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note
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Ammonium tetrachloropalladate (Aldrich, Gillingham, U.K.) was prepared asa 1 mM solution in "Milli-Q" water (Millipore, Watford, U.K.). Decamethylferrocene (Aldrich) was used as a 2 mM solution in DCE (Aldrich, HPLC grade). Neither solution was stirred in the deposition experiments reported here.
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0142243848
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note
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The 462 nm aqueous phase absorbance was monitored in situ for I h, using a Helios α spectrophotometer (Thermospetric, Cambridge, U.K.).
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17
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0041467470
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0142212828
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note
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SEM and energy dispersive X-ray analysis were performed using a Quanta 200 Environmental SEM (FEI Co., Hillsboro, OR).
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