Catalysis of aldehyde and imine silylcyanation by platinum and palladium NCN-pincer complexes

Tetrahedron Letters

Volumn 44, Issue 49, 2003, Pages 8773-8776

  Fossey, John S ^a   Richards, Christopher J ^a  

^a QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

Author keywords

Catalysis; Pincer complexes; Silylcyanation

Indexed keywords

ALDEHYDE DERIVATIVE; IMINE; NITRILE; PALLADIUM COMPLEX; PLATINUM COMPLEX; SCHIFF BASE; UNCLASSIFIED DRUG; [[2,6 BIS(N CYCLOHEXYL)IMINO]PHENYL]AQUOPLATINUM TRIFLUOROMETHANESULFONATE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CYANATION; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE;

EID: 0242266545     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.09.201     Document Type: Article

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23. 2. Column=CP-Chirasil-Dex CB: Initial temperature 75°C, initial time 1 min, ramp 1.5 deg./min to 195°C. 38.5 and 39.0 min corresponding to enantiomers of silylated 5 and 66.3 and 67.5 min corresponding to 5.