New bimetallic Ni-Rh carbonyl clusters: Synthesis and X-ray structure of the trigonal antiprismatic [NiRh5(CO)14]3- and body-centered cubic [NiRh14(CO)28]4- cluster anions

Inorganica Chimica Acta

Volumn 350, Issue , 2003, Pages 321-328

  Collini, Davide ^a   Femoni, Cristina ^a   Iapalucci, Maria Carmela ^a   Longoni, Giuliano ^a   Svensson, Per H ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

Bimetallic cluster; Carbonyl; Nickel; Rhodium; X ray structures

Indexed keywords

ALKALI METALS; ATOMS; BINARY ALLOYS; CARBON MONOXIDE; CRYSTAL STRUCTURE; MIXTURES; NICKEL; NICKEL COMPOUNDS; RHODIUM; RHODIUM COMPOUNDS; SALTS;

BIMETALLIC CLUSTERS; BODY-CENTERED CUBIC; CARBONYL; CARBONYL CLUSTERS; CLUSTER ANIONS; VALENCE ELECTRON; X-RAY DIFFRACTION STUDIES; X-RAY STRUCTURE;

RHODIUM ALLOYS;

ALKALI METAL; AMMONIUM DERIVATIVE; ANION; CARBON MONOXIDE; CARBONYL DERIVATIVE; HALIDE; HYDROXIDE; METAL COMPLEX; NICKEL; RHODIUM; SODIUM CHLORIDE;

ARTICLE; ATMOSPHERE; CHEMICAL REACTION; CRYSTAL STRUCTURE; DEGRADATION; ELECTRON; ISOLATION PROCEDURE; PROTON TRANSPORT; REDUCTION; SOLID STATE; SPECTROSCOPY; SYNTHESIS; X RAY DIFFRACTION;

EID: 0142025212     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01545-1     Document Type: Article

References (25)

1. Fumagalli A., Longoni G., Chini P., Albinati A., Bruckner S. J. Organomet. Chem. 202:1980;329.
2. Nagaki D.A., Badding J.V., Stacey A.M., Dahl L.F. J. Am. Chem. Soc. 108:1986;3825.
3. Demartin F., Femoni C., Iapalucci M.C., Lombardi A., Longoni G., Marin C., Svensson P.H. J. Organomet. Chem. 614-615:2000;294.
4. D. Collini, C. Femoni, M.C. Iapalucci, G. Longoni, P.H. Svensson, P. Zanello, Angew. Chem., Int. Ed. 41 (2002) 3685.
5. G. Ciani, A. Sironi, S. Martinengo, J. Chem. Soc., Dalton Trans. (1982) 1099.
6. Martinengo S., Ciani G., Sironi A., Chini P. J. Am. Chem. Soc. 100:1978;7096.
7. Vidal J.L., Kapicak L.A., Troup J.M. J. Organomet. Chem. 215:1981;C11.
8. Martinengo S., Chini P., Giordano G., Ceriotti A., Albano V.G., Ciani G. J. Organomet. Chem. 88:1975;375.
9. Albano V.G., Chini P., Scatturin V. J. Organomet. Chem. 15:1968;423.
10. Albano V.G., Bellon P.L., Chini P., Scatturin V. J. Organomet. Chem. 16:1969;461.
11. Martinengo S., Chini P. Gazz. Chim. Ital. 102:1972;344.
12. P. Chini, S. Martinengo, J. Chem. Soc., Chem. Commun. (1969) 1092.
13. Martinengo S., Fumagalli A., Chini P. J. Organomet. Chem. 284:1985;275.
14. F. Demartin, M. Manassero, M. Sansoni, L. Garlaschelli, F. Canziani, J. Chem. Soc., Chem. Commun. (1980) 903.
15. V.G. Albano, P.L. Bellon, G. Ciani, J. Chem. Soc., Dalton Trans. (1988) 1103.
16. Ciani G., Sironi A., Martinengo S. J. Organomet. Chem. 192:1980;C42.
17. Longoni G., Manassero M., Sansoni M. J. Am. Chem. Soc. 102:1980;3242.
18. E. Brivio, A. Ceriotti, R.D. Pergola, L. Garlaschelli, F. Demartin, M. Manassero, M. Sansoni, P. Zanello, F. Laschi, B.T. Heaton, J. Chem. Soc., Dalton Trans. (1994) 3237.
19. Weast R.C. Handbook of Chemistry and Physics. 1977;CRC Press, Boca Raton, FL.
20. Stevens A.E., Feigerle C.S., Lineberger W.C. J. Am. Chem. Soc. 104:1982;5026.
21. Blomberg M.R.A., Siegbahn P.E.M., Lee T.J., Rendell A.P., Rice J.E. J. Chem. Phys. 95:1991;5898.
22. Mealli C., Proserpio D.M. J. Chem. Ed. 67:1990;399.
23. Ceriotti A., Longoni G., Piva G. Inorg. Synth. 26:1989;312.
24. G.M. Sheldrick, SADABS, University of Göttingen, Göttingen, Germany.
25. G.M. Sheldrick, SHELX-97, University of Göttingen, Göttingen, Germany.