Unexpected formation of a weak metal-metal bond: Synthesis, electronic properties, and second-order NLO responses of push-pull late-early heteronuclear bimetallic complexes with W(CO)3(1,10-phenanthroline) acting as a donor ligand

Organometallics

Volumn 22, Issue 20, 2003, Pages 4001-4011

  Pizzotti, Maddalena ^a   Ugo, Renato ^a   Dragonetti, Claudia ^a   Annoni, Elisabetta ^a   Demartin, F ^b   Mussini, P ^c  

^a UNIVERSITY OF MILAN   (Italy)

^b DCSSI   (Italy)

^c Dipartimento di Chimica Fisica ed Elettrochimica   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; COORDINATION REACTIONS; ELECTRONIC PROPERTIES; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

ELECTRIC FIELD SECOND HARMONIC GENERATION; HETERONUCLEAR BIMETALLIC COMPLEXES; METAL-METAL BOND; PHENANTHROLINE; SOLVATOCHROMIC METHOD;

TUNGSTEN COMPOUNDS;

EID: 0141991930     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030247f     Document Type: Article

References (59)

1. (a) Long, N. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 21.
2. (b) Whittall, I. R.; McDonagh, A.M.; Humprhey, M.G.; Samoc, M. Adv. Organomet. Chem. 1998, 42, 291.
3. (c) Di Bella, S. Chem. Soc. Rev. 2001, 30, 355.
4. (a) Houbrechts, S.; Clays, K.; Persoons, A.; Cadierno, V.; Pilar Gamasa, M.; Gimeno, J. Organometallics 1996, 15, 5266.
5. (b) Mata, J.; Uriel, S.; Peris, E.; Llusar, R.; Houbrechts, S.; Persoons, A. J. Organomet. Chem. 1998, 562, 197.
6. (c) Heck, J.; Dabek, S.; Meyer-Friedrichsen, T.; Wong, H. Coord. Chem. Rev. 1999, 190-192, 1217 and references therein.
7. (d) Lee, I. S.; Seo, H.; Chung, Y. K. Organometallics 1999, 18, 1091.
8. (e) Tamm, M.; Bannenberg, T.; Baum, K.; Frohlich, R.; Steiner, T.; Meyer-Friedrichsen, T.; Heck, J. Eur. J. Inorg. Chem. 2000, 1161.
9. (f) Tranchier, J. P.; Chavignon, R.; Prim, D.; Auffrant, A.; Planas, J. G.; Rose-Munch, F.; Rose, E.; Stephenson, G. R. Tetrahedron Lett. 2001, 42, 3311.
10. (g) Meyer-Friedrichsen, T.; Mecker, C.; Prosenc, M.H.; Heck, J. Eur. J. Inorg. Chem. 2002, 239.
11. Pizzotti, M.; Ugo, R.; Roberto, D.; Bruni, S.; Fantucci, P.; Rovizzi, C. Organometallics 2002, 21, 5830 and references therein.
12. (a) Coe, B. J.; Jones, C. J.; McCleverty, J. A.; Bloor, D.; Kolinsky, P. V.; Jones, R. J. Polyhedron 1994, 13, 2107.
13. (b) Coe, B. J.; Jones, C. J.; McCleverty, J. A.; Bloor, D.; Kolinski, P. V. J. Chem. Soc., Chem. Commun. 1989, 1485.
14. Kanis, D. R.; Lacroix, P. G.; Ratner, M. A.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10089.
15. Zulu, M. M.; Lees, A. J. Organometallics 1989, 8, 955.
16. Lesley, M. J. G.; Woodward, A.; Taylor, N. J.; Marder, T. B.; Cazenobe, I.; Ledoux, I.; Zyss, J.; Thornton, A.; Bruce, D. W.; Kakkar, A. K. Chem. Mater. 1998, 10, 1355.
17. (a) Roberto, D.; Ugo, R.; Bruni, S.; Cariati, E.; Cariati, F.; Fantucci, P.; Invernizzi, I.; Ledoux, I.; Zyss, J. Organometallics 2000, 19, 1775.
18. (b) Roberto, D.; Ugo, R.; Tessore, F.; Lucenti, E.; Quici, S.; Vezza, S.; Fantucci, P.; Invernizzi, I.; Bruni, S.; Ledoux-Rak, I.; Zyss, J. Organometallics 2002, 21, 161.
19. Cheng, L. T.; Tam, W.; Eaton, D. F. Organometallics 1990, 9, 2856.
20. Roberto, D.; Psaro, R.; Ugo R. Organometallics 1993, 12, 2292.
21. Dolcetti, G.; Norton, J. R. Inorg. Synth. 1976, 16, 35.
22. (a) Stiddard, M. H. B. J. Chem. Soc. 1962, 4712.
23. (b) Saito, H.; Fujita, J.; Saito, K. Bull. Chem. Soc. Jpn. 1968, 41, 359.
24. Wrighton, M. S.; Morse, D. L. J. Organomet. Chem. 1975, 97, 405.
25. Dragonetti, C.; Pizzotti, M.; Roberto, D.; Galli, S. Inorg. Chim. Acta 2002, 330, 128.
26. Kolodziej, R. M.; Leese, A. J. Organometallics 1986, 5, 450.
27. (a) Guggenheim, E. A. Trans. Faraday Soc. 1949, 45, 203.
28. (b) Smith, W. Electric Dipole Moments; Butterworth Scientific: London 1965.
29. (c) Thompson, B. J. Chem. Educ. 1966, 43, 66.
30. (a) Levine, B. F.; Bethea, C. G. Appl. Phys. Lett. 1974, 24, 445.
31. (b) Singer, K. D.; Garito, A. F. J. Chem. Phys. 1981, 75, 3572.
32. (c) Ledoux, I.; Zyss, J. Chem. Phys. 1982, 73, 203.
33. Willetts, A.; Rice, J. E.; Burland, D. M.; Shelton, D. P. J. Chem. Phys. 1992, 97, 7590.
34. Bruni, S.; Cariati, F.; Cariati, E.; Porta, F. A.; Quici, S.; Roberto, D. Spectrochim. Acta, Part A 2001, 57, 1417.
35. (a) Oudar, J. L.; Chela, D. S. J. Chem. Phys. 1977, 66, 2664.
36. (b) Oudar, J. J. Chem. Phys. 1977, 67, 446.
37. 2′), 4.37 and 2.07 (two multiplets due to coordinated THF).
38. (a) Heilweil, E. J.; Cavanagh, R. R.; Stephenson, J. C. Chem. Phys. Lett. 1987, 134, 181.
39. (b) Willliams, A. F.; Bhaduri, S.; Maddock, A. G. J. Chem. Soc., Dalton Trans. 1975, 1958.
40. (c) Chatt, J.; Melville, D. P.; Richards, R. L.; J. Chem. Soc. A 1969, 18, 2841.
41. (d) Johnson, B. F. G.; Johnston, R. D.; Lewis, J. J. Chem. Soc. A 1969, 5, 792.
42. (e) Bradford, C. W.; Nyholm, R. S. Chem. Commun. (London) 1967, 8, 384.
43. Heaton, B. T.; Jacob, C.; Sampanthar, J. T. J. Chem. Soc., Dalton Trans. 1998, 8, 1403.
44. -1.
45. North, A. C. T.; Phillips, D. C.; Matthews, F. S. Acta Crystallogr., Sect. A 1968, 24, 351. SADABS Area-Detector Absorption Correction Program, Bruker AXS, Inc. Madison WI.
46. Sheldrick, G. M. SHELXS 86. Acta Crystallogr., Sect. A 1990 46, 467.
47. Sheldrick, G. M. SHELXS 93; University of Göttingen, Göttingen, Germany, 1993.
48. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; Wiley: New York, 2002; pp 231-239, 247-252.
49. Roberto, D.; Ugo, R.; Tessore, F.; Lucenti, E.; Quici, S.; Vezza, S.; Fantucci, P.; Invernizzi, I.; Bruni, S.; Ledoux-Rak, I.; Zyss, J. Organometallics 2002, 21, 161.
50. (a) Einstein, F. W. B.; Pomeroy, R. K.; Rushman, P.; Willis, A. C. Organometallics 1985, 4, 250.
51. (b) Baumann, F. E.; Howard, J. A. K.; Musgrove, R. J.; Sherwood, P.; Ruiz, M. A.; Stone, F. G. A. J. Chem. Soc., Chem. Commun. 1987, 1881.
52. (c) Rosenberg, S.; Whittle, R. C.; Geoffroy, G. L. J. Am. Chem. Soc. 1984, 106, 5934.
53. Dickson, R. S. In Organometallic Chemistry of Rhodium and Iridium; Academic Press: London, 1983.
54. Gade, L. H. Angew. Chem., Int. Ed. 2000, 39, 2658.
55. Zhang, Z. Z.; Cheng, H.; Kuang, S. M.; Zhou, Y. Q.; Liu, Z. X.; Zhang, J. K.; Wang, H. G. J. Organomet. Chem. 1996, 516. 1.
56. (a) Adamson, G. W.; Daly, J. J.: Forster, D. J. Organomet. Chem. 1974, 71 C17.
57. (b) Murphy, M. A.; Smith, B. L.; Torrence, G. P.; Aguilo, A. Inorg. Chim. Acta 1985, 101, L47.
58. Servaas, P. C.; van Dijk, H. K.; Snoeck, T. L.; Stufkens, D. J.; Oskam, A. Inorg. Chem. 1985, 24, 4494.
59. Orr, B.J.; Ward, J. F. Mol. Phys. 1971, 20, 513.