Solvent-free and TMEDA-solvated mixed alkali metal-magnesium tris-diisopropylamides

European Journal of Inorganic Chemistry

Volumn , Issue 18, 2003, Pages 3347-3353

  Hevia, Eva ^a   Kenley, Fiona R ^a   Kennedy, Alan R ^a   Mulvey, Robert E ^a   Rowlings, René B ^a  

^a UNIVERSITY OF STRATHCLYDE   (United Kingdom)

Author keywords

Alkali metals; Heterometallic complexes; Magnesium; N ligands; Potassium

Indexed keywords

AMIDES; LIGANDS; MAGNESIUM COMPOUNDS; POTASSIUM COMPOUNDS; X RAY DIFFRACTION;

DINUCLEAR; HETEROBIMETALLICS; HETEROMETALLIC COMPLEXES; METAL MAGNESIUMS; MIXED ALKALI; MOLAR EQUIVALENT; N LIGANDS; N-LIGANDS; SOLVENT FREE; SYNTHESISED;

SOLVENTS;

ALKALI METAL; AMIDE; DIAMINE; HYDROCARBON; LIGAND; MAGNESIUM; METAL COMPLEX; POTASSIUM DERIVATIVE; POTASSIUM MAGNESIUM TRIS DIISOPROPYLAMIDE; SODIUM DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CHELATION; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; SOLVATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0141670391     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300413     Document Type: Article

References (38)

1. For reviews of the uses of lithium amides in synthesis see: J. K. Crandall, M. Apparu, Org. React. 1983, 29, 345-443; V. Snieckus, Chem. Rev. 1990, 90, 879-933; C. H. Heathcock, in Comprehensive Organic Synthesis (Eds: B. M. Trost, I. Fleming), Pergamon, New York, 1991, vol. 2, chapter 1.6; T. Satoh, Chem. Rev. 1996, 96, 3303-3326.
2. For reviews of the uses of lithium amides in synthesis see: J. K. Crandall, M. Apparu, Org. React. 1983, 29, 345-443; V. Snieckus, Chem. Rev. 1990, 90, 879-933; C. H. Heathcock, in Comprehensive Organic Synthesis (Eds: B. M. Trost, I. Fleming), Pergamon, New York, 1991, vol. 2, chapter 1.6; T. Satoh, Chem. Rev. 1996, 96, 3303-3326.
3. For reviews of the uses of lithium amides in synthesis see: J. K. Crandall, M. Apparu, Org. React. 1983, 29, 345-443; V. Snieckus, Chem. Rev. 1990, 90, 879-933; C. H. Heathcock, in Comprehensive Organic Synthesis (Eds: B. M. Trost, I. Fleming), Pergamon, New York, 1991, vol. 2, chapter 1.6; T. Satoh, Chem. Rev. 1996, 96, 3303-3326.
4. For reviews of the uses of lithium amides in synthesis see: J. K. Crandall, M. Apparu, Org. React. 1983, 29, 345-443; V. Snieckus, Chem. Rev. 1990, 90, 879-933; C. H. Heathcock, in Comprehensive Organic Synthesis (Eds: B. M. Trost, I. Fleming), Pergamon, New York, 1991, vol. 2, chapter 1.6; T. Satoh, Chem. Rev. 1996, 96, 3303-3326.
5. Collum has made a colossal contribution to correlating the complicated structural chemistry of LDA in solution to its performances and kinetics in organic reactions. For leading papers see: Y.-J. Kim, M. P. Bernstein, A. S. Galiano Roth, F. E. Romesberg, P. G. Williard, D. J. Fuller, A. T. Harrison, D. B. Collum, J. Am. Chem. Soc. 1991, 56, 4435-4439; J. F. Remenar, B. L. Lucht, D. B. Collum, J. Am. Chem. Soc. 1997, 119, 5567-5571; X. Sun, D. B. Collum, J. Am. Chem. Soc. 2000, 122, 2459-2463; J. L. Rutherford, D. B. Collum, J. Am. Chem. Soc. 2001, 123, 199-202.
6. Collum has made a colossal contribution to correlating the complicated structural chemistry of LDA in solution to its performances and kinetics in organic reactions. For leading papers see: Y.-J. Kim, M. P. Bernstein, A. S. Galiano Roth, F. E. Romesberg, P. G. Williard, D. J. Fuller, A. T. Harrison, D. B. Collum, J. Am. Chem. Soc. 1991, 56, 4435-4439; J. F. Remenar, B. L. Lucht, D. B. Collum, J. Am. Chem. Soc. 1997, 119, 5567-5571; X. Sun, D. B. Collum, J. Am. Chem. Soc. 2000, 122, 2459-2463; J. L. Rutherford, D. B. Collum, J. Am. Chem. Soc. 2001, 123, 199-202.
7. Collum has made a colossal contribution to correlating the complicated structural chemistry of LDA in solution to its performances and kinetics in organic reactions. For leading papers see: Y.-J. Kim, M. P. Bernstein, A. S. Galiano Roth, F. E. Romesberg, P. G. Williard, D. J. Fuller, A. T. Harrison, D. B. Collum, J. Am. Chem. Soc. 1991, 56, 4435-4439; J. F. Remenar, B. L. Lucht, D. B. Collum, J. Am. Chem. Soc. 1997, 119, 5567-5571; X. Sun, D. B. Collum, J. Am. Chem. Soc. 2000, 122, 2459-2463; J. L. Rutherford, D. B. Collum, J. Am. Chem. Soc. 2001, 123, 199-202.
8. Collum has made a colossal contribution to correlating the complicated structural chemistry of LDA in solution to its performances and kinetics in organic reactions. For leading papers see: Y.-J. Kim, M. P. Bernstein, A. S. Galiano Roth, F. E. Romesberg, P. G. Williard, D. J. Fuller, A. T. Harrison, D. B. Collum, J. Am. Chem. Soc. 1991, 56, 4435-4439; J. F. Remenar, B. L. Lucht, D. B. Collum, J. Am. Chem. Soc. 1997, 119, 5567-5571; X. Sun, D. B. Collum, J. Am. Chem. Soc. 2000, 122, 2459-2463; J. L. Rutherford, D. B. Collum, J. Am. Chem. Soc. 2001, 123, 199-202.
9. For an excellent general monologue on the multivariate factors which determine the course of an organoalkali metal-mediated reaction see: M. Schlosser, in Organometallics in Synthesis A Manual, 2nd Edn (Ed.: M. Schlosser), John Wiley and Sons Ltd, Chichester, England, 2002, chapter 1, 1-352.
10. R. E. Mulvey, Chem. Commun. 2001, 1049-1056.
11. K. J. Drewette, K. W. Henderson, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, R. B. Rowlings, Chem. Commun. 2002, 1176-1177.
12. D. J. Gallagher, K. W. Henderson, A. R. Kennedy, C. T. O'Hara, R. E. Mulvey, R. B. Rowlings, Chem. Commun. 2002, 376-377.
13. W. Clegg, K. W. Henderson, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, R. B. Rowlings, D. M. Tooke, Angew. Chem. 2001, 113, 4020-4023;Angew. Chem. Int. Ed. 2001, 40, 3902-3905.
14. W. Clegg, K. W. Henderson, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, R. B. Rowlings, D. M. Tooke, Angew. Chem. 2001, 113, 4020-4023;Angew. Chem. Int. Ed. 2001, 40, 3902-3905.
15. A. M. Drummond, L. T. Gibson, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, R. B. Rowlings, T. Weightman, Angew. Chem. 2002, 114, 2488-2490; Angew. Chem. Int. Ed. 2002, 41, 2382-2384.
16. A. M. Drummond, L. T. Gibson, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, R. B. Rowlings, T. Weightman, Angew. Chem. 2002, 114, 2488-2490; Angew. Chem. Int. Ed. 2002, 41, 2382-2384.
17. R. Sanchez, W. Scott, Tetrahedron Lett. 1988, 29, 139-142.
18. P. Andrikopoulos, D. R. Armstrong, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, R. B. Rowlings, following paper in this issue.
19. P. C. Andrews, N. D. R. Barnett, R. E. Mulvey, W. Clegg, P. A. O'Neil, D. Barr, L. Cowton, A. J. Dawson, B. J. Wakefield, J. Organomet. Chem. 1996, 518, 85-95.
20. W. Clegg, S. Kleditzsch, R. E. Mulvey, P. O'Shaughnessy, J. Organomet. Chem. 1998, 558, 193-196.
21. M. Micha-Screttas, C. G. Screttas, B. R. Steele, G. A. Heropoulos, Tetrahedron Lett. 2002, 43, 4871-4873.
22. G. W. Gokel, L. Barbour, S. L. DeWall, E. S. Meadows, Coord. Chem. Rev. 2001, 222, 127-154.
23. E. S. Meadows, S. L. DeWall, L. J. Barbour, G. W. Gokel, J. Am. Chem. Soc. 2001, 123, 3092-3107.
24. Ch. Elschenbroich, A. Salzer, in Organometallics A Concise Introduction, 1st Edn, VCH, Weinheim, 1989, pp 80-81.
25. G. C. Forbes, A. R. Kennedy, R. E. Mulvey, B. A. Roberts, R. B. Rowlings, Organometallics 2002, 21, 5115-5121.
26. N. D. R. Barnett, R. E. Mulvey, W. Clegg, P. A. O'Neil, J. Am. Chem. Soc. 1991, 113, 8187-8188.
27. P. G. Williard, J. M. Salvino, J. Org. Chem. 1993, 58, 1-3.
28. M. P. Bernstein, F. E. Romesberg, D. J. Fuller, A. T. Harrison, D. B. Collum, Q.-Y. Liu, P. G. Williard, J. Am. Chem. Soc. 1992, 114, 5100-5110.
29. P. J. Brothers, R. J. Wehmschulte, M. M. Olmstead, K. Ruhlandt-Senge, S. R. Parkin, P. P. Power, Organometallics 1994, 13, 2792-2799.
30. A. Belforte, F. Calderazzo, U. Englert, J. Strahle, K. Wurst, J. Chem. Soc., Dalton Trans. 1991, 2419-2427.
31. K.-C. Yang, C.-C. Chang, J.-Y. Huang, C.-C. Lin, G.-H. Lee, Y. Wang, M.-Y. Chiang, J. Organomet. Chem. 2002, 648, 176-187.
32. T.-Y. Her, C.-C. Chang, L.-K. Liu, Inorg. Chem. 1992, 31, 2291-2294.
33. M.-D. Li, C.-C. Chang, Y. Wang, G.-H. Lee, Organometallics 1996, 15, 2571-2574.
34. G. C. Forbes, F. R. Kenley, A. R. Kennedy, R. E. Mulvey, C. T. O'Hara, J. A. Parkinson, Chem. Commun. 2003, 1140-1141.
35. B. E. Love, E. G. Jones, J. Org. Chem. 1999, 64, 3755-3756.
36. D. Hoffmann, W. Bauer, F. Hampel, N. J. R. van Eikema Hommes, P. v. R. Schleyer, P. Otto, U. Pieper, D. Stalke, D. S. Wright, R. Snaith, J. Am. Chem. Soc. 1994, 116, 528-536.
37. R. Pi, W. Bauer, B. Brix, C. Schade, P. v. R. Schleyer, J. Organomet. Chem. 1986, 306, C1-C4.
38. C. Schade, W. Bauer, P. v. R. Schleyer, J. Organomet. Chem. 1985, 295, C25-C28.