The carbon kinetic isotope effects of ozone-alkene reactions in the gas-phase and the impact of ozone reactions on the stable carbon isotope ratios of alkenes in the atmosphere

Geophysical Research Letters

Volumn 30, Issue 13, 2003, Pages

  Iannone, R ^a   Anderson, R S ^a   Rudolph, J ^a   Huang, L ^b   Ernst, D ^b  

^a YORK UNIVERSITY   (Canada)

^b ENVIRONMENT CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

COMBUSTION; GAS CHROMATOGRAPHY; ISOTOPES; MASS SPECTROMETRY; OLEFINS; OZONE; BUTENES; CARRIER MOBILITY; ETHYLENE; FREE RADICALS; GASES;

KINETIC ISOTOPE EFFECTS (KIE); CARBON KINETIC ISOTOPE EFFECTS; GAS CHROMATOGRAPHY COMBUSTION-ISOTOPE RATIO MASS SPECTROMETRY; INVERSE DEPENDENCE; ISOTOPIC FRACTIONATIONS; KINETIC ISOTOPE EFFECTS; OH CONCENTRATION; REACTION CHAMBERS; STABLE CARBON ISOTOPE RATIO;

EARTH ATMOSPHERE; HYDROCARBONS;

ALKENE; ATMOSPHERIC CHEMISTRY; CARBON ISOTOPE; OZONE; STABLE ISOTOPE;

EID: 0141737837     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2003GL017221     Document Type: Article

References (12)

1. Atkinson, R., Gas-phase tropospheric chemistry of volatile organic compounds, J. Phys. Chem. Ref. Data Monog., 2, 11-216, 1994.
2. Atkinson, R., Gas-phase tropospheric chemistry of volatile organic compounds, 1, Alkanes and alkenes. J. Phys. Chem. Ref. Data. 26, 215-290, 1997.
3. Brenninkmeijer, C. A. M., D. C. Lowe, M. R. Manning, R. J. Sparks, and P. F. J. van Velthoven, The 13C, 14C, and 180 isotopic composition of CO, CH4, and CO2 in the higher southern latitudes lower stratosphere, J. Geophys. Res., 100, 26,163-26,172, 1995.
4. Ciais, P., P. P. Tans, M. Trolier, J. W. C. White, and R. J. Francey, A large Northern Hemisphere terrestrial CO2 sink indicated by the 13C/12C ratio of atmospheric CO2, Science, 269, 1096-1101, 1995.
5. Ciais, P., P. P. Tans, A. S. Denning, R. J. Francey, M. Trolier, H. A. J. Meijer, J. W. C. White, J. A. Berry, D. A. Randall, G. J. Collatz, P. J. Sellers, P. Monfray, and M. Heimann, A three-dimensional synthesis study of δ180 in atmospheric CO2 2, Simulations with the TM2 transport model, J. Geophys. Res., 102, 5873-5883, 1997.
6. Lowe, D. C., C. A. M. Brenninkmeijer, G. W. Brailsford, K. R. Lassey, A. J. Gomez, and E. G. Nisbet, Concentration and 13C records of atmospheric methane in New Zealand and Antarctica: Evidence for changes in methane sources, J. Geophys. Res., 99, 16,913-16,925, 1994.
7. Rudolph, J., and E. Czuba, On the use of isotopic composition measurement of volatile organic compounds to determine the "photochemical age" of an air mass, Geophys. Res. Lett., 27, 3865-3868, 2000.
8. Rudolph, J., D. Lowe, R. Martin, and T. Clarkson, A novel method of compound specific determination of δ13C in volatile organic compounds at ppt levels in ambient air, Geophys. Res. Lett., 24, 659-662, 1997.
9. Rudolph, J., E. Czuba, and L. Huang, The stable carbon isotope fractionation for reactions of selected hydrocarbons with OH-radicals and its relevance for atmospheric chemistry, J. Geophys. Res., 105, 29,329-29,346, 2000.
10. Rudolph, J., R. S. Anderson, K. v. Czapicwski, E. Czuba, D. Ernst, T. Gillespie, L. Huang, C. Rigby, and A. E. Thompson, The stable carbon isotope ratio of biogenic emissions of isoprene and the potential use of stable isotope ratio measurements to study photochemical processing of isoprene in the atmosphere, J. Atmos. Chem., 44, 39-55, 2003.
11. Saito, T., U. Tsunogai, K. Kawamura, T. Nakatsuka, and N. Yoshida, Stable carbon isotopic composition of light hydrocarbons over the western North Pacific and implications for their photochemical ages, J. Geophys. Res., 107, 10.1029/2000JD000127, 2002.
12. Tsunogai, U., N. Yoshida, and T. Gamo, Carbon isotopic compositions of C2-C5 hydrocarbons and methyl chloride in urban, coastal, and marine atmospheres over the western North Pacific. J. Geophys. Res., 104, l6,033-16,039, 1999.