Nanoporous carbide-derived carbon with tunable pore size

Nature Materials

Volumn 2, Issue 9, 2003, Pages 591-594

  Gogotsi, Yury ^a   Nikitin, Alexei ^a   Ye, Haihui ^a   Zhou, Wei ^b   Fischer, John E ^b   Yi, Bo ^c   Foley, Henry C ^c   Barsoum, Michel W ^a  

^a Drexel University   (United States)

^b UNIVERSITY OF PENNSYLVANIA   (United States)

^c The Pennsylvania State University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITION; CRYSTAL STRUCTURE; CRYSTALLIZATION; NANOSTRUCTURED MATERIALS; NUMERICAL METHODS; PORE SIZE; POROSITY; POROUS MATERIALS; SURFACES; TEMPERATURE; ZEOLITES;

CARBIDE DERIVED CARBONS; NANOPOROUS CARBIDE; POROUS SOLIDS; TUNABLE PORE SIZE;

CARBIDES;

CARBON; CHLORINE;

ARTICLE; CHEMISTRY; CRYSTALLIZATION; CRYSTALLOGRAPHY; ELECTRON MICROSCOPY; EVALUATION; MATERIALS TESTING; METHODOLOGY; NANOTECHNOLOGY; POROSITY; RAMAN SPECTROMETRY; SURFACE PROPERTY; TEMPERATURE;

CARBON; CHLORINE; CRYSTALLIZATION; CRYSTALLOGRAPHY; MATERIALS TESTING; MICROSCOPY, ELECTRON; NANOTECHNOLOGY; POROSITY; SPECTRUM ANALYSIS, RAMAN; SURFACE PROPERTIES; TEMPERATURE;

EID: 0141990551     PISSN: 14761122     EISSN: None     Source Type: Journal    
DOI: 10.1038/nmat957     Document Type: Letter

References (27)

1. Davis, M. E. Ordered porous materials for emerging applications. Nature 417, 813-821 (2002).
2. Joo, S. H. et al. Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles. Nature 412, 169-172 (2001).
3. Gogotsi, Y. G. & Yoshimura, M. Formation of carbon films on carbides under hydrothermal conditions. Nature 367, 628-630 (1994).
4. Gogotsi, Y. G., Jeon, J. D. & McNallan, M. J. Carbon coatings on silicon carbide by reaction with chlorine-containing gases. J. Mater. Chem. 7, 1841-1848 (1997).
5. Ersoy, D., McNallan, M. J. & Gogotsi, Y. G. Carbon coatings produced by high temperature chlorination of silicon carbide ceramics. Mater. Res. Innov. 5, 55-62 (2001).
6. Hutchins, O. Method for the production of silicon tetrachlorid. US patent 1,271,713 (1918).
7. Boehm, H. P. & Warnecke, H. H. in Proc. 12th Biennial Conf. Carbon 149-150 (Pergamon, Oxford, 1975).
8. Gordeev, S. K., Kukushkin, S. A., Osipov, A. V. & Pavlov, Y. V. Self-organization in the formation of a nanoporous carbon material. Phys. Solid State 42, 2314-2317 (2000).
9. Fedorov, N. F. Untraditional solutions in chemical technology of carbon adsorbents. Russ. Chem. J. 39, 73-83 (1995).
10. Claye, A. & Fischer, J. E. Short-range order in disordered carbons: where does the Li go? Electrochim. Acta 45, 107-120 (1999).
11. Shiflett, M. B. & Foley, H. C. Ultrasonic deposition of high-selectivity nanoporous carbon membranes. Science 285, 1902-1905 (1999).
12. Rodriguez-Reinoso, F. & Sepulveda-Escribano, A. in Handbook of Surfaces and Interfaces of Materials (ed. Nalwa, H. S.) 309-355 (Academic, San Diego, 2001).
13. Derycke, V., Martel, R., Radosavljević, M., Ross, F. M. & Avouris, P. Catalyst-free growth of ordered single-walled carbon nanotube networks. Nano Lett. 2, 1043-1046 (2002).
14. Gogotsi, Y., Welz, S., Ersoy, D. A. & McNallan, M. J. Conversion of silicon carbide to crystalline diamond-structured carbon at ambient pressure. Nature 411, 283-287 (2001).
15. n phases: a new class of solids. Prog. Solid State Chem 28, 201-281 (2000).
16. Kyutt, R. N., Smorgonskaya, E. A., Danishevski, A. M., Gordeev, S. K. & Grechinskaya, A. V. Structural study of nanoporous carbon produced from polycrystalline carbide materials: small-angle X-ray scattering. Phys. Solid State 41, 1359-1363 (1999).
17. Ferrari, A. C. & Robertson, J. Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B 61, 14095-14107 (2000).
18. 2. J. Appl. Phys. 83, 112-119 (1998).
19. Leis, J., Perkson, A., Arulepp, M., Nigu,P. & Svensson, G. Catalytic effect of metals of the iron subgroup on the chlorination of titanium carbide to form nanostructural carbon. Carbon 40, 1559-1564 (2002).
20. Gogotsi, Y. et al. Formation of carbon coatings on SiC fibers by selective etching in halogens and supercritical water. Ceram. Eng. Sci. Proc. 19, 87-94 (1998).
21. Yanul', N. A. et al. Nanoporous carbon materials with varied porosity and specific features of their interaction with water. Russ. J. Appl. Chem. 72, 2159-2163 (1999).
22. Baughman, R. H., Zakhidov, A. A. & de Heer, W. A. Carbon nanotubes - the route toward applications. Science 297, 787-792 (2002).
23. Burke, A. Ultracapacitors: why, how, and where is the technology? J. Power Sources 91, 37-50 (2000).
24. Nijkamp, M. G., Raaymakers, J. E. M. J., van Dillen, A. J. & de Jong, K. P. Hydrogen storage using physisorbtion - materials demands. Appl. Phys. A. 72, 619-623 (2001).
25. Schlapbach, L. & Züttel, A. Hydrogen-storage materials for mobile applications. Nature 414, 353-358 (2001).
26. Mariwala, R. K. & Foley, H. C. Calculation of micropore sizes in carbogenic materials from the methyl chloride adsorption isotherm. Ind. Eng. Chem. Res. 33, 2314-2321 (1994).
27. Tuinstra, F. & Koenig, J. L. Raman spectrum of graphite. J. Chem. Phys. 53, 1126-1130 (1970).