Molecular structures of two cyclic bis(amino)tin dichlorides and their NMR spectroscopic characterization in solution. - The first 1,3,2-diazastanna-[3]ferrocenophane

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 629, Issue 7-8, 2003, Pages 1169-1174

  Wrackmeyer, Bernd ^a   Milius, Wolfgang ^a   Maisel, Heidi E ^a   Vollrath, Hendrik ^a   Herberhold, Max ^a  

^a UNIVERSITY OF BAYREUTH   (Germany)

Author keywords

Crystal structure; Ferrocene; NMR (multinuclear); Silylamines; Tin amides

Indexed keywords

2,2 DICHLORO 1,3 BIS(TRIMETHYLSILYL) 1,3,2 DIAZASTANNA[3]FERROCENOPHANE; CHLORIDE; CHLORINE DERIVATIVE; CYCLOPENTADIENE DERIVATIVE; NITROGEN; SILICON; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SOLUBILITY; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0141840717     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/zaac.200300026     Document Type: Article

References (47)

1. (a) M. Veith, O. Recktenwald, E. Humpfer, Z. Naturforsch., 1978, 33b, 14;
2. (b) M. Veith, Angew. Chem. 1975, 87, 287; Angew. Chem. Int. Ed. Engl. 1975, 14, 263.
3. (b) M. Veith, Angew. Chem. 1975, 87, 287; Angew. Chem. Int. Ed. Engl. 1975, 14, 263.
4. (a) C. Stader, B. Wrackmeyer, D. Schlosser, Z. Naturforsch. 1988, 43b, 707;
5. (b) K. Horchler, C. Stader, B. Wrackmeyer, Inorg. Chim. Acta 1986, 117, L39.
6. B. Wrackmeyer, G. Kehr, H. Zhou, S. Ali, Inorg. Chim. Acta 1992, 197, 129.
7. B. Wrackmeyer, A. Pedall, J. Weidinger, Z. Naturforsch. 2001, 56b, 1009.
8. (a) M. F. Lappert, P. P. Power, Adv. Chem. Ser. 1976, 157, 70 (1976);
9. (b) D. H. Harris, M. F. Lappert, J. Chem. Soc., Chem. Commun. 1974, 895.
10. B. Wrackmeyer, A. Pedall, W. Milius, O. L. Tok, Yu. N. Bubnov, J. Organomet. Chem. 2002, 649, 232.
11. Yu. I. Dergunov, V. F. Gerega, O: S: D'yachkovskaja, Russ. Chem. Rev. 1977, 46, 1132.
12. A. Shafir, M. P. Power, G. D. Whitener, J. Arnold, Organometallics 2001, 20, 1365.
13. (a) C. Ackerhaus, H. W. Roesky, D. Vidovic, J. Magul, Eur. J. Inorg. Chem. 2003, 66;
14. (b) S. L. Hinchley, B. A. Smart, C. Morrison, H. E. Robertson, D. W. H. Rankin, R. A. Coxall, S. Parsons, T. R. Zink, H. Siegl, K. Hassler, J. Chem. Soc., Dalton Trans. 2001, 2916;
15. (c) A. Naka, K. Yoshida, M. Ishikawa, I. Miyahara, K. Hirotsu, S.-H. Cha, K. K. Lee, Y.-W. Kwak, Organometallics 2001, 20, 1204;
16. (d) N. Wiberg, H. Auer, W. Niedermayer, H. Nöth, H. Schwenk-Kircher, K. Polborn, J. Organomet. Chem. 2000, 612, 141;
17. (e) U. Herzog, U. Böhme, G. Rheinwald, J. Organomet. Chem. 2000, 612, 133;
18. (f) U. Böhme, B. Günther, B. Rittmeister, Inorg. Chem. Commun. 2000, 3, 428.
19. (g) B. Wrackmeyer, W. Milius, A. Badshah, J. Organomet. Chem. 2002, 656, 97;
20. (h) B. Wrackmeyer, H. E. Maisel, W. Milius, Chem. Ber. / Recueil 1997, 130, 1349.
21. (a) S. Diemer, H. Nöth, K. Polborn, W. Storch, Chem. Ber. 1992, 125, 389;
22. (b) H. Puff, D. Hänssgen, N. Beckemann, A. Roloff, W. Schuh, J. Organomet. Chem. 1989, 373, 37.
23. (c) U. Döhring, D. Hänssgen, M. Jansen, M. Nieger, A. Tellenbach, Z. Anorg. Allg. Chem. 1998, 624, 965.
24. M. Herberhold, in A. Togni, T. Hayashi (eds.), Ferrocenes VCH, Weinheim, 1995, pp. 219-278, and references cited.
25. (a) R. Rulkens; A. J. Lough; I. Manners, Angew. Chem. 1996, 108, 1924; Angew. Chem. Int. Ed. Engl. 1996, 35, 1805;
26. (a) R. Rulkens; A. J. Lough; I. Manners, Angew. Chem. 1996, 108, 1924; Angew. Chem. Int. Ed. Engl. 1996, 35, 1805;
27. (b) F. Jakle, R. Rulkens, G. Zech, D. A. Foucher, A. J. Lough; I. Manners, Chem. Eur. J. 1998, 4, 2117;
28. (c) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, Angew. Chem. 1996, 108, 1927; Angew. Chem. Int. Ed. Engl. 1996, 35, 1803;
29. (c) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, Angew. Chem. 1996, 108, 1927; Angew. Chem. Int. Ed. Engl. 1996, 35, 1803;
30. (d) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, J. Organomet. Chem. 1997, 533, 109;
31. (e) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, Angew. Chem. 1997, 109, 1545; Angew. Chem. Int. Ed. Engl. 1997, 36, 1510;
32. (e) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, Angew. Chem. 1997, 109, 1545; Angew. Chem. Int. Ed. Engl. 1997, 36, 1510;
33. (f) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, Z. Anorg. Allg. Chem. 1998, 624, 386;
34. (g) M. Herberhold, U. Steffl, W. Milius, B. Wrackmeyer, Chem. Eur. J. 1998, 4, 1027.
35. C. J. Jameson, in J. Mason (ed.), Multinuclear NMR, Plenum Press, New York, 1987, pp. 89-131.
36. (a) W. McFarlane, Annu. Rep. NMR Spectrosc. 1968, 1, 135-163;
37. (b) W. McFarlane, Annu. Rep. NMR Spectrosc. 1972, 5A, 353-393.
38. A. Bax, R. Freeman, J. Magn. Reson. 1981, 45, 177.
39. 15N NMR of Silicon, Germanium, Tin and Lead-Nitrogen Compounds, in M. Gielen (ed.), Topics of Physical Organometallic Chemistry, Vol. 4, Freund Publishing House, Tel Aviv, 1992, pp. 289-352;
40. 119Sn-X Spin-Spin Coupling, in M. Gielen, R. Willem, B. Wrackmeyer (eds.), Physical Organometallic Chemistry, Advanced Applications of NMR to Organometallic Chemistry, Vol. 1, Wiley, London 1996, pp. 87-122.
41. (a) B. Wrackmeyer, H. Zhou, Main Group Met. Chem. 1990, 13, 99;
42. (b) B. Wrackmeyer, H. Zhou, Magn. Reson. Chem. 1990, 28, 1066;
43. (c) B. Wrackmeyer, J. Weidinger, H. Nöth, W. Storch, T. Seifert, M. Vosteen, Z. Naturforsch. 1998, 53b, 1494.
44. (a) J. D. Kennedy, W. McFarlane, G. S. Pyne, B. Wrackmeyer, J. Organomet. Chem. 1980, 195, 285;
45. (b) B. Wrackmeyer, K. Horchler, H. Zhou, Spectrochim Acta 1990, 46A, 809.
46. A. Shafir, M. P. Power, G. D. Whitener, J. Arnold, Organometallics 2000, 19, 2987.
47. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-202846 (2) and CCDC-202845 (6). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax (internat.): +44 (0)1223/336033; e-mail: deposit@ccdc.cam.ac.uk].