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For the cleavage of the C-S bond with concurrent S-arylation under palladium-copper catalysis see: Kundu, N. G.; Nandi, B. Tetrahedron 2001, 57, 5885 and references therein.
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Aryl propargyl ethers were prepared according to the procedure described in the literature, see for example: Ishikawa, T.; Mizutani, A.; Miwa, C.; Oku, Y.; Komano, N.; Takami, A.; Watanabe, T. Heterocycles 1997, 45, 2261.
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47
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0141713169
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note
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Participation of Pd(0) is supported further by the appearance of a palladium black on the wall of the reaction flask in a few cases.
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48
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0033579591
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For a similar mechanistic sequences, see: (a) Labrosse, J.-R.; Lhoste, P.; Sinou, D. Tetrahedron Lett. 1999, 40, 9025. (b) Monteiro, N.; Arnold, A.; Blame, G. Synlett 1998, 1111.
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For a similar mechanistic sequences, see: (a) Labrosse, J.-R.; Lhoste, P.; Sinou, D. Tetrahedron Lett. 1999, 40, 9025. (b) Monteiro, N.; Arnold, A.; Blame, G. Synlett 1998, 1111.
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