Relationship between droplet pH and aerosol dissolution kinetics: Effects of incorporated aerosol particles on droplet pH during cloud processing

Journal of Atmospheric Chemistry

Volumn 46, Issue 2, 2003, Pages 159-172

  Desboeufs, K V ^a   Losno, R ^a   Colin, J L ^a  

^a UNIVERSITÉ PARIS EST CRÉTEIL   (France)

Author keywords

Aerosol dissolution; Ionic exchange; Neutralising capacity; pH balance

Indexed keywords

BASE; GRAPHITE; PROTON; SILICATE; SULFATE; SULFURIC ACID;

AEROSOL; DISSOLUTION; DROPLET; ION EXCHANGE; KINETICS; PH;

ACIDIFICATION; AEROSOL; AQUEOUS SOLUTION; ARTICLE; CHEMICAL COMPOSITION; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CLOUD; CONTROLLED STUDY; DISSOLUTION; EVAPORATION; EXPERIMENTATION; LEACHING; PH MEASUREMENT; SOLUBILIZATION;

CAMEROON;

EID: 0142244236     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1026011408748     Document Type: Article

References (30)

1. Andreae, M. O., Charlson, R. J., Bruynseels, F., Storms, H., van Grieken, R., and Maenhaut, W., 1986: Internal mixture of sea salt, silicates, and excess sulfate in marine aerosols, Science 32, 1620-1623.
2. Ausset, P., Del Monte, M., and Lefèvre, R. A., 1999: Embryonic sulphated black crusts on carbonate rocks in atmospheric simulation chamber and in the field: Role of carbonaceous fly ash, Atmos. Environ. 33, 1525-1534.
3. Berglund, J. and Elding, L. I., 1995: Manganese-catalysed autoxidation of dissolved sulfur dioxide in the atmospheric aqueous phase, Atmos. Environ. 29, 1379-1391.
4. Calvert, J., Kok, L. A., Walega, Lind, and Cantrell, 1985: Chemical mechanism of acid generation in the troposphere, Nature 317, 27-35.
5. 2 in acid rain chemistry, Atmos. Environ. 21, 1115-1123.
6. Collett Jr., J. L., Hoag, K. J., Rao X., and Pandis, S. N., 1999: Internal acid buffering in San Joaquim Valley fog drops and its influence on aerosol processing, Atmos. Environ. 33, 4833-4847.
7. Daum, P. H., Schwartz S. E., and Newman, L., 1984: Acidic and related constituents in liquid water stratiform clouds, J. Geophys. Res. 89, 1447-1458.
8. Desboeufs, K., Losno, R., Vimeux F., and Cholbi, S., 1999: pH dependent dissolution of wind transported Saharan dust, J. Geophys. Res., 104, 21287-21299.
9. Desboeufs, K. V., Losno R., and Colin, J. L., 2001: Factors influencing aerosol solubility during cloud processes, Atmos. Environ. 35, 3529-3537.
10. Graedel, T. E., Weschler, C. J., and Mandlich, M. L., 1985: Influence of transition metal complexes on atmospheric droplet acidity, Nature 317, 240-242.
11. Grgic, I., Poznic, M., and Bizjak, M., 1999: S(IV) autoxidation in atmospheric liquid water: The role of Fe(II) and the effect of oxalate, J. Atmos. Chem. 33, 89-102.
12. Hegg, D. A., 1991: Particle production in clouds, Geophys. Res. Lett. 18, 995-998.
13. Herut, B., Starinsky, A., Katz A., and Rosenfeld, D., 2000: Relationship between the acidity and chemical composition of rainwater and climatological conditions along a transition zone between large deserts and Mediterranean, Atmos. Environ. 34, 1281-1292.
14. Hobbs, P. V., 1993: Aerosol-cloud interaction, in P. V. Hobbs (ed.), Aerosol-Cloud-Climate Interaction, Washington.
15. Khemani, L. T., Monin, G. A., Naik, M. S., Pakasa Rao, P. S., Safai D. P., and Murty, A. S. R., 1987: Influence of alkaline particulates on pH of cloud and rain water in India, Atmos. Environ. 21, 1137-1145.
16. Kulshrestha, U. C., Sarkar, A. K., Srivastava S. S., and Parashar, D. C., 1996: Investigation into atmospheric deposition through precipitation studies at New Delhi (India), Atmos. Environ. 30, 4149-4154.
17. Larssen, T. and Carmichael, G. R., 2000: Acid rain and acidification in China: the importance of base cation deposition, Environmental Pollution 110, 89-102.
18. Levin, Z., Price, C., and Ganor, E., 1990: The contribution of sulfate and desert aerosols to the acidification of clouds and rain in Israel, Atmos. Environ. 24A, 1143-1151.
19. Li, J. and Tang, H., 1998: Acidification capacity model: Formulation and application, Water Research, 32, 3378-3386.
20. Losno, R., Bergametti, G., Carlier P., and Mouvier, G., 1991: Major ions in marine rainwater with attention to sources of alkaline and acidic species, Atmos. Environ. 25, 771-777.
21. Loÿe-Pilot, M. D., Martin J. M., and Morelli, J., 1986: Influence of Saharan dust on rain acidity and atmospheric input to the Mediterranean, Nature 321, 427-428.
22. Mamane, Y. and Gottlieb, J., 1992: Nitrate formation on sea-salt and mineral particles-A single particle approach, Atmos. Environ. 26A, 1763-1769.
23. Nguyen Hong, K., 2000: Air emission and acidity of rain water of Hanoi city, Progress in Nuclear Energy 37, 41-46.
24. Sanusi, A., Wortham, H., Millet M., and Mirabel, P., 1996: Chemical composition of rainwater in eastern France, Atmos. Environ. 30, 59-71.
25. Schwartz, S. E., 1986: Mass-transport considerations pertinent to aqueous phase reactions of gases in liquid water clouds, in Jaeschkle, W. (ed.), Chemistry of Multiphase Atmospheric Systems, NATO ASI Series, G6, Spinger-Verlag, pp. 415-471.
26. Singh, S. P., Satsangi, G. S., Khare, P., Lakhani, A., Maharaj Kumari, K., and Srivastava, S. S., 2001: Multiphase measurement of atmospheric ammonia, Chemosphere - Global Change Science 3, 107-116.
27. Spokes, L. J., Jickells T. D., and Lim, B., 1994: Solubilisation of aerosol trace metals by cloud procesing: A laboratory study, Geochimica and Cosmochimica Acta 58, 3281-3287.
28. Tanner, P. A., 1999: Analysis of Hong Kong daily bulk and wet deposition data from 1994 to 1995, Atmos. Environ. 33, 1757-1766.
29. Vong, R. J., Baker, B. M., Brechtel, F. J., Collier, R. T., Harris, J. M., Kowalski, A. S., McDonald N. C., and McInnes, L. M., 1997: Ionic and trace metals composition of cloud water collected on the Olympic peninsula of Washington State, Atmos. Environ. 31, 1991-2001.
30. Wurzler, S., Reisin T., and Levin, Z., 2000: Modification of mineral dust particles by cloud processing and subsequent effects on drop size distribution, J. Geophys. Res. 105, 4501-4512.