSTITUTE   (Japan)

Author keywords

Baeyer Villiger reaction; Diels Alder reaction; Direct esterification; Fluorous; Fluorous reverse phase silica gel; Lewis acid; Recycling; Water

Indexed keywords

ALCOHOL; CARBOXYLIC ACID; LEWIS ACID; LIGAND; SILICA GEL; WATER;

ARTICLE; BAEYER VILLIGER REACTION; CATALYSIS; CATALYST; DIELS ALDER REACTION; ESTERIFICATION; FILTRATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

BETULACEAE;

EID: 0242266548     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.09.183     Document Type: Article

References (32)

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26. 2NH (4 mol%) was also less active (44% yield, 48% selec.).
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32. 4 (5 mol%) in 1,2-dichloroethane (1.5 mL), methacrylic acid (0.5 mmol) and methanol (3 mmol) was added. Reaction mixture was stirred at 60°C for 16 h. Supported catalyst was recovered by filtration and washed with 1,2-dichloroethane (5 mL). Yields of product were determined by GC using naphthalene as an internal standard.