Molecular mobility and the perceived sweetness of sucrose, fructose, and glucose solutions

Food Chemistry

Volumn 84, Issue 2, 2004, Pages 169-179

  Mahawanich, T ^a   Schmidt, S J ^b  

^a CHULALONGKORN UNIVERSITY   (Thailand)

^b UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

Mobility; Nuclear magnetic resonance (NMR) spectroscopy; Sugars; Sweetness; Water

Indexed keywords

FRUCTOSE; GLUCOSE; SUCROSE; WATER;

ARTICLE; CORRELATION ANALYSIS; DIFFUSION COEFFICIENT; MOLECULAR MECHANICS; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; SWEETNESS; TASTE;

EID: 0142248296     PISSN: 03088146     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0308-8146(03)00197-3     Document Type: Article

References (31)

1. Aroulmoji V., Hutteau F., Mathlouthi M., Rutledge D.N. Hydration properties and the role of water in taste modalities of sucrose, caffeine, and sucrose-caffeine mixtures. Journal of Agricultural & Food Chemistry. 49:2001;4039-4045.
2. 1H-NMR relaxation values of glucose syrups. Journal of Science and Food Agriculture. 58(4):1992;563-568.
3. Birch G.G., Munton S.L. Use of the 'SMURF' in taste analysis. Chemical Senses. 6(1):1981;45.
4. Carr H.Y., Purcell E.M. Effects of diffusion on free precession in nuclear magnetic resonance experiments. Phys. Rev. 91:1954;630-638.
5. Cliff M., Noble A.C. Time-intensity evaluation of sweetness and fruitiness and their interaction in a model system. Journal of Food Science. 55:1990;450-454.
6. Derbyshire W. The dynamics of water in heterogeneous systems with emphasis on subzero temperatures. Franks F. Water: a comprehensive treatise (Vol. 7). 1982;339-450 Plenum Press, New York.
7. Dubois G.E., Lee J.F. A simple technique for the evaluation of temporal taste qualities. Chemical Senses. 7(3):1983;237-247.
8. Dwek R.A. Nuclear magnetic resonance (N. M. R.) in biochemistry. 1973;Clarendon Press, Oxford.
9. Hutteau F., Mathlouthi M. Physicochemical properties of sweeteners in artificial saliva and determination of a hydrophobicity scale for some sweeteners. Food Chemistry. 63(2):1998;199-206.
10. Kier L.B. A molecular theory of sweet taste. Journal of Pharm. Science. 61(9):1972;1394-1397.
11. Ketelsen S.M., Keay C.L., Wiet S.O. Time-intensity parameters of selected carbohydrate and high potency sweeteners. Journal of Food Science. 58:1993;1418-1421.
12. Lai, H. M. (1990). Water relations of simple sugar solutions and skim milk powder as studied by nuclear magnetic resonance spectroscopy. PhD thesis, University of Illinois at Urbana-Champaign, Urbana, IL.
13. Lai H.S., Schmidt S.J. Water mobility and crystallization action of lactose-water systems by oxygen-17 and carbon-13 NMR. Journal of Food Science. 55:1990;1435-1440.
14. Mahawanich, T. (2000). Using NMR to probe solute mobility and its relationship to functionality and sensory characteristics of carbohydrate-containing systems. PhD thesis, University of Illinois at Urbana-Champaign, Urbana, IL.
15. Mathlouthi M. Relationship between the structure and the properties of carbohydrates in aqueous solutions. solute-solvent interactions and the sweetness of D-fructose, D-glucose and sucrose in solution Food Chemistry. 13:1984;1-16.
16. Mathlouthi M., Hutteau F. Sweet-bitter interactions and the solution properties of chlorinated sugars. Food Chemistry. 64:1999;77-82.
17. Mathlouthi M., Seuvre A. Solution properties and the sweet taste of small carbohydrates. J. Chem. Soc. Faraday Trans. 184:1988;2641-2650.
18. Mathlouthi M., Hutteau F., Angiboust I.F. Physicochemical properties and vibrational spectra of small carbohydrates in aqueous solution and the role of water in their sweet taste. Food Chemistry. 56:1996;215-221.
19. Meiboom S., Gill P. Modified spin-echo method for measuring nuclear relaxation times. Rev. Sci. Instrum. 29:1958;688-691.
20. 13C NMR data for carbohydrate solutions Journal of Agricultural and Food Chemistry. 37:1989;1459-1465.
21. Padua, G. W. (1989). Water states associated with skim milk components quantitated by NMR. PhD thesis, University of Illinois at Urbana-Champaign, Urbana, IL.
22. Padua G.W., Schmidt S.J. Proton nuclear magnetic resonance measurements on various sugar solutions. Journal of Agricultural and Food Chemistry. 40:1992;1524-1527.
23. Richardson S.J., Baianu I.C., Steinberg M.P. Mobility of water in sucrose solutions determined by deuterium and oxygen-17 nuclear magnetic resonance measurements. Journal of Food Science. 52:1987;806-809.
24. Shallenberger R.S., Acree T.E. Molecular theory of sweet taste. Nature. 216:1967;480-482.
25. Shamil S., Birch G.O., Mathlouthi M., Clifford M.N. Apparent molar volumes and tastes of molecules with more than one sapophore. Chemical Senses. 12(2):1987;397-409.
26. Swartz M. Sensory screening of synthetic sweeteners using time-intensity evaluations. Journal of Food Science. 45:1980;577-581.
27. Sybesma C. An introduction to biophysics. 1977;Academic Press, New York.
28. Tanner J.E., Stejskal E.O. Restricted self-diffusion of protons in colloidal systems by the pulsed-gradient spin-echo method. J. Chem. Phys. 49:1968;1768-1777.
29. Van der Heijden A. Sweet and bitter tastes. Acress T.E., Teranishi R. Flavour Science: sensible principles and techniques. 1993;67-140 American Chemical Society, Washington D.C.
30. Vold R.L., Waugh J.S., Klein M.P., Phelps D.E. Measurement of spin relaxation in complex systems. J. Chem. Phys. 48:1968;3831-3832.
31. Zimmerman J.R., Brittin W.E. Nuclear magnetic resonance studies in multiple phase on silica gel. J. Phys. Chem. 61:1957;1328-1333.