Epimerization of 2′-carbonylalkyl-C-glycosides via enolation, β-elimination and intramolecular cycloaddition

Journal of Organic Chemistry

Volumn 68, Issue 21, 2003, Pages 8097-8105

  Wang, Zerong ^a   Shao, Huawu ^a   Lacroix, Edith ^a   Wu, Shih Hsiung ^b   Jennings, Harold J ^a   Zou, Wei ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b INSTITUTE OF BIOLOGICAL CHEMISTRY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; DEUTERIUM; METHANOL; MOLECULAR DYNAMICS;

EPIMERIZATION;

SUGARS;

1 (2,3 DI O BENZYL ALPHA LEVO ARABINOPYRANOSYL)ACETONE; 1 (2,3 DI O BENZYL ALPHA,BETA LEVO ARABINOFURANOSYL)ACETONE; 2 (2,3,4,6 TETRA O BENZYL ALPHA DEXTRO GALACTOPYRANOSYL)ETHYL ALDEHYDE; 2 (5 O ACETYL 2,3 DI O BENZYL ALPHA,BETA LEVO ARABINOFURANOSYL)ETHYL ALDEHYDE; 2' CARBONYL ALPHA C GLYCOPYRANOSIDE; ACETONE; ALDEHYDE; CARBONYL DERIVATIVE; DEUTERIUM; GLYCOSIDE; KETONE; METHANOL; UNCLASSIFIED DRUG;

ARTICLE; CYCLOADDITION; DRUG STABILITY; DRUG STRUCTURE; EPIMERIZATION; MICHAEL ADDITION; REACTION ANALYSIS; STRUCTURE ANALYSIS; THERMODYNAMICS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; STEREOISOMERISM; SYNTHESIS;

CYCLIZATION; GLYCOSIDES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 0142090168     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo034446k     Document Type: Article

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